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| | TRIMETHYLSILYLMETHYL AZIDE Basic information |
| | TRIMETHYLSILYLMETHYL AZIDE Chemical Properties |
| Boiling point | 92-95°C | | density | 0,87 g/cm3 | | refractive index | 1.4300 to 1.4340 | | Fp | 6°C | | solubility | Sol organic solvents; insol water. | | form | clear liquid | | color | Colorless to Yellow to Green | | Specific Gravity | 0.87 | | Hydrolytic Sensitivity | 7: reacts slowly with moisture/water |
| | TRIMETHYLSILYLMETHYL AZIDE Usage And Synthesis |
| Physical properties | bp 43 °C/43 mmHg; IR νmax 2100 cm?1;
1H NMR (CDCl3) δ = 0.12 (s, 9H), 2.75 (s, 2H); MS m/z
129, 73. | | Uses | Trimethylsilylmethyl Azide is used in the amination of organometallic compounds; preparation of
heterocyclic compounds; precursor of azomethine ylide, reactant in Silylmethyl-Substituted Heterocumulenes and [3 + 2] Cycloaddition etc. | | Preparation | Obtained in high yield by reaction of
sodium azide and (chloromethyl)trimethylsilane in DMF or
HMPA at 80°C. |
| | TRIMETHYLSILYLMETHYL AZIDE Preparation Products And Raw materials |
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