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| | (1R,2S,5R)-(-)-MENTHYL (S)-P-TOLUENESULFINATE Basic information |
| Product Name: | (1R,2S,5R)-(-)-MENTHYL (S)-P-TOLUENESULFINATE | | Synonyms: | (S)-(-)-Menthyl p-toluenesulfinate, (-)-(1R)-Menthyl (S)-p-toluenesulfinate;4-Methylbenzenesulfinic acid (1R)-2α-isopropyl-5β-methylcyclohexane-1β-yl ester;4-Methylbenzenesulfinic acid (1R,3R,4S)-p-menthane-3-yl ester;p-Toluenesulfinic acid (1R,1β)-2α-isopropyl-5β-methylcyclohexyl ester;p-Toluenesulfinic acid (1R,2S,5R)-2-isopropyl-5-methylcyclohexyl ester;p-Toluenesulfinic acid (1R,3R,4S)-menthyl ester;p-Toluenesulfinic acid (1R,3R,4S)-p-menthane-3-yl ester;(1R,2S,5R)-(-)-Menthyl (S)-p-toluenesulfinate,98% | | CAS: | 1517-82-4 | | MF: | C17H26O2S | | MW: | 294.45 | | EINECS: | | | Product Categories: | Chiral Building Blocks;Organic Building Blocks;Sulfonates/Sulfinates;chiral;Asymmetric Synthesis;Biochemistry;Monocyclic Monoterpenes;Synthetic Organic Chemistry;Terpenes | | Mol File: | 1517-82-4.mol |  |
| | (1R,2S,5R)-(-)-MENTHYL (S)-P-TOLUENESULFINATE Chemical Properties |
| Melting point | 99-104 °C | | Boiling point | 402.3±38.0 °C(Predicted) | | density | 1.08 | | refractive index | -199 ° (C=1.5, Acetone) | | storage temp. | -20°C | | solubility | Acetone (Slightly), Chloroform (Slightly) | | form | Solution | | color | Yellow to brown or gray | | optical activity | [α]20/D 195°, c = 2 in acetone | | BRN | 3207468 |
| Safety Statements | 22-24/25 | | WGK Germany | 3 | | HS Code | 29309090 |
| | (1R,2S,5R)-(-)-MENTHYL (S)-P-TOLUENESULFINATE Usage And Synthesis |
| Chemical Properties | White crystalline powder | | Uses | (1R,2S,5R)-(-)-Menthyl (S)-p-toluenesulfinate can react with:
- metal ketimines to form enantiopure sulfinimines
- p-(methylthio)benzaldehyde to form (S)-(-)-N-(4-methylthiobenzylidene)-p-toluenesulfinimine
| | Uses | (1R,2S,5R)-(-)-Menthyl (S)-p-Toluenesulfinate is a reactant used in the synthesis of sulfoxide pincer complexes of Mg, Rh and Ir. | | General Description | (1R,2S,5R)-(-)-Menthyl (S)-p-toluenesulfinate is mainly used for the introduction of p-toluenesulfinyl group in asymmetric synthesis. |
| | (1R,2S,5R)-(-)-MENTHYL (S)-P-TOLUENESULFINATE Preparation Products And Raw materials |
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