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| Product Name: | Nickel(II) acetate tetrahydrate | | Synonyms: | Nickel(II)acetatehydrate,99+%;Nickel(II)acetatetetrahydrate,98+%;NICKEL(II) ACETATE 4 H2O;Nickel(II) acetate tetrahydrate, for analysis, 99+%;NICKEL ACETATE, TETRAHYDRATE REAGENT;Nickel(II)acetatetetrahydrate(99.999%-Ni)PURATREM;nickel(ii) acetate tetrahydrate, puratronic;NICKELACETATE,TETRAHYDRATE,CRYSTAL,REAGENT | | CAS: | 6018-89-9 | | MF: | C4H14NiO8 | | MW: | 248.84 | | EINECS: | 611-946-4 | | Product Categories: | nickel , acetate;Imidazoles;Catalysis and Inorganic Chemistry;Chemical Synthesis;Materials Science;Metal and Ceramic Science;Nickel;Salts;metal acetate salt;Nickel Salts | | Mol File: | 6018-89-9.mol |  |
| | Nickel(II) acetate tetrahydrate Chemical Properties |
| Melting point | °Cd ec.) | | Boiling point | 16℃ | | density | 1.798 g/mL at 25 °C(lit.) | | storage temp. | Inert atmosphere,Room Temperature | | solubility | soluble in H2O, ethanol | | form | Solid | | Specific Gravity | 1.798 | | color | White to off-white | | Water Solubility | 182 g/L (20 ºC) | | Sensitive | Hygroscopic | | Hydrolytic Sensitivity | 0: forms stable aqueous solutions | | Merck | 14,6499 | | BRN | 3730764 | | Exposure limits | NIOSH: IDLH 10 mg/m3; TWA 0.015 mg/m3 | | Stability: | Stable. | | CAS DataBase Reference | 6018-89-9(CAS DataBase Reference) | | EPA Substance Registry System | Nickel diacetate tetrahydrate (6018-89-9) |
| | Nickel(II) acetate tetrahydrate Usage And Synthesis |
| Physical Properties | The tetrahydrate is a green crystalline solid; sweet taste; odor of acetic acid; density 1.744 g/cm3; loses water on heating to form a yellow-green powder of anhydrous nickel acetate; decomposes above 250°C; soluble in water, 17g/100mL at 20°C; sparingly soluble in alcohol.
| | Uses | Nickel acetate is used as a catalyst. It also is used as a dye mordant in textiles. Other applications are in electroplating nickel and as a sealer for anodizing aluminum.
| | Preparation | Nickel acetate is prepared by reacting nickel hydroxide or nickel carbonate with dilute acetic acid. The tetrahydrate is crystallized from solution.
Ni(OH)2 + 2CH3COOH → (CH3COO)2Ni + 2H2O
NiCO3 + 2CH3COOH → (CH3COO)2Ni + CO2 + 2H2O
On heating, the solution hydrolyzes depositing nickel hydroxide.
| | Chemical Properties | green monoclinic crystal(s); hygroscopic; used in textiles as a mordant [HAW93] | | Uses | Nickel(II) acetate tetrahydrate can be used in synthesis of polynuclear-nickel polyoxotungstate cluster compounds that are ideal for the design of molecular magnets. | | Uses | Nickel(II) Acetate Tetrahydrate is a reactant in the synthesis of metalloprophyrazines as active components of membranes of anion-selective electrodes. | | Safety Profile | Confirmed human
carcinogen. Poison by ingestion and
intraperitoneal routes. Mutation data
reported. When heated to decomposition it
emits acrid smoke and irritating fumes. See
also NICKEL(II) ACETATE and NICKEL
COMPOUNDS. | | Purification Methods | The acetate crystallises from aqueous AcOH as the green tetrahydrate salt. It is soluble in 6 parts of H2O. It forms lower hydrates and should be kept in a well-sealed container. [Hardt & Pohlmann Z Anorg Allgem Chem 343 92 1966, Beilstein 2 IV 120.] |
| | Nickel(II) acetate tetrahydrate Preparation Products And Raw materials |
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