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| | CYCLOPENTADIENYLTRIMETHYLSILANE Chemical Properties |
| Melting point | -19 °C | | Boiling point | 32-34 °C12 mm Hg(lit.) | | density | 0.833 g/mL at 25 °C(lit.) | | refractive index | n20/D 1.465 | | Fp | 29 °C | | storage temp. | -20°C | | form | liquid | | Specific Gravity | 0.833 | | color | colorless | | Sensitive | Moisture Sensitive | | InChI | 1S/C8H14Si/c1-9(2,3)8-6-4-5-7-8/h4-8H,1-3H3 | | InChIKey | VMFHCJPMKUTMMQ-UHFFFAOYSA-N | | SMILES | C[Si](C)(C)C1C=CC=C1 | | CAS DataBase Reference | 3559-74-8(CAS DataBase Reference) |
| Hazard Codes | Xi | | Risk Statements | 10-36/37/38 | | Safety Statements | 23-24/25-36/37/39-26-16 | | RIDADR | UN 1993 3/PG 3 | | WGK Germany | 3 | | F | 10 | | HazardClass | 3 | | PackingGroup | III | | HS Code | 29310099 | | Storage Class | 3 - Flammable liquids | | Hazard Classifications | Eye Irrit. 2
Flam. Liq. 3
Skin Irrit. 2
STOT SE 3 |
| | CYCLOPENTADIENYLTRIMETHYLSILANE Usage And Synthesis |
| Description | Cyclopentadienyltrimethylsilane (also known as trimethylsilyl cyclopentadiene) is a kind of organosilicon compound. It is used in the synthesis of some metal cyclopentadienyl complexes and has attracted interest for its structure owing to its property undergoing rapid sigmatropic rearrangement. It is a useful reactant involved in numerous reactions such as Diels-Alder reactions, synthesis of ring-functionalized molybdenocene complexes, allyl isomerization, aromatization of C5 rings and synthesis of N-hydroxyindoles via nucleophilic addition.
| | Sources | https://en.wikipedia.org/wiki/Trimethylsilyl_cyclopentadiene
https://www.sigmaaldrich.com/catalog/product/aldrich/257885?lang=en®ion=US
| | Chemical Properties | Clear colorless liquid | | Uses | Reactant involved in:
- Diels-Alder reactions
- Synthesis of ring-functionalized molybdenocene complexes
- Allyl isomerization
- Aromatization of C5 rings
- Synthesis of N-hydroxyindoles via nucleophilic addition
| | Uses | Reactant involved in:• ;Diels-Alder reactions1,2• ;Synthesis of ring-functionalized molybdenocene complexes3• ;Allyl isomerization4• ;Aromatization of C5 rings5• ;Synthesis of N-hydroxyindoles via nucleophilic addition6 | | General Description | Trimethylsilyl cyclopentadiene reacts with ruthenium trichloride in alcohol solvent to yield ruthenocene. |
| | CYCLOPENTADIENYLTRIMETHYLSILANE Preparation Products And Raw materials |
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