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| Carbonyldihydrotris(triphenylphosphine)ruthenium Basic information | Reaction |
| Carbonyldihydrotris(triphenylphosphine)ruthenium Chemical Properties |
Melting point | 161-163 °C(lit.) | storage temp. | Inert atmosphere,2-8°C | form | Powder | color | white to off-white | Water Solubility | Insoluble in water. | Sensitive | Moisture Sensitive |
Hazard Codes | Xn | Risk Statements | 20/21/22 | Safety Statements | 36 | RIDADR | UN2813 | WGK Germany | 3 | HazardClass | 4.3 | PackingGroup | III | HS Code | 28439000 |
| Carbonyldihydrotris(triphenylphosphine)ruthenium Usage And Synthesis |
Reaction |
- Catalyst for the arylation (or alkenylation) of anthraquinone and PBI.
- Catalytic C-C bond formation.
- Transfer hydrogenative coupling of isoprene to alcohols or aldehydes.
- Alkanes (and alkenes) from alcohols by tandem hydrogen transfer and condensation.
- Catalyst for the conversion of primary alcohols and aldehydes into methyl esters.
- Precatalyst for hydrogen production by means of alcohol dehydrogenation.
| Chemical Properties | White to off-white powder | Uses | &bull Catalyst for conversion of 1,4-alkynediols into pyrroles &bull Catalyst for oxidation of primary alcohols to methyl esters &bull Catalyst for rearrangement of oximes to amides &bull Catalyst for C-C coupling via directed C-H activation &bull Cata | Uses | - Catalyst for conversion of 1,4-alkynediols into pyrroles
- Catalyst for oxidation of primary alcohols to methyl esters
- Catalyst for rearrangement of oximes to amides
- Catalyst for C-C coupling via directed C-H activation
- Catalyst for enyne cyclization
| Uses | Carbonyldihydrotris(triphenylphosphine)ruthenium(II) is a catalyst used in the preparation of ruthenium (diphenylphosphino)ethyl)amine complexes pre-catalysts for hydrogenation and dehydrogenation. |
| Carbonyldihydrotris(triphenylphosphine)ruthenium Preparation Products And Raw materials |
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