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Cupric acetate monohydrate

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CAS:6046-93-1
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Products Intro: Product Name:Copper(II) acetate monohydrate
CAS:6046-93-1
Purity:99% Package:5KG;1KG Remarks:C4H8CuO5

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Cupric acetate monohydrate Basic information
Physical Properties Uses Preparation Toxicity
Product Name:Cupric acetate monohydrate
Synonyms:Aceticacid,copper(2+)salt,monohydrate;Aceticacidcopper(2+)salt,monohydrate;Copperdiacetatemonohydrate;Kupfer(II)-acetat-hydrat;VERDIGRIS;CUPRIC ACETATE 1-HYDRATE;CUPRIC ACETATE H2O;CUPRIC ACETATE, MONOHYDRATE
CAS:6046-93-1
MF:C4H8CuO5
MW:199.65
EINECS:611-978-9
Product Categories:metal acetate salt
Mol File:6046-93-1.mol
Cupric acetate monohydrate Structure
Cupric acetate monohydrate Chemical Properties
Melting point 115 °C
Boiling point 240 °C
density 1.88
vapor density 6.9 (vs air)
storage temp. Store at +5°C to +30°C.
solubility 72g/l
form Solid
color Dark Green
Specific Gravity1.882
PH5.2-5.5 (20g/l, H2O, 20℃)
OdorSlight acetic acid odor
PH Range5.2 - 5.5
Water Solubility 72 g/L (20 ºC)
Hydrolytic Sensitivity0: forms stable aqueous solutions
Merck 14,2624
BRN 3730548
Stability:Stable. Incompatible with oxidizing agents.
InChIKeyNWFNSTOSIVLCJA-UHFFFAOYSA-L
CAS DataBase Reference6046-93-1(CAS DataBase Reference)
Safety Information
Hazard Codes Xn,N,Xi,C
Risk Statements 22-36/37/38-50/53-34
Safety Statements 36/37/39-60-61-36-26-45
RIDADR UN 3077 9/PG 3
WGK Germany 3
RTECS AG3500000
TSCA Yes
HazardClass 9
PackingGroup III
HS Code 29152900
ToxicityLD50 orally in Rabbit: 501 mg/kg
MSDS Information
ProviderLanguage
Copper(II) acetate monohydrate English
SigmaAldrich English
ACROS English
ALFA English
Cupric acetate monohydrate Usage And Synthesis
Physical PropertiesBluish-green fine powder; hygroscopic. The monohydrate is dimeric; density 1.88 g/cm3; melts at 115°C; decomposes at 240°C; soluble in water and ethanol; and slightly soluble in ether.
UsesCopper(II) acetate is used as a pigment for ceramics; in the manufacture of Paris green; in textile dyeing; as a fungicide; and as a catalyst.
PreparationCopper(II) acetate is prepared by treatment of copper(II) oxide, CuO, or copper(II) carbonate, CuCO3, with acetic acid, followed by crystallization:
CuO + 2CH3COOH → (CH3COO)2Cu + H2O
ToxicityCopper(II) acetate is moderately toxic by ingestion and possibly other routes of administration.
LD50 oral (rat): c. 600 mg/kg
Chemical PropertiesDark green small crystal with odour of acetic acid
Chemical PropertiesCupric acetate is a greenish Blue powder or small crystals.
UsesCupric acetate monohydrate can be used in preparation of Fehling's reagent for sugars
PreparationCopper(II) acetate monohydrate can easily be produced by the reaction of acetic acid solutions with copper(II) carbonate or copper(II) hydroxide or by the reaction of copper(II) oxide with hot acetic acid. Large-scale commercial production uses copper metal in the presence of air and refluxing acetic acid.
Copper(II) acetate monohydrate is used as a catalyst in the polymerization of organic materials and as a mordant in the dying of textiles. It is also used as a ceramic pigment and as a fungicide.
Potential ExposureCupric acetate is used as a fungicide, as a catalyst for organic reactions; in textile dyeing and as a pigment for ceramics.
ShippingUN3077 Environmentally hazardous substances, solid, n.o.s., Hazard class: 9; Labels: 9-Miscellaneous hazardous material, Technical Name Required.
Purification MethodsRecystallise it twice from warm dilute acetic acid solutions (5mL/g) by cooling. [Beilstein 2 IV 111.]
IncompatibilitiesForms explosive materials with acetylene gas, ammonia, caustic solutions; sodium hypobromite; notromethane. Keep away from chemically active metals; strong acids; nitrates. Decomposes above 240C forming acetic acid fumes
Waste DisposalCopper-containing soluble wastes can be concentrated through the use of ion exchange, reverse osmosis, or evaporators to the point where copper can be electrolytically removed and sent to a reclaiming firm. If recovery is not feasible, the copper can be precipitated through the use of caustics and the sludge deposited in a chemical waste landfill.
Tag:Cupric acetate monohydrate(6046-93-1) Related Product Information
Copper(II) chloride dihydrate Copper sulfate monohydrate Acetic anhydride POLY(VINYL ACETATE) Chloroacetic acid Cupric acetate monohydrate Ammonium acetate COPPER(II) ACETATE,COPPER(II) ACETATE-1-HYDRATE,COPPER(II) ACETATE HYDRATE,COPPER (II) ACETATE, HYDROUS,CUPRIC ACETATE 1-HYDRATE,CUPRIC ACETATE H2O,CUPRIC ACETATE,ACETIC ACID, COPPER SALT Vinyl acetate Trichloroacetic acid ACETATE Glycine Ethyl acetate Cupric oxide CUPRIC ACETATE,Cupric acetate, anhydrous: (Copper acetate),COPPER(II) ACETATE,Copper(II) acetate, anhydrous, pure, 99%,Copper(II)acetate,anhydrous,min.97%,Copper(II) acetate, 99.999% (metals basis),Copper(ii) acetate, 99%, anhydrous, pure,Copper(II) acetate, anhydrous, min. 97%,Copper (II) acetate, anhydrous, ,COPPER(II) ACETATE, 99.999%,Copper(Ii)Acetate,>98% CELLULOSE ACETATE Copper Peroxyacetic acid