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Nickel(II) acetate tetrahydrate

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Products Intro: Product Name:Nickel(II) acetate tetrahydrate
Purity:98%min Package:25kgs drum
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Products Intro: Product Name:Nickel(II) acetate tetrahydrate
Purity:AR,98% Package:250g
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Products Intro: CAS:6018-89-9
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Purity:99% Package:5KG;1KG Remarks:C4H14NiO8
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Products Intro: Product Name:Nickel(II) acetate tetrahydrate

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Nickel(II) acetate tetrahydrate Basic information
Physical Properties Uses Preparation
Product Name:Nickel(II) acetate tetrahydrate
Synonyms:Nickel(II)acetatehydrate,99+%;Nickel(II)acetatetetrahydrate,98+%;NICKEL(II) ACETATE 4 H2O;Nickel(II) acetate tetrahydrate, extra pure, 99%;Nickel(II) acetate tetrahydrate, for analysis, 99+%;NICKEL ACETATE, TETRAHYDRATE REAGENT;Nickel(II)acetatetetrahydrate(99.999%-Ni)PURATREM;nickel(ii) acetate tetrahydrate, puratronic
Product Categories:metal acetate salt;Nickel Salts;Catalysis and Inorganic Chemistry;Chemical Synthesis;Materials Science;Metal and Ceramic Science;Nickel;Salts;nickel , acetate;Imidazoles
Mol File:6018-89-9.mol
Nickel(II) acetate tetrahydrate Structure
Nickel(II) acetate tetrahydrate Chemical Properties
Melting point °Cd ec.)
Boiling point 16℃
density 1.798 g/mL at 25 °C(lit.)
form Solid
color White to off-white
Specific Gravity1.798
Water Solubility 182 g/L (20 ºC)
Sensitive Hygroscopic
Hydrolytic Sensitivity0: forms stable aqueous solutions
Merck 14,6499
BRN 3730764
CAS DataBase Reference6018-89-9(CAS DataBase Reference)
EPA Substance Registry SystemNickel diacetate tetrahydrate (6018-89-9)
Safety Information
Hazard Codes T,Xn,N
Risk Statements 45-22-43-40-68-50/53-48/23-42/43-20/22-61-49
Safety Statements 53-36/37-45-24-22-61-60
WGK Germany 3
RTECS QR6126000
HazardClass 9
PackingGroup III
HS Code 29152990
MSDS Information
Acetic acid nickel(II) salt English
ACROS English
SigmaAldrich English
ALFA English
Nickel(II) acetate tetrahydrate Usage And Synthesis
Physical PropertiesThe tetrahydrate is a green crystalline solid; sweet taste; odor of acetic acid; density 1.744 g/cm3; loses water on heating to form a yellow-green powder of anhydrous nickel acetate; decomposes above 250°C; soluble in water, 17g/100mL at 20°C; sparingly soluble in alcohol.
UsesNickel acetate is used as a catalyst. It also is used as a dye mordant in textiles. Other applications are in electroplating nickel and as a sealer for anodizing aluminum.
PreparationNickel acetate is prepared by reacting nickel hydroxide or nickel carbonate with dilute acetic acid. The tetrahydrate is crystallized from solution.
Ni(OH)2 + 2CH3COOH → (CH3COO)2Ni + 2H2O
NiCO3 + 2CH3COOH → (CH3COO)2Ni + CO2 + 2H2O
On heating, the solution hydrolyzes depositing nickel hydroxide.
Chemical Propertiesgreen monoclinic crystal(s); hygroscopic; used in textiles as a mordant [HAW93]
UsesNickel(II) acetate tetrahydrate can be used in synthesis of polynuclear-nickel polyoxotungstate cluster compounds that are ideal for the design of molecular magnets.
Safety ProfileConfirmed human carcinogen. Poison by ingestion and intraperitoneal routes. Mutation data reported. When heated to decomposition it emits acrid smoke and irritating fumes. See also NICKEL(II) ACETATE and NICKEL COMPOUNDS.
Purification MethodsThe acetate crystallises from aqueous AcOH as the green tetrahydrate salt. It is soluble in 6 parts of H2O. It forms lower hydrates and should be kept in a well-sealed container. [Hardt & Pohlmann Z Anorg Allgem Chem 343 92 1966, Beilstein 2 IV 120.]
Nickel(II) acetate tetrahydrate Preparation Products And Raw materials
Raw materialsAcetic acid-->Sodium carbonate-->Hydrofluoric acid-->Nickel sulfate-->Nickel carbonate-->NICKEL(II) CARBONATE BASIC HYDRATE
Preparation Products6,6'-Dimethyl-2,2'-dipyridyl-->5,5'-DIMETHYL-2,2'-DIPYRIDYL
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