ChemicalBook > Product Catalog >Organic Chemistry >Hydrocarbons and derivatives >Acyclic hydrocarbons >Isobutylene

Isobutylene

Isobutylene Suppliers list
Company Name: Hebei Mojin Biotechnology Co., Ltd
Tel: +86-13288715578 +86-13231137666
Email: sales@hbmojin.com
Products Intro: Product Name:Isobutylene
CAS:115-11-7
Purity:99% Package:1KG;20USD
Company Name: Henan Fengda Chemical Co., Ltd
Tel: +8613613820652
Email: info@fdachem.com
Products Intro: Product Name:Isobutylene
CAS:115-11-7
Purity:99% Package:1KG;101USD|1000KG;1USD
Company Name: Henan Tianfu Chemical Co.,Ltd.
Tel: +86-0371-55170693 +86-19937530512
Email: info@tianfuchem.com
Products Intro: Product Name:Isobutene
CAS:115-11-7
Purity:99% Package:25KG;5KG;1KG
Company Name: career henan chemical co
Tel: +86-0371-86658258
Email: sales@coreychem.com
Products Intro: Product Name:ISOBUTYLENE
CAS:115-11-7
Purity:99% Package:1kg;1USD
Company Name: Hubei Jusheng Technology Co.,Ltd.
Tel: 18871490254
Email: linda@hubeijusheng.com
Products Intro: Product Name:Isobutene
CAS:115-11-7
Purity:99% Package:5KG;1KG

Isobutylene manufacturers

  • Isobutylene
  • Isobutylene pictures
  • $101.00 / 1KG
  • 2023-12-29
  • CAS:115-11-7
  • Min. Order: 1KG
  • Purity: 99%
  • Supply Ability: g-kg-tons, free sample is available
  • Isobutylene
  • Isobutylene pictures
  • $20.00 / 1KG
  • 2023-08-14
  • CAS:115-11-7
  • Min. Order: 1KG
  • Purity: 99%
  • Supply Ability: 50000kg
  • ISOBUTYLENE
  • ISOBUTYLENE pictures
  • $1.10 / 1g
  • 2023-07-27
  • CAS:115-11-7
  • Min. Order: 1g
  • Purity: 99.0% Min
  • Supply Ability: 100 Tons
Isobutylene Basic information
Product Name:Isobutylene
Synonyms:HP-ISOBUTYLENE;ISOBUTYLENE;1,1-dimethylethene;1,1-Dimethylethylene;2-methyl-1-propen;2-Methylpropene-isobutylene;2-METHYLPROPENE CYL. WITH 27 L (NET~14KG;2-METHYLPROPENE PRESSURE TIN WITH 250 ML (NET ~150 G)
CAS:115-11-7
MF:C4H8
MW:56.11
EINECS:204-066-3
Product Categories:Chemical Synthesis;Specialty Gases;Synthetic Reagents;Gas Cylinders;Hydrocarbons (Low Boiling point);Synthetic Organic Chemistry
Mol File:115-11-7.mol
Isobutylene Structure
Isobutylene Chemical Properties
Melting point −140 °C
Boiling point −6.9 °C(lit.)
density 0.5879
vapor density 2 (vs air)
vapor pressure 3278 mm Hg ( 37.7 °C)
refractive index 1.3811
Fp -80 °C
form clear liquid
color Colorless to Almost colorless
Odor Threshold10ppm
Water Solubility 263mg/L(25 ºC)
FreezingPoint -140.34℃
Merck 14,5141
BRN 773645
Henry's Law Constant0.20, 0.26, 0.33, and 0.41 at 30, 40, 50, and 60 °C, respectively (Leung et al., 1987:Zhang et al., 2002)
Stability:Stable. Highly flammable - readily forms an explosive mixture with air. Incompatible with strong oxidizing agents.
InChIKeyVQTUBCCKSQIDNK-UHFFFAOYSA-N
LogP2.35 at 20℃
CAS DataBase Reference115-11-7(CAS DataBase Reference)
EPA Substance Registry SystemIsobutene (115-11-7)
Safety Information
Hazard Codes F+
Risk Statements 12
Safety Statements 9-16-33
RIDADR UN 1055 2.1
WGK Germany -
RTECS UD0890000
4.5-31
Autoignition Temperature869 °F
DOT Classification2.1 (Flammable gas)
HazardClass 2.1
PackingGroup III
HS Code 29012330
Hazardous Substances Data115-11-7(Hazardous Substances Data)
ToxicityLC50 (inhalation) for mice 415 g/m3/2-h, rats 620 g/m3/4-h (quoted, RTECS, 1985).
MSDS Information
ProviderLanguage
SigmaAldrich English
Isobutylene Usage And Synthesis
Physical propertiesColorless gas with a coal gas-like odor. The odor threshold concentration is 10 ppmv Nagata and Takeuchi (1990). This gas can be liquefied under pressure. The substance has low solubility in water, soluble in organic solvent, easy to polymerize. It is nonexplosive; however, it forms explosive mixtures with air. Containers holding isobutylene under pressure may explode if heated. The boiling point and freezing point of isobutylene are -6.9°C (19.6°F) and -141°C (-221°F), respectively. Isobutylene is extremely flammable. It is stable under recommended storage conditions and no decomposition may occur if stored and applied as directed.
UsesIsobutylene is used as a monomer for the production of various polymers such as butyl rubber, polybutene and polyisobutylene. The most important application of butyl rubber is the manufacture of tyres for cars and other vehicles. Other applications of butyl rubber, polybutene and poyisobutylene are lubricants (motor oils), adhesives, sealants and coatings. Another major use of isobutylene is the production of methyl-tert-butyl ether (MTBE) and ethy-tert-butyl ether (ETBE) which are gasoline blending components for cleaner burning fuels. Isobutylene is also used for the production of anti-oxidants, fragrances and gas odorization products.
UsesIsobutylene is an easily liquefied gas that primarily used to produce diisobutylene, trimers, butyl rubber, and other polymers. It is also used to produce antioxidants for foods, packaging, food supplements, and for plastics: Hatch, Pet. Refin. 39, No. 6, 207 (1960).
ApplicationIsobutylene is an important petrochemical raw material. In the pesticide industry, it is mainly used for the preparation of the organophosphorus insecticide terbufos, the pyrethroid insecticide permethrin and the acaricide pyridaben. Industrially, high-concentration isobutylene is mainly used for the production of polyisobutylene and copolymerization with isoprene to produce butyl rubber. The alkylation reaction of isobutene and isobutane can produce high-octane alkylated gasoline, and methyl tert-butyl ether obtained by reacting with methanol is an excellent gasoline additive.
DefinitionChEBI: isobutylene is an alkene that is prop-1-ene substituted by a methyl group at position 2. It is an alkene and a gas molecular entity.
Production MethodsIsobutene is produced in refinery streams by absorption on 65% H2SO4 at about 15C, or by reacting with an aliphatic primary alcohol and then hydrolyzing the resulting ether.
General DescriptionIsobutylene is a colorless gas with a faint petroleum-like odor. For transportation it may be stenched. It is shipped as a liquefied gas under its own vapor pressure. Contact with the liquid can cause frostbite. It is easily ignited. Its vapors are heavier than air and a flame can flash back to the source of leak very easily. The leak can either be a liquid or vapor leak. It can asphyxiate by the displacement of air. Under prolonged exposure to fire or heat the containers may rupture violently and rocket. It is used in the production of isooctane, a high octane aviation gasoline.
Air & Water ReactionsHighly flammable.
Reactivity ProfileISOBUTYLENE is incompatible with oxidizers. ISOBUTYLENE polymerizes easily. ISOBUTYLENE reacts easily with numerous materials, such as alkyl halides, halogens, concentrated sulfuric acid, hypochlorous acid, aluminum chloride, carbon monoxide and hydrogen with a cobalt catalyst. Polymerization is catalyzed by aluminum chloride and boron trifluoride.
HazardHighly flammable, dangerous fire and explosion risk, explosive limits in air 1.8–8.8%.
Health HazardInhalation of moderate concentrations causes dizziness, drowsiness, and unconsciousness. Contact with eyes or skin may cause irritation; the liquid may cause frostbite.
Fire HazardBehavior in Fire: Containers may explode in fire. Vapor is heavier than air and may travel a long distance to a source of ignition and flash back.
Flammability and ExplosibilityExtremely flammable
CarcinogenicityGroups of 50 male and 50 female F344/N rats were exposed to isobutene at concentrations of 0, 500, 2000, or 8000 ppm6 h/day 5 days/week for 105 weeks. Groups of 50 male and 50 female B6C3F1 mice were exposed to isobutene at concentrations of 0, 500, 2000, or 8000 ppm 6 h/day, 5 days/week for 105 weeks. Under the conditions of these 2 year inhalation studies, there was some evidence of the carcinogenic activity of isobutene in male F344/N rats based on an increased incidence of follicular cell carcinoma of the thyroid gland. There was no evidence of the carcinogenic activity of isobutene in female F344/N rats or male or female B6C3F1 mice exposed to 500, 2000, or 8000 ppm.
SourceSchauer et al. (2001) measured organic compound emission rates for volatile organic compounds, gas-phase semi-volatile organic compounds, and particle-phase organic compounds from the residential (fireplace) combustion of pine, oak, and eucalyptus. The gas-phase emission rate of 2-methylpropene was 40.1 mg/kg of pine burned. Emission rates of 2-methylbutene were not measured during the combustion of oak and eucalyptus.
California Phase II reformulated gasoline contained 2-methylpropene at a concentration of 170 mg/kg. Gas-phase tailpipe emission rates from gasoline-powered automobiles with and without catalytic converters were 15.6 and 427 mg/km, respectively (Schauer et al., 2002).
Environmental fatePhotolytic. Products identified from the photoirradiation of 2-methylpropene with nitrogen dioxide in air are 2-butanone, 2-methylpropanal, acetone, carbon monoxide, carbon dioxide, methanol, methyl nitrate, and nitric acid (Takeuchi et al., 1983). Similarly, products identified from the reaction of 2-methylpropene with ozone included acetone, formaldehyde, methanol, carbon monoxide, carbon dioxide, and methane (Tuazon et al., 1997).
The following rate constants were reported for the reaction of 2-methylpropene and OH radicals in the atmosphere: 3.0 x 10-13 cm3/molecule?sec at 300 K (Hendry and Kenley, 1979); 5.40 x 10-11 cm3/molecule?sec (Atkinson et al., 1979); 5.14 x 10-11 at 298 K (Atkinson, 1990). Reported reaction rate constants for 2-methylpropene and ozone in the atmosphere include 2.3 x 10-19 cm3/molecule?sec (Bufalini and Altshuller, 1965); 1.17 x 10-19 cm3/molecule?sec at 300 K (Adeniji et al., 1965); 1.21 x 10-17 cm3/molecule?sec at 298 K (Atkinson, 1990).
Chemical/Physical. Complete combustion in air yields carbon dioxide and water. Incomplete combustion yields carbon monoxide.
Solubility in organics(mole fraction):
In 1-butanol: 0.131, 0.0695, and 0.0458 at 25, 30, and 70 °C, respectively; chlorobenzene: 0.234, 0.132, and 0.0796 at 25, 30, and 70 °C, respectively; octane: 0.333, 0.184, and 0.119 at 25, 30, and 70 °C, respectively (Hayduk et al., 1988).
Purification MethodsDry isobutene by passage through anhydrous CaSO4 at 0o. Purify it further by freeze-pump-thaw cycles and trap-to-trap distillation. [Beilstein 1 IV 796.]
Tag:Isobutylene(115-11-7) Related Product Information
tert-Butyl methyl ether n-Butane ISOBUTYLLITHIUM 2-Methyl-1-propanol Isobutylmercaptan Isobutyric anhydride Triethoxyisobutylsilane Isobutaneboronic acid Isobutyraldehyde Isopropyl alcohol Isopropyl ether 2 1-CHLORO-2-METHYL-1-PROPENE 1,4,5,8,9,10-Hexahydroanthracene 4-Chloro-alpha-methylstyrene Bianthrone 3-Chloro-2-methylpropene 3,3-Dimethylallyl bromide BROMINATED ISOPRENE-ISOBUTYLENE POLYMER