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| | COBALT(II) BROMIDE Basic information |
| | COBALT(II) BROMIDE Chemical Properties |
| Melting point | 678°C | | density | 4.909 g/mL at 25 °C(lit.) | | solubility | acetone: soluble(lit.) | | form | beads | | color | Green | | Specific Gravity | 4.909 | | Water Solubility | Soluble in water. Soluble in methyl acetate, ether, alcohol, acetone. | | Specific Heat Capacity | Cp(crystal): 0.36 J/(g·K), at 25℃ | | Sensitive | Hygroscopic | | Merck | 14,2435 | | Exposure limits | ACGIH: TWA 0.02 mg/m3 | | Major Application | battery precursors
catalysts
material synthesis precursor | | InChI | InChI=1S/2BrH.Co/h2*1H;/q;;+2/p-2 | | InChIKey | BZRRQSJJPUGBAA-UHFFFAOYSA-L | | SMILES | [Co](Br)Br | | CAS DataBase Reference | 7789-43-7(CAS DataBase Reference) | | EPA Substance Registry System | Cobalt bromide (7789-43-7) |
| Hazard Codes | T,Xn | | Risk Statements | 45-20/21/22-36/37/38-42/43 | | Safety Statements | 36-45-36/37/39-26-22-53 | | RIDADR | UN 3077 9 / PGIII | | WGK Germany | 3 | | RTECS | GF9595000 | | TSCA | TSCA listed | | Storage Class | 6.1C - Combustible acute toxic Cat.3
toxic compounds or compounds which causing chronic effects | | Hazard Classifications | Acute Tox. 4 Oral
Aquatic Acute 1
Aquatic Chronic 1
Carc. 1B
Muta. 2
Resp. Sens. 1
Skin Sens. 1 | | Hazardous Substances Data | 7789-43-7(Hazardous Substances Data) |
| | COBALT(II) BROMIDE Usage And Synthesis |
| Chemical Properties | The green anhydrous salt is prepared by dehydration of the red hexahydrate or by the action of bromine on heated cobalt. It is very soluble in water and soluble in many polar organic solvents; it deliquesces in moist air to a red solution. The hexahydrate crystallizes from aqueous solution at room temperature; it melts at 100°, evolving water and forming the purple dihydrate. | | Chemical Properties | Reddish violet crystalline powder | | Uses | Cobalt(II) bromide is used as a catalyst in organic synthesis. It is used as a precursor in the production of ethylsulfanyl)porphyrazinato)cobalt(II), which gives the possibility of intermolecular ferromagnetic interactions. | | Uses | Used in the preparation of a new complex, Co(OESPz), which offers the possibility of intermolecular ferromagnetic interactions.1 | | Preparation | Cobalt(II) bromide (CoBr2) is on its anhydrous form a green solid that is soluble in water, used primarily as a catalyst in some processes. Cobalt(II) bromide can be formed as a hydrate by the reaction of cobalt hydroxide with hydrobromic acid.
Co (OH) 2 (s)+2HBr (aq)→CoBr2.6H2O(aq) | | General Description | COBALT(II) BROMIDE is a red violet crystalline solid. COBALT(II) BROMIDE is soluble in water. The primary hazard is the threat to the environment. Immediate steps should be taken to limit its spread to the environment. COBALT(II) BROMIDE is used as a catalyst in the production of other chemicals. | | Air & Water Reactions | Water soluble. | | Reactivity Profile | Acidic salts, such as COBALT(II) BROMIDE, are generally soluble in water. The resulting solutions contain moderate concentrations of hydrogen ions and have pH's of less than 7.0. They react as acids to neutralize bases. These neutralizations generate heat, but less or far less than is generated by neutralization of inorganic acids, inorganic oxoacids, and carboxylic acid. They usually do not react as either oxidizing agents or reducing agents but such behavior is not impossible. Many of these compounds catalyze organic reactions. When heated to decomposition can give off highly toxic fumes of Br [USCG, 1999]. | | Health Hazard | SOLID: Irritating to skin and eyes. Harmful if swallowed. | | Fire Hazard | Not flammable. POISONOUS FUMES ARE PRODUCED WHEN HEATED TO DECOMPOSITION. When heated to decomposition can give off highly toxic fumes of Br. | | Purification Methods | Crystallise it from water (1mL/g) by partial evaporation in a desiccator. The anhydrous salt is soluble in EtOH, Me2CO, MeOAc to form blue-coloured solutions. [Glemser in Handbook of Preparative Inorganic Chemistry (Ed. Brauer) Academic Press Vol II p 1517 1965.] |
| | COBALT(II) BROMIDE Preparation Products And Raw materials |
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