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| | ISOPROPENYLMAGNESIUM BROMIDE Basic information |
| Product Name: | ISOPROPENYLMAGNESIUM BROMIDE | | Synonyms: | Isopropenylmagnesium bromide, 0.5 M solution in THF, HySeal;Isopropenylmagnesium bromide 1M solution in tetrahydrofuran;ISOPROPENYLMAGNESIUM BROMIDE;isopropenylmagnesium bromide solution;ISOPROPENYLMAGNESIUM BROMIDE SOLUTION, ~ 0.5 M IN THF;ISOPROPENYLMAGNESIUM BROMIDE, 0.5M SOLUT ION IN TETRAHYDROFURAN;ISOPROPENYLMAGNESIUM BROMIDE in ETHYL ETHER;ISOPROPENYLMAGNESIUM BROMIDE in TETRAHYDROFURAN | | CAS: | 13291-18-4 | | MF: | C3H5BrMg | | MW: | 145.28 | | EINECS: | 603-688-6 | | Product Categories: | Grignard Reagent;Alkenyl;Grignard Reagents;Organometallic Reagents | | Mol File: | 13291-18-4.mol |  |
| | ISOPROPENYLMAGNESIUM BROMIDE Chemical Properties |
| Melting point | 102-104 °C | | Boiling point | 67 °C | | density | 0.94 g/mL at 20 °C | | Fp | −36 °F | | storage temp. | 2-8°C | | form | Crystalline Powder | | color | White to yellow to orange | | BRN | 3587297 | | InChIKey | LFTYALBVGVNGLI-UHFFFAOYSA-M |
| | ISOPROPENYLMAGNESIUM BROMIDE Usage And Synthesis |
| Uses | Grignard reagent in greener solvent, 2-methyltetrahydrofuran (2-MeTHF)
2-Methyltetrahydrofuran (2-MeTHF): A Biomass-Derived Solvent with Broad Application in Organic Chemistry | | Uses | Isopropenylmagnesium bromide (iPrMgBr) solution (0.5 M in THF) has been used in the Grignard reaction, a key step the in preparation of zofenoprilat and (S)-(?)-phosphonotrixin. It can also be used for the regioselective ring opening of an optically active epoxy alcohol in the total synthesis of (+)-desepoxyasperdiol. | | General Description | This product, 1.0 M in 2-methyltetrahydrofuran aligns with Safer Solvents and Auxiliaries, Use of Renewable Feedstocks and Inherently Safer Chemistry for Accident Prevention. |
| | ISOPROPENYLMAGNESIUM BROMIDE Preparation Products And Raw materials |
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