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3-METHYL-2-BUTANOL

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CAS:598-75-4
Purity:99% Package:25KG
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CAS:598-75-4
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3-METHYL-2-BUTANOL Basic information
Product Name:3-METHYL-2-BUTANOL
Synonyms:SEC-ISOAMYL ALCOHOL;(CH3)2CHCH(OH)CH3;(R,S)-3-Methyl-butan-2-ol;3-Methyl butan-2-ol;secondaryisoamylalcohol;(+/-)-3-METHYL-2-BUTANOL;3-METHYL-2-BUTANOL;2-HYDROXY-3-METHYLBUTANE
CAS:598-75-4
MF:C5H12O
MW:88.15
EINECS:209-950-2
Product Categories:
Mol File:598-75-4.mol
3-METHYL-2-BUTANOL Structure
3-METHYL-2-BUTANOL Chemical Properties
Melting point -51.44°C (estimate)
Boiling point 112 °C (lit.)
density 0.818 g/mL at 25 °C (lit.)
FEMA 3703 | 3-METHYL-2-BUTANOL
refractive index n20/D 1.409(lit.)
Fp 80 °F
storage temp. Flammables area
solubility 56g/l
form Liquid
pka15.17±0.20(Predicted)
color Clear colorless
Odorfruity
Odor Typefruity
explosive limit1.2-10.5%(V)
Water Solubility Miscible in Ether, Alcohols. Slightly soluble in water. (2.8g/100mL, 30°C)
Merck 14,6031
JECFA Number300
BRN 1718800
Exposure limitsNIOSH: IDLH 500 ppm; TWA 100 ppm(360 mg/m3); STEL 125 ppm(450 mg/m3)
LogP1.04
CAS DataBase Reference598-75-4(CAS DataBase Reference)
EPA Substance Registry System2-Butanol, 3-methyl- (598-75-4)
Safety Information
Hazard Codes Xn
Risk Statements 10-20-37-66
Safety Statements 46
RIDADR UN 1105 3/PG 3
WGK Germany 1
TSCA Yes
HazardClass 3
PackingGroup III
HS Code 29051490
MSDS Information
ProviderLanguage
ACROS English
SigmaAldrich English
ALFA English
3-METHYL-2-BUTANOL Usage And Synthesis
Chemical PropertiesAmyl alcohols (pentanols) have eight isomers. All are flammable, colorless liquids, except the isomer 2,2- dimethyl-1-propanol, which is a crystalline solid.
Chemical PropertiesCLEAR COLOURLESS LIQUID
Chemical Properties3-Methyl-2-butanol has a fruity, fresh odor.
UsesA flotation agent, a solvent, and in organic synthesis.
Uses3-Methyl-2-butanol has been used as a reference for microbially produced, volatile organic compounds (MVOC) in GC-MS analyses.
DefinitionChEBI: A secondary alcohol that is 2-butanol carrying an additional methyl substituent at position 3.
HazardModerately toxic.
Potential Exposure(n-isomer); Suspected reprotoxic hazard, Primary irritant (w/o allergic reaction), (iso-, primary): Possible risk of forming tumors, Primary irritant (w/o allergic reaction), (sec-, active primary-, and other isomers) Primary irritant (w/o allergic reaction). Used as a solvent in organic synthesis and synthetic flavoring, pharmaceuticals, corrosion inhibitors; making plastics and other chemicals; as a flotation agent. The (n-isomer) is used in preparation of oil additives, plasticizers, synthetic lubricants, and as a solvent.
ShippingUN2811 Pentanols, Hazard Class: 3; Labels: 3- Flammable liquid. UN1987 Alcohols, n.o.s., Hazard Class: 3; Labels: 3-Flammable liquid.
Purification MethodsReflux it with magnesium, then fractionally distil it. [Beilstein 1 IV 1675.]
IncompatibilitiesForms an explosive mixture with air. Contact with strong oxidizers and hydrogen trisulfide may cause fire and explosions. Incompatible with strong acids. Violent reaction with alkaline earth metals forming hydrogen, a flammable gas.
Waste DisposalDissolve or mix the material with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber. All federal, state, and local environmental regulations must be observed.
3-METHYL-2-BUTANOL Preparation Products And Raw materials
Raw materials2-Bromopropane
Preparation Products(S)-(+)-3-METHYL-2-BUTANOL-->Benzenamine, N-(1,2-dimethylpropyl)-4-methyl--->2-Butanol, 3-methyl-, 2-benzoate
Tag:3-METHYL-2-BUTANOL(598-75-4) Related Product Information
CYCLOPROPYL DIPHENYL CARBINOL 1-CYCLOHEXYL-1-PROPANOL 2-TERT-BUTYLCYCLOHEXANOL 2,2,4,4-TETRAMETHYL-1,3-CYCLOBUTANEDIOL DICYCLOHEXYLMETHANOL 1-Cyclohexylethanol ALPHA-CYCLOPROPYLBENZYL ALCOHOL 2,3-DIMETHYLCYCLOHEXANOL (-)-MENTHOXYACETIC ACID L-MENTHYL ACETATE TRANS-2-METHYLCYCLOPENTANOL 2-Methylcyclohexanol 1-CYCLOPROPYLETHANOL 2-METHYL-1-BUTANOL (R)-2-[3-(3-METHOXYPROPOXY)-4-METHOXYBENZYL]-3-METHYL-1-BUTANOL (R)-2-ISOPROPYLAMINO-2-PHENYLETHANOL (S)-2-Benzyloxymethyl-3-methylbutan-1-ol 1-METHYL-1-BUTANOL