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J & K SCIENTIFIC LTD.
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010-82848833 400-666-7788 |
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Product Name:(11aR)-(+)-5,6,10,11,12,13-Hexahydro-5-phenyl-4H-diindeno[7,1-cd:1',7'-ef]phosphocin, min. 97% (R)-SITCP
CAS:856407-37-9
Purity:min. 97% Package:100mg;25mg
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| Company Name: |
BeiJing Hwrk Chemicals Limted
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0757-86329057 18934348241 |
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| Products Intro: |
Product Name:(R)-dimethylene-[7,7′-(1,1′-spiroindan)]-phenylphospholane
CAS:856407-37-9
Purity:98.00% Package:10g Remarks:HWG29926
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| | (11aR)-(+)-5,6,10,11,12,13-Hexahydro-5-phenyl-4H-diindeno[7,1-cd:17ef]phosphocin, min. 97% (R)-SITCP Basic information | | Reaction |
| Product Name: | (11aR)-(+)-5,6,10,11,12,13-Hexahydro-5-phenyl-4H-diindeno[7,1-cd:17ef]phosphocin, min. 97% (R)-SITCP | | Synonyms: | (11aR)-(+)-5,6,10,11,12,13-Hexahydro-5-phenyl-4H-diindeno[7,1-cd:17ef]phosphocin, min. 97% (R)-SITCP;4H-Diindeno[7,1-cd:1',7'-ef]phosphocin,5,6,10,11,12,13-hexahydro-5-phenyl-, (11aR)- (9CI);(R)-diMethylene-[7,7′-(1,1′-spiroindan)]-phenylphospholane;(11aR)-5,6,10,11,12,13-Hexahydro-5-phenyl-4H-diindeno[7,1-cd:1',7'-ef]phosphocin;(R)-SITCP;(R)-dimethylene-\n[7,7′-(1,1′-spiroin\ndan)]-phenylphos\npholane;(11aR)-(+)-5,6,10,11,12,13-Hexahydro-5-phenyl-4H-diindeno[7,1-cd;17ef]phosphocin, min. 97% (R)-SITCP | | CAS: | 856407-37-9 | | MF: | C25H23P | | MW: | 354.42 | | EINECS: | | | Product Categories: | Chiral Phosphine;Chiral Spiro Ligand | | Mol File: | 856407-37-9.mol | ![(11aR)-(+)-5,6,10,11,12,13-Hexahydro-5-phenyl-4H-diindeno[7,1-cd:17ef]phosphocin, min. 97% (R)-SITCP Structure](CAS/20150408/GIF/856407-37-9.gif) |
| | (11aR)-(+)-5,6,10,11,12,13-Hexahydro-5-phenyl-4H-diindeno[7,1-cd:17ef]phosphocin, min. 97% (R)-SITCP Chemical Properties |
| Melting point | 148-149°C | | alpha | +6° (c 0.5, CH2Cl2) | | Boiling point | 505.6±50.0 °C(Predicted) | | form | solid | | color | white | | Sensitive | air sensitive |
| | (11aR)-(+)-5,6,10,11,12,13-Hexahydro-5-phenyl-4H-diindeno[7,1-cd:17ef]phosphocin, min. 97% (R)-SITCP Usage And Synthesis |
| Reaction |
- Phosphine-catalyzed intra-and intermolecular gamma-addition of nitrogen nucleophiles to allenoates and alkynoates.
- Catalytic asymmetric construction of the tryptanthrin skeleton via enantioselective decarboxylative [4+2] cyclization.
- Catalytic, enantioselective carbon-oxygen bond formation – phosphine-catalyzed synthesis of benzylic esters via oxidation of benzylic C-H bonds.
- Use of a new spirophosphine to achieve catalytic, enantioselective [4+1] annulations of amines with allenes to generate dihydropyrroles.
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| | (11aR)-(+)-5,6,10,11,12,13-Hexahydro-5-phenyl-4H-diindeno[7,1-cd:17ef]phosphocin, min. 97% (R)-SITCP Preparation Products And Raw materials |
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