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Tosylmethyl isocyanide

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Company Name: Capot Chemical Co.,Ltd.
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Products Intro: Product Name:Tosylmethyl isocyanide
CAS:36635-61-7
Purity:99%(Min,HPLC) Package:100g;1kg;5kg,10kg,25kg,50kg
Company Name: Henan DaKen Chemical CO.,LTD.
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Products Intro: Product Name:Tosylmethyl isocyanide
CAS:36635-61-7
Purity:99.00% Package:100g,500g,1KG,10KG,100KG
Company Name: Henan Tianfu Chemical Co.,Ltd.
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Products Intro: CAS:36635-61-7
Purity:99% Package:500G;1KG;5KG;25KG
Company Name: Mainchem Co., Ltd.
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Products Intro: Product Name:Tosylmethyl isocyanide
CAS:36635-61-7
Company Name: career henan chemical co
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Products Intro: Product Name:Tosylmethyl isocyanide
CAS:36635-61-7
Purity:99% Package:1kg;1USD

Lastest Price from Tosylmethyl isocyanide manufacturers

  • Tosylmethyl isocyanide
  • US $1.00 / kg
  • 2018-12-17
  • CAS:36635-61-7
  • Min. Order: 1kg
  • Purity: 99%
  • Supply Ability: Customized
Tosylmethyl isocyanide Basic information
Product Name:Tosylmethyl isocyanide
Synonyms:1-[(isocyanomethyl)sulfonyl]-4-methyl-benzen;(p-Tolylsulfonyl)methyl isocyanide, TosMIC, Tosylmethyl isocyanide;(4-Methylphenylsulfonylmethyl) isocyanide;4-Methylphenylsulfonylmethyl isocyanide;Tosylmethyl isocyanide,98%;p-Toluenesulfonyl Isocyanide;P-tolysulfonylmethylisocyanide;Tosylmethy isocyanide ,98%
CAS:36635-61-7
MF:C9H9NO2S
MW:195.24
EINECS:253-140-1
Product Categories:Aliphatics;Sulfur Compounds (for Synthesis);Synthetic Organic Chemistry;Tosmic;Tesaglitazar Carbjdopa;Building Blocks;Chemical Synthesis;Isocyanides;Nitrogen Compounds;Organic Building Blocks;cyanide;Benzene derivatives;Boron, Nitrile, Thio,& TM-Cpds
Mol File:36635-61-7.mol
Tosylmethyl isocyanide Structure
Tosylmethyl isocyanide Chemical Properties
Melting point 109-113 °C(lit.)
density 1.2721 (rough estimate)
refractive index 1.5270 (estimate)
storage temp. -20°C
solubility water: slightly soluble
form Liquid
color Clear
Water Solubility insoluble
Sensitive Moisture Sensitive
Merck 14,9556
BRN 3592382
CAS DataBase Reference36635-61-7(CAS DataBase Reference)
Safety Information
Hazard Codes T,Xi
Risk Statements 23/24/25
Safety Statements 36/37-45-38-36/37/39-28A
RIDADR UN 2811 6.1/PG 3
WGK Germany 3
21
Hazard Note Irritant
HazardClass 6.1(b)
PackingGroup III
HS Code 29299000
MSDS Information
ProviderLanguage
(p-Tolylsulfonyl)methyl isocyanide English
SigmaAldrich English
ACROS English
ALFA English
Tosylmethyl isocyanide Usage And Synthesis
Chemical PropertiesPale yellow to light brown crystalline powder
UsesReagent for use in the preparation of biologically active pyrroles and imidazoles.1,2
UsesTosylmethyl Isocyanide is used as a synthetic reagent in the preparation of variety or biologically active heterocycles such as pyrroles and imidazoles. Tosylmethyl Isocyanide is reported to inhibit [ Fe]-hydrogenase with very high affinity.
UsesVersatile synthon in organic chemistry, especially in the synthesis of heterocyclic Compounds.
Purification MethodsUse an efficient fume cupboard. Purify TOSMIC by dissolving (50g) in CH2Cl2 (150mL) and passing it through a column (40x3cm) containing neutral alumina (100g) in CH2Cl2 and eluting with CH2Cl2. A nearly colourless solution (700mL) is collected, evaporated in vacuo and the residue (42-47g) of TOSMIC (m 113-114o dec) is recrystallised once from MeOH (m 116-117o dec). [Hoogenboom et al. Org Synth 57 102 1977, Lensen Tetrahedron Lett 2367 1972.] It also crystallises from EtOH (charcoal) [Saito & Itano, J Chem Soc, Perkin Trans 1 1 1986].
Tosylmethyl isocyanide Preparation Products And Raw materials
Preparation ProductsMETHYL-2-CHLOROOXAZOLE-5-CARBOXYLATE-->3-(3,4-DIHYDROXYPHENYL)PROPIONIC ACID
Tag:Tosylmethyl isocyanide(36635-61-7) Related Product Information
Paraquat dichloride Ammonium dihydrogen phosphate Tosyl cyanide Acetonitrile Methanol p-Tolunitrile Methyl Sulfosulfuron Kresoxim-methyl Basic Violet 1 Ammonium acetate Ammonium carbonate Ammonium nitrate Methylparaben Methyl acrylate Molybdic acid Methyl bromide Ammonium sulfate