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| | Ethyl α-bromophenylacetate Basic information |
| | Ethyl α-bromophenylacetate Chemical Properties |
| Boiling point | 89-92 °C/0.9 mmHg (lit.) | | density | 1.389 g/mL at 25 °C (lit.) | | refractive index | n20/D >1.5390(lit.) | | Fp | >230 °F | | storage temp. | under inert gas (nitrogen or Argon) at 2-8°C | | form | Liquid | | color | Clear colorless to yellow | | Water Solubility | Not miscible or difficult to mix in water. | | Sensitive | Moisture Sensitive | | InChIKey | BKTKLDMYHTUESO-UHFFFAOYSA-N | | CAS DataBase Reference | 2882-19-1(CAS DataBase Reference) | | EPA Substance Registry System | Ethyl .alpha.-bromophenylacetate (2882-19-1) |
| Hazard Codes | C | | Risk Statements | 34 | | Safety Statements | 26-36/37/39-45 | | RIDADR | UN 3265 8/PG 2 | | WGK Germany | 3 | | HazardClass | 8 | | PackingGroup | III | | HS Code | 29163990 |
| | Ethyl α-bromophenylacetate Usage And Synthesis |
| Uses | α-Bromobenzeneacetic acid ethyl ester is used as an alkyl halide initiator in controlled/living radical polymerization of styrene and methyl methacrylate. | | Uses | ETHYL ALPHA-BROMOPHENYLACETATE is used as an alkyl halide initiator in controlled/living radical polymerization of styrene and methyl methacrylate. | | Application | Ethyl α-bromophenylacetate (EBPA) may be used to synthesize α-ethoxycarbonyl-N,α-diphenylnitrone.
EBPA may be used as an initiator for the following:
polymerization of dimethyl(methacryloyloxymethyl) phosphonate
polymerization of methyl methacrylate (MMA)
polymerization of trimethylolpropane triacrylate(TMPTA) | | Synthesis Reference(s) | Tetrahedron Letters, 13, p. 4067, 1972 DOI: 10.1016/S0040-4039(01)94239-X | | Precautions | Moisture sensitive. Store away from oxidizing agents, air and water/moisture. Keep the container tightly closed and place it in a cool, dry and well ventilated condition. Store under inert gas. |
| | Ethyl α-bromophenylacetate Preparation Products And Raw materials |
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