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SALCOMINE

SALCOMINE Suppliers list
Company Name: J & K SCIENTIFIC LTD.  
Tel: 400-666-7788 +86-10-82848833
Email: jkinfo@jkchemical.com;market6@jkchemical.com
Products Intro: Product Name:N,N'-Bis(salicylidene)ethylenediaMinecobalt(Ⅱ)
CAS:14167-18-1
Purity:97% Package:1G,25G,5G
Company Name: Meryer (Shanghai) Chemical Technology Co., Ltd.  
Tel: +86-(0)21-61259100(Shanghai) +86-(0)755-86170099(ShenZhen) +86-(0)10-62670440(Beijing)
Email: sh@meryer.com
Products Intro: Product Name:SalcoMine
CAS:14167-18-1
Purity:95% Package:5g;25g Remarks:AAA124002
Company Name: INTATRADE GmbH  
Tel: +49 3493/605464
Email: sales@intatrade.de
Products Intro: Product Name:N,N'-Bis(salicylidene)ethylenediaminecobalt(II)
CAS:14167-18-1
Remarks:EO05124
Company Name: Alfa Aesar  
Tel: 400-610-6006; 021-67582000
Email: saleschina@alfa-asia.com
Products Intro: Product Name:N,N'-Bis(salicylidene)ethylenediaMinecobalt(II), 96%
CAS:14167-18-1
Package:1g Remarks:043174
Company Name: TCI (Shanghai) Development Co., Ltd.  
Tel: 021-67121386 / 800-988-0390
Email: Sales-CN@TCIchemicals.com
Products Intro: Product Name:Salcomine [=N,N'-Bis(salicylidene)ethylenediiminocobalt(II)]
CAS:14167-18-1
Purity:95.0% T Package:100G,25G
SALCOMINE Basic information
Product Name:SALCOMINE
Synonyms:N,N'-DISALICYLALETHYLENEDIAMINE COBALT(II);N,N'-ETHYLENEBIS(SALICYLIDENEIMINATO)COBALT(II);SALCOMINE;SALEN-CO;CO(SALEN)2;((2,2’-(1,2-ethanediylbis(nitrilomethylidyne))bis(phenolato))(2-)-n,n-cobal;((alpha,alpha’-(ethylenedinitrilo)di-o-cresolato)(2-))-cobal;(N,N'-Ethylenebis(salicylaldehyde iminato))cobalt(II)
CAS:14167-18-1
MF:C16H14CoN2O2
MW:325.23
EINECS:238-012-5
Product Categories:Catalysts for Organic Synthesis;Classes of Metal Compounds;Co (Cobalt) Compounds;Homogeneous Catalysts;Metal Complexes;Synthetic Organic Chemistry;Transition Metal Compounds
Mol File:14167-18-1.mol
SALCOMINE Structure
SALCOMINE Chemical Properties
Water Solubility Insoluble in water. Soluble in benzene, chloroform, and pyridine.
Stability:Stable. Incompatible with strong acids, strong oxidizing agents.
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26-36
WGK Germany 2
RTECS GG0590000
10
TSCA Yes
MSDS Information
ProviderLanguage
SigmaAldrich English
ALFA English
SALCOMINE Usage And Synthesis
Chemical Propertiesblack crystalline powder
General DescriptionA solid complex between the cobalt(II) ion and the condensation product of salicylaldehyde and ethylenediamine. Such condensation products are called "Schiff's bases." Complexation with cobalt nullifies their basic properties. Used as a catalyst for various oxidation reactions in which SALCOMINE behaves as an oxygen carrier.
Reactivity ProfileSALCOMINE may increase the rate of oxidation reactions such as the conversion of amines to nitro compounds by peroxides or hydroperoxides.
Purification MethodsThe powder should have an oxygen capacity of 4.7-4.8% as measured by the increase in weight under O2 at 100 pounds pressure at ca 20o. The O2 is expelled on heating the material to 65o. It crystallises from pyridine, CHCl3 or *C6H6, and the solvent may be removed by heating at 120o in a vacuum. However, this heating may mean reduced O2 capacity. In the dry state it absorbs O2, turning from a maroon colour to black. [Diehl & Hack Inorg Synth III 196 1950.]
SALCOMINE Preparation Products And Raw materials
Tag:SALCOMINE(14167-18-1) Related Product Information
Ethylenediamine Salicylaldehyde SALCOMINE SALCOMINE HYDRATE