Phenylselenenyl chloride manufacturers
- PHENYLSELENENYL CHLORIDE
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- $2.00 / 1KG
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2020-01-08
- CAS:5707-04-0
- Min. Order: 1KG
- Purity: 98%
- Supply Ability: 100g , 1kg, 5kg , 50kg
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| Phenylselenenyl chloride Basic information |
| Phenylselenenyl chloride Chemical Properties |
Melting point | 59-62 °C (lit.) | Boiling point | 120 °C/20 mmHg (lit.) | Fp | 120°C/20mm | storage temp. | Store below +30°C. | solubility | Soluble in methanol. | form | crystal | color | red | Sensitive | Moisture Sensitive | Hydrolytic Sensitivity | 7: reacts slowly with moisture/water | BRN | 1237091 | Exposure limits | ACGIH: TWA 0.2 mg/m3 NIOSH: IDLH 1 mg/m3; TWA 0.2 mg/m3 | Stability: | Stable, but may be air or moisture sensitive. Incompatible with strong bases, strong oxidizing agents. | InChI | InChI=1S/C6H5ClSe/c7-8-6-4-2-1-3-5-6/h1-5H | InChIKey | WJCXADMLESSGRI-UHFFFAOYSA-N | SMILES | C1([Se]Cl)=CC=CC=C1 | CAS DataBase Reference | 5707-04-0(CAS DataBase Reference) |
| Phenylselenenyl chloride Usage And Synthesis |
Chemical Properties | crystalline solid | Uses | Phenylselenenyl chloride is used in the preparation of (cyclobut-1-enylselanyl)benzene. It is an important versatile reagent used in organic synthesis. Further, it serves as a useful synthon for 2-amino alcohols. | Application | Phenylselenenyl chloride as a reagent for the facile preparation of cyclic ethers from diolefins[1]. | General Description | Phenylselenyl chloride is a synthon for 2-amino alcohols. It is a versatile reagent in organic synthesis. | Purification Methods | Purify it by distillation in a vacuum, and recrystallisation (orange needles) from hexane [Foster J Am Chem Soc 55 822 1933, Foster et al. Recl Trav Chim, Pays-Bas 53 405, 408 1934, Behaghel & Seibert Chem Ber 66 714 1933]. [Beilstein 6 III 1110.] HIGHLY TOXIC. | References | [1] S. Uemura. “Phenylselenenyl chloride as a reagent for the facile preparation of cyclic ethers from diolefins.” Tetrahedron Letters 21 1 (1980): 1533–1536.
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| Phenylselenenyl chloride Preparation Products And Raw materials |
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