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Magnesium carbonate

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Magnesium carbonate Basic information
Description Chemical Properties Magnesium Compounds Occurrence and Uses
Product Name:Magnesium carbonate
Synonyms:carbonicacid,magnesiumsalt;Carbonicacid,magnesiumsalt(1:1);ci77713;DCI Light Magnesium Carbonate;dcilightmagnesiumcarbonate;barringtonite;C.I. 77713;c.i.77713
CAS:546-93-0
MF:CMgO3
MW:84.31
EINECS:208-915-9
Product Categories:Pharmacopoeia (USP);Pharmacopoeia A-ZPharmacopoeia (USP);Pharmacopoeial OrganicsEssential Chemicals;Routine Reagents;USP;Inorganics;546-93-0
Mol File:546-93-0.mol
Magnesium carbonate Structure
Magnesium carbonate Chemical Properties
Melting point 990°C
density 3.050
solubility Practically insoluble in water. It dissolves in dilute acids with effervescence.
form Solid
color White
Odorat 100.00?%. odorless
Water Solubility g MgCO3/100g solution at CO2 pressure, kPa, 18°C: 3.5 (203), 4.28 (405), 5.90 (1010), 7.49 (1820), 7.49 (5670); at 0°C 8.58 (3445), at 60°C 5.56 (3445); soluble acids; insoluble alcohol [HAW93] [KIR81]
Stability:Hygroscopic
LogP-0.809 (est)
CAS DataBase Reference546-93-0(CAS DataBase Reference)
NIST Chemistry ReferenceMagnesium carbonate(546-93-0)
EPA Substance Registry SystemMagnesium carbonate (546-93-0)
Safety Information
Safety Statements 24/25-22
RTECS OM2470000
HS Code 28369910
Hazardous Substances Data546-93-0(Hazardous Substances Data)
MSDS Information
ProviderLanguage
ACROS English
Magnesium carbonate Usage And Synthesis
DescriptionMagnesium carbonate (MgCO3, pKso=7.5-8.2), another important compound of magnesium, occurs naturally as magnesite,but the magnesium carbonate used in the United States is all synthetically manufactured. It's used in the pharmaceutical industry as an inert material: whenever you take a tablet, chances are, you're also taking magnesium carbonate. Its used as an inert binder to hold the actual particles of the drug together.It's also used in cosmetics, talcum powders, and the manufacture of soap because it can hold and carry a scent very effectively.
Magnesium carbonate is added to rubber and plastics as a flame retardant: it reduces the rate at which fire spreads and the amount of char and ash that is produced.
Chemical PropertiesMagnesium carbonate is a white, yellowish, grayish-white or brown crystalline solid or crystalline powder. It occurs in nature as the mineral magnesite and is an important source of elemental magnesium. It can be produced artificially by the action of carbon dioxide on a variety of magnesium compounds.
Magnesium carbonate
Magnesium carbonate is a flux. It can be used to make matte, but too much can cause pinholes. Cobalt will produce violet hues when combined with magnesium carbonate, and pink shades when combined with zinc.
Magnesium carbonates can be used as magnesium source for the manufacture of catalyst compounds.
Magnesium CompoundsCompound                 Mineral                Formula                     CAS No.
anhydrous salt             magnesite              MgCO3                       [13717-00-5]
dihydrate                barringtonite           MgCO3•2H2O                    [5145-48-2]
trihydrate               nesquehonite           MgCO3•3H2O                    [14457-83-1]
pentahydrate              lansfordite            MgCO3•5H2O                     [61042-72-6]
basic carbonate            artinite              MgCO3•Mg(OH)2•3H2O               [12143-96-3]
basic carbonate            hydromagnestite         4MgCO3•Mg(OH)2•4H2O         [12072-90-1]
basic carbonate            dypingite             4MgCO3•Mg(OH)2•5H2O                [12544-02-4]
basic carbonate              ---               4MgCO3•Mg(OH)2•8H2O                [75300-49-1]
Occurrence and UsesMagnesium carbonate occurs in nature in several minerals as hydrated, basic and double salts, as shown above. The two principal minerals are magnesite, MgCO3 and dolomite, a double salt, CaCO3•MgCO3. Both minerals are used as source materials in the production of magnesium metal. Also, they are calcined to produce basic refractory bricks. Other applications of magnesium carbonate are in flooring, fireproofing and fire-extinguishing compositions; as a filler material and smoke suppressant in plastics; as a reinforcing agent in neoprene rubber; as a drying agent and for color retention in foods; in cos-metics; in dusting powder; and in toothpaste. The high purity magnesium carbonate is used as an antacid in medicine; and as an additive to table salt. Another important application of magnesium carbonate is as a starting material in producing a number of magnesium compounds.
DescriptionMagnesium carbonate is obtained mainly by mining the natural mineral magnesite. The trihydrate salt, MgCO3·3H2O, is prepared by mixing solutions of magnesium and carbonate ions in the presence of carbon dioxide.
Chemical PropertiesMagnesium carbonate occurs as light, white-colored friable masses or as a bulky, white-colored powder. It has a slightly earthy taste and is odorless but, since it has a high absorptive ability, magnesium carbonate can absorb odors.
The USP 32 describes magnesium carbonate as either a basic hydrated magnesium carbonate or a normal hydrated magnesium carbonate. However, the PhEur describes magnesium carbonate as being a hydrated basic magnesium carbonate in two separate monographs: heavy magnesium carbonate and light magnesium carbonate. The molecular formulas for heavy magnesium carbonate and light magnesium carbonate vary, but heavy magnesium carbonate may generally be regarded as the tetrahydrate [(MgCO3)3·Mg(OH)2·4H2O], while light magnesium carbonate may be regarded as the trihydrate [(MgCO3)3· Mg(OH)2·3H2O].
The molecular weights of the heavy and light forms of magnesium carbonate are 383.32 and 365.30, respectively.
Physical propertiesThis material is available in a very light, fluffy grade which absorbs well. The before-mentioned qualities are why magnesium carbonate is often used to absorb perfume before incorporation into face powders.
UsesUsed in Pharmaceutical units as a Magnesium Salt, Heat Insulator and Refractor, Antacid. Also used in Cosmetics, inks, glass, drying agent, color retention agent and etc.
UsesChemical intermediate for magnesium salts; component of pharmaceuticals, cosmetics, dentifrices, free-running table salt; agent in heat insulation and refractory applications
UsesSome applications of magnesiumcarbonate are uses in flooring, fireproofing and fire-extinguishing compositions; as a filler material and smoke suppressant in plastics; as a reinforcing agent in neoprene rubber; as a drying agent and for color retention in foods; in cosmetics. Magnesium carbonate is used as an antacid in medicine and as an additive to table salt. Another important application of magnesium carbonate is as a starting material in producing a number of magnesium compounds.
Because of its water-insoluble, hygroscopic properties, MgCO3 was first added to salt in 1911 to make the salt flow more freely. Magnesium carbonate, most often referred to as “chalk”, is used as a drying agent for hands in gymnastics, weight lifting and rock climbing. Magnesium carbonate is also used in taxidermy for whitening skulls. It can be mixed with hydrogen peroxide to create a paste, which is then spread on the skull to give it awhite finish. Basic magnesium carbonate is used as a clay in face masks and it has mild astringent properties and helps to smooth and soften skin. It is recommended for use on normal to dry skins.
DefinitionA whitecompound, MgCO3, existing in anhydrousand hydrated forms. The anhydrousmaterial (trigonal; r.d.2.96) is found in the mineral magnesite.There is also a trihydrate,MgCO3.3H2O (rhombic; r.d. 1.85),which occurs naturally as nesquehonite,and a pentahydrate, MgCO3.5H2O (monoclinic; r.d. 1.73),which occurs as lansfordite. Magnesiumcarbonate also occurs in themixed salt dolomite (CaCO3.MgCO3)and as basic magnesium carbonatein the two minerals artinite(MgCO3.Mg(OH)2.3H2O) and hydromagnesite(3MgCO3.Mg(OH)2.3H2O).The anhydrous salt can be formed byheating magnesium oxide in astream of carbon dioxide:
MgO(s) + CO2(g) → MgCO3(s)
Above 350°C, the reverse reactionpredominates and the carbonate decomposes.Magnesium carbonate isused in making magnesium oxideand is a drying agent (e.g. in tablesalt). It is also used as a medicalantacid and laxative (the basic carbonateis used) and is a componentof certain inks and glasses.
Definitionlansfordite: A mineral form ofmagnesium carbonate pentahydrate,MgCO3.5H2O.
Definitionhydromagnesite: A mineral formof basic magnesium carbonate,3MgCO3.Mg(OH)2.3H2O.
DefinitionThe term magnesite is loosely used as a synonym for magnesia as are also the terms caustic-calcined magnesite, dead-burned magnesite, and synthetic magnesite.
Production MethodsDepending upon the manufacturing process used, the composition of the magnesium carbonate obtained may vary from normal hydrated magnesium carbonate to basic hydrated magnesium carbonate.
Light magnesium carbonate may be manufactured by saturating an aqueous suspension of dolomite, CaMg(CO3)2, with carbon dioxide under pressure. On increase of the temperature, calcium carbonate precipitates almost entirely. The filtered solution is then heated to boiling; the magnesium bicarbonate in the solution loses precipitates.
Heavy magnesium carbonate may be manufactured by mixing a hot concentrated solution of magnesium chloride or magnesium sulfate with a solution of sodium carbonate. The heavy magnesium carbonate may be either precipitated to produce a granular material or spray-dried. Varying the temperature of the reaction solutions produces heavy magnesium carbonate with differing physical properties: e.g. material with a higher specific surface area is produced at a lower reaction temperature. Low processing temperature provided the largest surface area, which produced optimum granules or spray-dried powder.If dilute magnesium chloride or magnesium sulfate solutions are used for the reaction, a less dense material is produced.
Magnesium carbonates in varying states of hydration are also found as minerals in nature.
General DescriptionWhite, yellowish, grayish-white or brown crystalline solid or crystalline powder. Density: 3-3.1 g cm-3. An important ore for magnesium. Used in the manufacture of materials capable of withstanding very high temperatures. Sometimes used to produce carbon dioxide.
Reactivity ProfileMagnesium carbonate has generally low chemical reactivity. Non-flammable and non-combustible. Reacts with acids and acidic salts to generate gaseous carbon dioxide with effervescence (bubbling). The reaction may be rapid and exothermic with concentrated solutions of acids. The efferversence can create foaming. Incompatible with formaldehyde.
HazardA nuisance particulate.
Health HazardMagnesite is considered to be a nuisance dust.
Flammability and ExplosibilityNon flammable
Agricultural UsesNesquehonite is the natural form of magnesium carbonate trihydrate (MgCO3.3H2O).
Agricultural UsesMagnesium carbonate is a white compound occurring in anhydrous and hydrated forms. It is used as a fertilizer and also for making magnesium oxide.
The anhydrous material is found naturally in mineral magnesite. There is also a trihydrate, MgC03·3H2O (rhombic) that occurs naturally as nesquehonite, and a pentahydrate, MgCO3.5H2O (monoclinic) that occurs as lansfordite.
Magnesium carbonate also occurs in a mixed salt dolomite (CaCO3·MgCO3) and as basic magnesium carbonate in two minerals, namely, artinite [MgCO3·Mg(OH)2.3H2O] and hydromagnesite [3MgC03·Mg(OH)2.3H2O]. Heating magnesium oxide in a stream of carbon dioxide leads to the formation of the anhydrous salt.
Above 350°C, the reverse reaction predominates and the carbonate decomposes to give back MgO.
Agricultural UsesHydromagnesite is a magnesium ore which occurs as a carbonate. Magnesium carbonate occurs in a mixed salt dolomite (CaCO3.MgCO3) and as basic magnesium carbonate in two minerals, namely, artinite (MgCO3.Mg(OH)2.3H2O) and hydromagnesite (3MgCO3.Mg(OH)2.3H2O).
Pharmaceutical ApplicationsAs an excipient, magnesium carbonate is mainly used as a directly compressible tablet diluent in concentrations up to 45% w/w. Heavy magnesium carbonate produces tablets with high crushing strength, low friability, and good disintegration properties. However, magnesium carbonate can have varying effects on dissolution and stability.Magnesium carbonate has been incorporated in microsphere formulations for the purpose of stabilizing encapsulated proteins. It has also been coencapsulated in poly(lactide-co-glycolide) microsphere formulations to neutralize acidity and enhance the immunogenicity of a contraceptive peptide vaccine. Magnesium carbonate is also used to absorb liquids, such as flavors, in tableting processes. Magnesium carbonate is additionally used as a food additive and therapeutically as an antacid.
SafetyMagnesium carbonate is used as an excipient in oral solid-dosage pharmaceutical formulations and is generally regarded as an essentially nontoxic and nonirritant material. However, the use of magnesium salts, such as magnesium carbonate, is contraindicated in patients with renal impairment. In certain studies, magnesium carbonate has been shown to be an effective phosphate binder in short-term use for patients with chronic kidney disease, but the effects of long-term use require further study.The probable oral lethal dose in humans has been estimated at 0.5–5.0g/kg bodyweight. On contact with gastric acid, magnesium carbonate reacts in the stomach to form soluble magnesium chloride and carbon dioxide. Magnesium carbonate should therefore not be used as an antacid by those individuals whose stomachs cannot tolerate the evolution of carbon dioxide. Some magnesium is absorbed but is usually excreted in the urine. As with other magnesium salts, magnesium carbonate has a laxative effect and may cause diarrhea.
Therapeutically, the usual dose of magnesium carbonate as an antacid is 250–500mg, and 2.0–5.0g as a laxative.
storageMagnesium carbonate is stable in dry air and on exposure to light. The bulk material should be stored in a well-closed container in a cool, dry place.
IncompatibilitiesIncompatible with phenobarbital sodium,diazepam solution at a pH≥5, some binary powder mixtures, lansoprazole, and formaldehyde. Acids will dissolve magnesium carbonate, with the liberation of carbon dioxide. Slight alkalinity is imparted to water. Magnesium carbonate was also found to increase the dissolution of acetazolamide formulations at a pH of 1.12; however, dissolution was retarded at a pH of 7.4.
Regulatory StatusGRAS listed. Accepted as a food additive in Europe. Included in the FDA Inactive Ingredients Database (oral capsules and tablets). Included in nonparenteral medicines licensed in the UK.
Magnesium carbonate Preparation Products And Raw materials
Tag:Magnesium carbonate(546-93-0) Related Product Information
Calcium carbonate Magnesium sulfate Sodium carbonate Hydrotalcite Dimethyl carbonate Magnesium carbonate Artinite MAGNESIUM CARBONATE MAGNESIUM CARBONATE Magnesium sulfate heptahydrate Carbonic acid, magnesium salt (1:1), mixt. with magnesium hydroxide (Mg(OH)2), hydrate Carbonic acid, magnesium salt (2:1) Guanidine carbonate Strontium carbonate Cesium carbonate Manganese carbonate Lithium carbonate LEAD CARBONATE