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2-Methyleneglutaronitrile

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Products Intro: Product Name:2-Methyleneglutaronitrile
CAS:1572-52-7
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Products Intro: Product Name:2-Methyleneglutaronitrile
CAS:1572-52-7
Purity:0.98 Package:1KG;10KG;50KG
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CAS:1572-52-7
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Products Intro: Product Name:2-Methyleneglutaronitrile
CAS:1572-52-7
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Products Intro: Product Name:2-methyleneglutaronitrile
CAS:1572-52-7
Purity:99% Package:1kg

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2-Methyleneglutaronitrile Basic information
Product Name:2-Methyleneglutaronitrile
Synonyms:3-Butene-1,3-dicarbonitrile;Methyleneglutarodinitrile (MGN);2-METHYLENEGLUTARONITRILE 95%;acrylonitrile dimer;2,4-Dicyanobutene-1;2-Methyleneglutarodinitrile;2-methylene-pentanedinitril;alpha-Methyleneglutarodinitrile
CAS:1572-52-7
MF:C6H6N2
MW:106.13
EINECS:216-391-8
Product Categories:C6 to C7;Cyanides/Nitriles;Nitrogen Compounds
Mol File:1572-52-7.mol
2-Methyleneglutaronitrile Structure
2-Methyleneglutaronitrile Chemical Properties
Melting point −9.6 °C(lit.)
Boiling point 254 °C(lit.)
density 0.976 g/mL at 25 °C(lit.)
refractive index n20/D 1.456(lit.)
Fp >230 °F
storage temp. Sealed in dry,Room Temperature
CAS DataBase Reference1572-52-7(CAS DataBase Reference)
NIST Chemistry ReferencePentanedinitrile, 2-methylene-(1572-52-7)
EPA Substance Registry SystemPentanedinitrile, 2-methylene- (1572-52-7)
Safety Information
Hazard Codes Xn
Risk Statements 20/21/22
Safety Statements 36
RIDADR UN 3276 6.1/PG 3
WGK Germany 3
HazardClass 6.1
PackingGroup III
HS Code 2926907090
MSDS Information
ProviderLanguage
SigmaAldrich English
2-Methyleneglutaronitrile Usage And Synthesis
Description2-Methyleneglutaronitrile [1572-52-7], acrylonitrile dimer, 2,4-dicyano-1-butene, 2- methylenepentanedinitrile, NCC2H4C (=CH2) CN, is a colorless liquid slightly miscible with water, ethanol, acetone and benzene, immiscible with hexane.
Chemical PropertiesColorless liquid.Slightly soluble in water; insoluble in aliphatic andalicyclic hydrocarbons, soluble in aromatic hydro-carbons and polar organic solvents.
UsesVinyl monomer for polymerization and copoly-merization, intermediate in making fibers and phar-maceuticals.
Synthesis Reference(s)Tetrahedron Letters, 28, p. 4591, 1987 DOI: 10.1016/S0040-4039(00)96573-0
Synthesis2-Methyleneglutaronitrile is obtained by dimerization of acrylonitrile in the presence of a metal halide and a tertiary amine. Its hydrogenation yields 2-methylglutaronitrile, which in turn can be converted into 3-methylpyridine.
2-Methyleneglutaronitrile Preparation Products And Raw materials
Preparation ProductsDBDCB-->1,3,5-PENTANETRICARBONITRILE-->1,4-DICYANO-2-BUTENE
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