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Ammonium hexafluorophosphate

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CAS:16941-11-0
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CAS:16941-11-0
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Ammonium hexafluorophosphate Basic information
Description Reference
Product Name:Ammonium hexafluorophosphate
Synonyms:AMMONIUM HEXAFLUOROPHOSPHATE: 99.5%;Azanium hexafluorophosphate;Ammonium hexafluorophosphate, 99.5%, extra pure;Ammonium hexafluorophosphate, extra pure;AMMONIUM HEXAFLUOROPHOSPHATE, NH4PF6;Ammonium hexafluorop;Ammonium hexafluorophosphate ,99.4% [extra pure];Ammonium hexafluorophosphate - 98.5%
CAS:16941-11-0
MF:F6H4NP
MW:163
EINECS:241-009-1
Product Categories:Industrial/Fine Chemicals;Ammonium Salts;AmmoniumMetal and Ceramic Science;Inorganic Salts;Salts;Synthetic Reagents;metal fluorophosphate complex;Ammonium;Ammonium Salts;Chemical Synthesis;Inorganic Salts;Materials Science;Metal and Ceramic Science;Synthetic Reagents;-;Preservative
Mol File:16941-11-0.mol
Ammonium hexafluorophosphate Structure
Ammonium hexafluorophosphate Chemical Properties
Melting point 198 °C
density 2.18 g/mL at 25 °C(lit.)
solubility H2O: 50 mg/mL, clear, colorless
form Crystalline Powder or Needles
Specific Gravity2.180
color White to beige
Water Solubility 74.8 g/100 mL (20 ºC)
Sensitive Hygroscopic
Merck 14,526
Stability:Stable. Incompatible with strong acids. Hygroscopic. Combustion may generate hydrogen fluoride, phosphorus oxides, phosphine or ammonia.
CAS DataBase Reference16941-11-0(CAS DataBase Reference)
EPA Substance Registry SystemPhosphate(1-), hexafluoro-, ammonium(16941-11-0)
Safety Information
Hazard Codes C
Risk Statements 34
Safety Statements 26-36/37/39-45
RIDADR UN 3260 8/PG 2
WGK Germany 3
3
Hazard Note Corrosive/Hygroscopic
TSCA T
HazardClass 8
PackingGroup III
HS Code 28269090
MSDS Information
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Ammonium hexafluorophosphate Usage And Synthesis
Description

Ammonium hexafluorophophate can be used to for the synthesis of non-aqueous polymer gel electrolytes based on polyethylene oxide (PEO), which show high conductivity above 10-2 S/cm at 25°C.1 It can be used to prepare other hexafluorophosphate.2 It is also used for the synthesis of ruthenium and palladium complexes.3

Reference
  • J. P. Sharma, S. S. Sekhon, Highly conductive non aqueous polymer gel electrolytes containing ammonium hexafluorophosphate (NH4PF6), Journal of Materials Science, 2006, vol. 41, pp. 3617-3622
  • C. Hiort, P. Lincoln, B. Norden, DAN binding of .DELTA.and .LAMBDA.-[Ru(phen)2DPPZ]2+, Journal of the American Chemical Society, 1993, vol. 115, pp. 3448-3454
  • D. Schmollinger, J. Kraft, C. Ewald, T. Ziegler, Synthesis of ruthenium and palladium complexes from glycosylated 2,2′-bipyridine and terpyridine ligands, 2017, vol. 58, pp. 3643-3645
Chemical Propertiesoff-white powder
Purification MethodsIt crystallises from H2O in square plates and decomposes on heating before melting. Its solublility in H2O at 20o is 74.8% w/v, and it is very soluble in Me2CO, MeOH, EtOH and MeOAc but is decomposed by boiling mineral acids. [Lange & Müller Chem Ber 63 1063 1930, Kwasnik in Handbook of Preparative Inorganic Chemistry (Ed. Brauer) Academic Press Vol I p 195 1963.]
Ammonium hexafluorophosphate Preparation Products And Raw materials
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BENZYLTRIMETHYLAMMONIUM HEXAFLUOROPHOSPHATE TETRAMETHYLAMMONIUM HEXAFLUOROPHOSPHATE MORPHOLINIUM HEXAFLUOROPHOSPHATE 4-NITROBENZENEDIAZONIUM HEXAFLUOROPHOSPHATE TRIMETHYLPHENYLAMMONIUM HEXAFLUOROPHOSPHATE 4-CHLOROBENZENEDIAZONIUM HEXAFLUOROPHOSPHATE PHENYLDIAZONIUM HEXAFLUOROPHOSPHATE HBTU DI-2-ETHYLHEXYLAMMONIUM HEXAFLUOROPHOSPHATE TETRAPROPYLAMMONIUM HEXAFLUOROPHOSPHATE Ammonium hexafluorophosphate Ammonium sulfate TRI-AMMONIUM ORTHOPHOSPHATE Molybdic acid Hexafluorophosphate Ammonium carbonate Ammonium acetate Ammonium chloride