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Bis(benzonitrile)palladium chloride

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Company Name: Wuhan LPBchem Technology Co.,Ltd
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Products Intro: Product Name:Bis(benzonitrile)palladium(II)chloride
CAS:14220-64-5
Purity:0.98 Package:10g;10USD|100g;10USD|1000g;10USD Remarks:Yellow powder
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Products Intro: Product Name:Bis(benzonitrile)palladium chloride
CAS:14220-64-5
Purity:98%(Min,HPLC) Package:100g;1kg;5kg,10kg,25kg,50kg
Company Name: Henan DaKen Chemical CO.,LTD.
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Products Intro: Product Name:Bis(benzonitrile)palladium(II)chloride
CAS:14220-64-5
Purity:98.00% Package:1g,5g,10g,100g,500g,1kg Remarks:Catalysts
Company Name: Hangzhou FandaChem Co.,Ltd.
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CAS:14220-64-5
Purity:As coa Package:As request Remarks:14220-64-5
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Products Intro: Product Name:Bis(benzonitrile)palladium chloride
CAS:14220-64-5
Purity:0.99 Package:5G,10G,25G,50G,100G,250G,1KG

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Bis(benzonitrile)palladium chloride Basic information
Reaction
Product Name:Bis(benzonitrile)palladium chloride
Synonyms:TRANS-BIS-(BENZONITRILE)PALLADIUM(II) CHLORIDE;Dichlorobis(benzonitrile)palladiuM(II),98% (C6H5CN)2PdCl2;Pd(PhCN)2Cl2;trans-Bis(benzonitrile)palladiuM chloride;Dichlorobis(benzonitrile)palladium(Ⅱ);Benzonitrile, palladium complex;Bis(phenylnitrile)dichloropalladium;Dibenzonitrilepalladium dichloride
CAS:14220-64-5
MF:C14H10Cl2N2Pd
MW:383.57
EINECS:238-085-3
Product Categories:organometallic complexes;Metal Compounds;Catalysts for Organic Synthesis;Classes of Metal Compounds;Homogeneous Catalysts;Metal Complexes;Pd (Palladium) Compounds;Synthetic Organic Chemistry;Transition Metal Compounds;chemical reaction,pharm,electronic,materials;Pd
Mol File:14220-64-5.mol
Bis(benzonitrile)palladium chloride Structure
Bis(benzonitrile)palladium chloride Chemical Properties
Melting point 131 °C(lit.)
storage temp. Inert atmosphere,2-8°C
solubility Soluble in acetone, chloroform
form Crystalline Powder
color Orange to brown
Water Solubility insoluble
Hydrolytic Sensitivity4: no reaction with water under neutral conditions
BRN 3981730
InChIKeyWXNOJTUTEXAZLD-UHFFFAOYSA-L
CAS DataBase Reference14220-64-5(CAS DataBase Reference)
Safety Information
Hazard Codes Xn
Risk Statements 20/21-23/24/25
Safety Statements 22-24/25-23-45-36/37-27-20-9-4
RIDADR UN3439
WGK Germany 3
9
TSCA No
HazardClass 6.1
PackingGroup III
HS Code 28439090
MSDS Information
ProviderLanguage
Bis(benzonitrile)palladium chloride English
SigmaAldrich English
ACROS English
ALFA English
Bis(benzonitrile)palladium chloride Usage And Synthesis
Reaction
  1. Catalyst for the cyclization of δ-acetylenic carboxylic acids to butenolides.
  2. Catalyst for the aza-Michael reaction of carbamates with enones.
  3. Catalyst for the rearrangement of allylic imidates to allylic amides.
  4. Catalyst for the Nazarov cyclization of α-alkoxy dienones.
  5. Catalyst for the diamination of conjugated dienes.
  6. Three component Michael addition, cyclization, cross-coupling reaction.
  7. C-H activation of indoles.

Chemical Propertiesyellow powder
Usessuzuki reaction
UsesCatalyst for greener amine synthesis from terminal olefins by Wacker oxidation followed by transfer hydrogenation of the resultant imine.
Bis(benzonitrile)palladium chloride Preparation Products And Raw materials
Raw materialsToluene-->Palladium chloride-->Benzonitrile
Preparation ProductsChlorodimethylphenylsilane
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