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Lead acetate trihydrate

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CAS:6080-56-4
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Lead acetate trihydrate Basic information
Product Name:Lead acetate trihydrate
Synonyms:PLATINIZING SOLUTION;PLATINIZING SOLUTION, ASTM;Lead(Ⅱ) acetate trihydrate;LEAD(II) ACETATE TRIHYDRATE, REAGENTPLUS , 99.99+%;LEAD ACETATE-3-HYDRATE R. G., REAG. ACS, REAG. ISO, REAG;LEAD ACETATE TRIHYDRATE ACS REAGENT;Lead(II) acetate trihydrate, 99.999% metals basis;LEAD(II) ACETATE TRIHYDRATE, ACS
CAS:6080-56-4
MF:C4H12O7Pb
MW:379.33
EINECS:612-031-2
Product Categories:ACS GradeChemical Synthesis;Essential Chemicals;Routine Reagents;Analytical Reagents for General Use;E-L, Puriss p.a. ACS;Puriss p.a. ACS;Catalysis and Inorganic Chemistry;Chemical Synthesis;Lead;Lead Salts;Materials Science;Metal and Ceramic Science;Salts;Solution Deposition Precursors;metal acetate salt;Micro/Nanoelectronics;Solution Deposition Precursors;6080-56-4
Mol File:6080-56-4.mol
Lead acetate trihydrate Structure
Lead acetate trihydrate Chemical Properties
Melting point 75 °C (dec.)(lit.)
Boiling point 280°C
density 2,55 g/cm3
storage temp. 2-8°C
solubility 443g/l
form Solid
Specific Gravity2.55
color White or colorless, efflorescent
PH5.5-6.5 (50g/l, H2O, 20℃)
Water Solubility 625 g/L
Hydrolytic Sensitivity0: forms stable aqueous solutions
Merck 14,5397
BRN 3730298
Exposure limitsNIOSH: IDLH 100 mg/m3; TWA 0.050 mg/m3
InChIKeyDYRQFRHCGBQJII-UHFFFAOYSA-M
CAS DataBase Reference6080-56-4(CAS DataBase Reference)
EPA Substance Registry SystemLead(II) acetate trihydrate (6080-56-4)
Safety Information
Hazard Codes T,N
Risk Statements 61-33-48/22-50/53-62
Safety Statements 53-45-60-61
RIDADR UN 1616 6.1/PG 3
WGK Germany 2
RTECS OF8050000
TSCA Yes
HazardClass 6.1
PackingGroup III
HS Code 29152900
ToxicityLD50 orally in Rabbit: 4665 mg/kg
MSDS Information
ProviderLanguage
Lead(II) acetate trihydrate English
Lead acetate trihydrate Usage And Synthesis
Chemical PropertiesLead acetate trihydrate, also known as plumbous acetate trihydrate, has the chemical formula Pb(C2H3O2)2·3H2O. It appears as a white, monoclinic crystalline solid. Upon heating it loses some of its water of crystallization, and after melting, decomposes at 200 °C. The trihydrate is highly soluble in water but insoluble in ethyl alcohol. It has an intensely sweet taste, hence it is sometimes called sugar of lead, but it is poisonous. The trihydrate is made by dissolving lead monoxide in hot dilute acetic acid solution; on cooling, large crystals separate, sometimes up to 60-cm long.
UsesLead(II) acetate trihydrate is used as a mordant in textile printing and dyeing, drier in paints, varnishes and as a water repellant. It is also used in cosmetics and to prepare other lead compounds. It serves as an ingredient in progressive types of hair coloring dyes. Further, it is used in the detection of poisonous gas hydrogen sulfide.
UsesLead acetate trihydrate, the usual commercial form, is used in the preparation of basic lead carbonate and lead chromate, as a mordant in cotton dyes, as a reagent for the manufacture of lead salts of higher fatty acids, as a water repellant, as a component in combined toning and fixing baths for daylight printing papers, and as a means of treating awnings and outdoor furniture to prevent removal of mildew- and rotproofing agents by rain or laundering. Other uses include preparation of rubber antioxidants; processing agent in the cosmetic, perfume, and toiletry industries; component of coloring agents for adhesives; and preparation of organic lead soaps as driers of paints and inks.
ApplicationLead(II) acetate trihydrate was a component of the solution which was used towards the fabrication of platinum black microelectrodes. Lead acetate trihydrate may be used in the manufacturing of other lead salts. It may be used in the textile industry for dyeing and printing. In paint industry, lead acetate acts as a drying agent and as a purification agent in chemical synthesis.
General DescriptionLead acetate trihydrate appears as white powder or white chunky solid. Slight odor. pH (5% aqueous solution at 77°F) 5.5-6.5. It is water soluble and stable under normal conditions.
Air & Water ReactionsSlowly effloresces in air. Water soluble but solutions absorb carbon dioxide from the air and to give incompletely soluble products.
Reactivity ProfileLead acetate trihydrate may react with acids and oxidizing agents. Is incompatible with sulfates, citrates, tartrates, chlorides, carbonates, alkalis, tannin, resorcinol, salicylic acid, phenol, chloral hydrate, sulfites, vegetable infusions and tinctures. Incompatible with phosphates . Incompatible with KBrO3 and with EDTA.
Fire HazardLiterature sources indicate that Lead acetate trihydrate is nonflammable.
Purification MethodsCrystallise it twice from anhydrous acetic acid and dry it under vacuum for 24hours at 100o. The solubility in H2O is 63% (at ~20o) and 200% (at boiling point). [Beilstein 2 IV 118.]
Tag:Lead acetate trihydrate(6080-56-4) Related Product Information
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