ChemicalBook > Product Catalog >Biochemical Engineering >Saccharides >Monosaccharide >beta-D-Ribofuranose 1,2,3,5-tetraacetate

beta-D-Ribofuranose 1,2,3,5-tetraacetate

beta-D-Ribofuranose 1,2,3,5-tetraacetate Suppliers list
Company Name: SIMAGCHEM CORP
Tel: +86-13806087780
Email: sale@simagchem.com
Products Intro: Product Name:beta-d-ribofuranose 1,2,3,5-tetraacetate
CAS:13035-61-5
Purity:0.99 Package:1kg,5kg,25kgs,200kgs;bulk
Company Name: Hangzhou Measure Life Technology Co., LTD
Tel: +8613343730176
Email: 2924244016@qq.com
Products Intro: Product Name:beta-D-Ribofuranose1,2,3,5-tetraacetate
CAS:13035-61-5
Purity:0.99 Package:25KG
Company Name: Xinxiang Aurora Biotechnology Co.,Ltd.
Tel: +86-0086-0373-3088722 +8618637352520
Email: info@aurora-biotech.com
Products Intro: Product Name:Tetraacetylribofuranose
CAS:13035-61-5
Purity:98% Package:25Kg
Company Name: Hebei Weibang Biotechnology Co., Ltd
Tel: +8615531157085
Email: abby@weibangbio.com
Products Intro: Product Name:beta-D-Ribofuranose 1,2,3,5-tetraacetate
CAS:13035-61-5
Purity:99% Package:1kg;1.00;USD
Company Name: Hebei Mujin Biotechnology Co.,Ltd
Tel: +86 13288715578 +8613288715578
Email: sales@hbmojin.com
Products Intro: Product Name:Beta-D-Ribofuranose 1,2,3,5-tetraacetate
CAS:13035-61-5
Purity:99% Package:25KG

beta-D-Ribofuranose 1,2,3,5-tetraacetate manufacturers

beta-D-Ribofuranose 1,2,3,5-tetraacetate Basic information
Product Name:beta-D-Ribofuranose 1,2,3,5-tetraacetate
Synonyms:-D-RIBOFURANOSE 1,2,3,5-TETRAACETATE;β-D-Ribo;1,2,3,5-Tetraacetylribofuranose;D-Ribose tetraacetate;Tetraacetyl-β-D-ribofuranose;beta-D-Ribofuranose 1,2,3,5-tetraacetate, 98+%;á-d-ribofuranose 1,2,3,5-tetraacetate;β-d-ribofuranose 1,2,3,5-tetra-o-acetate
CAS:13035-61-5
MF:C13H18O9
MW:318.28
EINECS:235-898-5
Product Categories:Nucleic acids;Pharmaceutical Intermediates;Sugars, Carbohydrates & Glucosides;Biochemistry;Nucleosides, Nucleotides & Related Reagents;O-Substituted Sugars;Ribose;Riboses and 2'-Deoxyriboses;Sugars;Carbohydrates & Derivatives;Intermediates & Fine Chemicals;Pharmaceuticals;13035-61-5;Glycon Biochem
Mol File:13035-61-5.mol
beta-D-Ribofuranose 1,2,3,5-tetraacetate Structure
beta-D-Ribofuranose 1,2,3,5-tetraacetate Chemical Properties
Melting point 81-83 °C(lit.)
alpha -15.4 º (c=7, MeOH)
Boiling point 417.45°C (rough estimate)
density 1.4171 (rough estimate)
refractive index -14.5 ° (C=5, MeOH)
storage temp. Inert atmosphere,Room Temperature
solubility Chloroform (Sparingly), Methanol (Slightly)
form Crystalline Powder
color White to almost white
optical activity[α]26/D 11.4°, c = 10 in chloroform
BRN 94078
InChIInChI=1/C13H18O9/c1-6(14)18-5-10-11(19-7(2)15)12(20-8(3)16)13(22-10)21-9(4)17/h10-13H,5H2,1-4H3/t10-,11-,12-,13-/s3
InChIKeyTTXVPMATRDJQIA-BKUVIOGVSA-N
SMILES[C@@H]1(OC(=O)C)[C@@H](COC(=O)C)O[C@@H](OC(=O)C)[C@@H]1OC(=O)C |&1:0,5,12,17,r|
CAS DataBase Reference13035-61-5(CAS DataBase Reference)
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 22-24/25-36-26
WGK Germany 3
HS Code 29400090
MSDS Information
ProviderLanguage
beta-D-Ribofuranose 1,2,3,5-tetraacetate English
SigmaAldrich English
ACROS English
ALFA English
beta-D-Ribofuranose 1,2,3,5-tetraacetate Usage And Synthesis
Descriptionbeta-D-Ribofuranose 1,2,3,5-tetraacetate is an acetylated derivative of ribose extensively used in carbohydrate research and synthetic chemistry. This compound features acetyl groups protecting the hydroxyl functionalities at positions 1, 2, 3, and 5 of the ribofuranose ring, which enhances its stability and solubility in organic solvents. β-D-Ribofuranose 1,2,3,5-tetraacetate is a crucial intermediate in synthesising nucleosides, nucleotides, and other complex carbohydrates. In research, it is utilized to study glycosylation mechanisms, focusing on the formation and stereochemistry of glycosidic bonds.
Chemical Propertiesbeta-D-Ribofuranose 1,2,3,5-tetraacetate is white to almost white crystalline powder
Usesbeta-D-Ribofuranose 1,2,3,5-tetraacetate is used in the synthesis of 3-(β-D-ribofuranosyl)-2,3-dihydro-6H-1,3-oxazine-2,6-dione, a new pyrimidine nucleoside analog related to uridine.
Applicationbeta-D-Ribofuranose 1,2,3,5-tetraacetate, also known as 1,2,3,5-tetra-O-Acetyl-beta-D-ribofuranose (TAR), is an important organic reagent that can be used in the following pathways:
(1) Used in low-energy electron-induced reactions in gas-phase TAR. Since the acetyl group in TAR is coupled to the five-membered ribose ring at relevant positions, it can serve as a suitable model compound for studying the reaction of sugar units in DNA to low-energy electrons[1].
(2) Used to prepare 1,2,3-tri-O-acetyl-β-d-ribofuranose by enzymatic deacetylation[2].
(3) Used in condensation reactions. In the presence of tin chloride, 1-hexene reacts with 1- O -acetyl-2,3,5-tri- O -benzoyl-β- d -ribofuranose ( 5b ) or 1,2,3,5-tetra- O -acetyl-β- d -ribofuranose ( 5a ) to form a complex mixture[3].
References[1] ILKO BALD. Low energy electron-induced reactions in gas phase 1,2,3,5-tetra-O-acetyl-beta-D-ribofuranose: a model system for the behavior of sugar in DNA.[J]. Journal of Chemical Physics, 2007. DOI:10.1063/1.2436873.
[2] TUN-CHENG CHIEN; Ji W C. A convenient preparation of 1,2,3-tri-O-acetyl-β-d-ribofuranose by enzymatic regioselective 5-O-deacetylation of the peracetylated ribofuranose[J]. Carbohydrate Research, 2004. DOI:10.1016/j.carres.2004.01.010.
[3] THOMAS L. CUPPS; Leroy B T; Dean S Wise. A further investigation of the stannic chloride-catalyzed condensation reaction of 1-hexene and 1,2,3,5-tetra-O-acyl-β-d-ribofuranoses[J]. Carbohydrate Research, 1983. DOI:10.1016/0008-6215(83)88135-X.
beta-D-Ribofuranose 1,2,3,5-tetraacetate Preparation Products And Raw materials
Raw materialsInosine
Preparation Products7H-Purin-6-amine, 7-(2,3,5-tri-O-acetyl-β-D-ribofuranosyl)--->5-Bromouridine-->alpha-D-ribofuranose,1,2-O-(1-methylethylidene)-
Tag:beta-D-Ribofuranose 1,2,3,5-tetraacetate(13035-61-5) Related Product Information
Acetylacetone Acetaminophen Tetraacetylethylenediamine Acetylsalicylic acid Acetylcholine Acetylspiramycin Ribonucleic acid Acetyl chloride Acetyl coenzyme A sodium salt N-Acetyl-L-cysteine beta-D-Ribofuranose 1-acetate 2,3,5-tribenzoate 1-O-Acetyl-2,3,5-tri-O-(4-chlorobenzoyl)-beta-D-ribofuranose 1-ACETYL-2,3,5-TRI-O-BENZOYL-B-L-RIBOFURANOSE TETRAACETYLRIBOFURANOSE ETHYL-BIS-(SODIUMTETRAZOYLAZO)ACETATE 1,2,3,5-Tetra-O-benzoyl-2C-methyl-D-ribofuranose ACETAMINOPHENOL BP/USP beta-D-Ribofuranose 1,2,3,5-tetraacetate