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Dimethyl maleate

Dimethyl maleate Suppliers list
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CAS:624-48-6
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CAS:624-48-6
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CAS:624-48-6
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Dimethyl maleate manufacturers

  • Dimethyl maleate
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  • 2023-12-24
  • CAS:624-48-6
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  • 2023-03-06
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  • 2023-01-31
  • CAS:624-48-6
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Dimethyl maleate Basic information
Product Name:Dimethyl maleate
Synonyms:dimethylesterkyselinymaleinove;Sipomer DMM 6;sipomerdmm;TwoMethyl esterof Maleic acid;DiMethyl Maleate, 96% 1LT;DiMethyl Maleate, 96% 250ML;Maleic Acid Dimethyl Ester Methyl Maleate;DiMethyl Maleat
CAS:624-48-6
MF:C6H8O4
MW:144.13
EINECS:210-848-5
Product Categories:Fatty Acid Esters (Plasticizer);Functional Materials;Plasticizer;C6 to C7;Carbonyl Compounds;Esters;bc0001;hnw00001
Mol File:624-48-6.mol
Dimethyl maleate Structure
Dimethyl maleate Chemical Properties
Melting point -19°C
Boiling point 204-205 °C(lit.)
density 1.152 g/mL at 25 °C(lit.)
vapor pressure 48Pa at 25℃
refractive index n20/D 1.441(lit.)
Fp 196 °F
storage temp. Sealed in dry,Room Temperature
solubility water: soluble77.9g/L at 20°C
form Liquid
color Clear
Odormild char. odor
Water Solubility Miscible with water.
BRN 471705
Stability:Stable. Combustible. Incompatible with acids, bases, reducing agents, strong oxidizing agents.
LogP0.52 at 35℃
CAS DataBase Reference624-48-6(CAS DataBase Reference)
NIST Chemistry Reference2-Butenedioic acid (Z)-, dimethyl ester(624-48-6)
EPA Substance Registry System2-Butenedioic acid (2Z)-, dimethyl ester (624-48-6)
Safety Information
Hazard Codes Xn,C
Risk Statements 21/22-36/37/38-43-37-34-22
Safety Statements 26-36/37-23-45-36/37/39
RIDADR UN 2810 6.1/PG 3
WGK Germany 1
RTECS EM6300000
TSCA Yes
HazardClass 6.1(b)
PackingGroup III
HS Code 29171990
MSDS Information
ProviderLanguage
Dimethyl maleate English
SigmaAldrich English
ACROS English
ALFA English
Dimethyl maleate Usage And Synthesis
Chemical Propertiescolourless liquid
UsesDimethyl maleate is acts as a dienophile involved in ultrasonic irradiation promoted Diels-Alder reaction with substituted furans. It is widely used as an intermediate and additive for pharmaceuticals, copolymers, pigments, plastics, paints, adhesives and agrochemicals. As an internal modifier, it increases the glass transition temperature of styrene or vinyl chloride polymer. It plays a vital role to improve the hardness and toughness of polymer films such as copolymers of vinyl acetate.
UsesDimethyl maleate is widely used in the plastics and chemical industries and as a vaporization retardant of insecticides.
DefinitionChEBI: Dimethyl maleate is a maleate ester resulting from the formal condensation of both carboxy groups of maleic acid with methanol. It is commonly used as a dienophile for Diels-Alder-type cycloaddition reactions in organic synthesis. It is a maleate ester, a diester and a methyl ester. It derives from a methanol.
PreparationDimethyl maleate can be synthesized from maleic anhydride and methanol, with sulfuric acid acting as acid catalyst, via a nucleophilic acyl substitution for the monomethyl ester, followed by a Fischer esterification reaction for the dimethyl ester.
General DescriptionDimethyl maleate (DMM) is a reactive dienophile and undergoes ultrasonic irradiation promoted Diels-Alder reaction with substituted furans. Mesoporous siliceous SBA-15-supported Cu catalyzed gas phase hydrogenolysis of DMM to 1,4-butanediol (BDO) has been reported. Aluminium chloride has been reported to accelerate the Diels-Alder reaction of DMM and anthracene. DMM can be synthesized by the esterification of maleic anhydride with sulfuric acid and methanol.
Flammability and ExplosibilityNon flammable
Tag:Dimethyl maleate(624-48-6) Related Product Information
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