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Benzeneacetonitrile

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Company Name: Henan DaKen Chemical CO.,LTD.
Tel: +86-371-55531817
Email: info@dakenchem.com
Products Intro: Product Name:Benzeneacetonitrile
CAS:140-29-4
Purity:99% Package:100g,500g,1KG,10KG,100KG
Company Name: Mainchem Co., Ltd.
Tel: +86-0592-6210733
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Products Intro: Product Name:Benzeneacetonitrile
CAS:140-29-4
Company Name: Hefei TNJ Chemical Industry Co.,Ltd.
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Products Intro: Product Name:Benzeneacetonitrile
CAS:140-29-4
Purity:99.9% Package:1KG;5USD
Company Name: career henan chemical co
Tel: +86-371-86658258
Email: sales@coreychem.com
Products Intro: Product Name:Benzeneacetonitrile
CAS:140-29-4
Purity:99% Package:1kg;1USD
Company Name: Shanghai Billion Chemical Chemical Co. Ltd.  Gold
Tel: 021-58771921 13818686088(wechat)
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Products Intro: Product Name:Phenylacetonitrile
CAS:140-29-4
Purity:99% Package:1t,10t,100t

Lastest Price from Benzeneacetonitrile manufacturers

  • Benzeneacetonitrile
  • US $1.00 / kg
  • 2018-12-24
  • CAS:140-29-4
  • Min. Order: 1kg
  • Purity: 99%
  • Supply Ability: as request
Benzeneacetonitrile Basic information
Product Name:Benzeneacetonitrile
Synonyms:phenyl acetyl nitrile;PHENYLACETONITRILE;TOLUNITRILE;(Cyanomethyl)benzene;2-Phenylacetonitrile;aceticacid,phenyl-nitrile;Acetonitrile, phenyl-;acetonitrile,phenyl-
CAS:140-29-4
MF:C8H7N
MW:117.15
EINECS:205-410-5
Product Categories:Pharmaceutical Intermediates;Organics;Agrochemical
Mol File:140-29-4.mol
Benzeneacetonitrile Structure
Benzeneacetonitrile Chemical Properties
Melting point −24 °C(lit.)
Boiling point 233-234 °C(lit.)
density 1.015 g/mL at 25 °C(lit.)
vapor pressure 0.1 mm Hg ( 20 °C)
refractive index n20/D 1.524
Fp 215 °F
storage temp. Store below +30°C.
solubility 0.1g/l
Water Solubility insoluble. <0.1 g/100 mL at 17 ºC
Merck 14,1131
BRN 385941
Stability:Stable. Incompatible with strong oxidizing agents. May produce hydrogen cyanide in a fire.
CAS DataBase Reference140-29-4(CAS DataBase Reference)
NIST Chemistry ReferenceBenzeneacetonitrile(140-29-4)
EPA Substance Registry SystemBenzeneacetonitrile(140-29-4)
Safety Information
Hazard Codes T+,T
Risk Statements 22-24-26-23/24/25
Safety Statements 28-36/37-45-23
RIDADR UN 2470 6.1/PG 3
WGK Germany 3
RTECS AM1400000
8-9
Autoignition Temperature590 °C
Hazard Note Very Toxic
TSCA Yes
HazardClass 6.1(b)
PackingGroup III
HS Code 29269090
Hazardous Substances Data140-29-4(Hazardous Substances Data)
ToxicityLD50 orally in Rabbit: 270 mg/kg LD50 dermal Rabbit 270 mg/kg
MSDS Information
ProviderLanguage
SigmaAldrich English
ACROS English
ALFA English
Benzeneacetonitrile Usage And Synthesis
Chemical Propertiescolourless liquid
Chemical PropertiesBenzyl cyanide is a colorless, oily liquid with an aromatic odor.
UsesOrganic synthesis, especially penicillin precursors.
DefinitionChEBI: A nitrile that is acetonitrile where one of the methyl hydrogens is substituted by a phenyl group.
General DescriptionA colorless oily liquid with an aromatic odor. Insoluble in water and slightly denser than water. Contact may irritate skin, eyes, and mucous membranes. May be toxic by ingestion. Used to make other chemicals.
Air & Water ReactionsBenzeneacetonitrile is moisture sensitive. Insoluble in water.
Reactivity ProfilePHENYLACETONITRILE can react with strong acids, strong bases, strong oxidizing agents and strong reducing agents. Benzeneacetonitrile may react vigorously with sodium hypochlorite. .
HazardHighly toxic, absorbed by skin.
Health HazardPoisonous. May be fatal if inhaled, swallowed, or absorbed through skin. Contact may cause burns to skin and eyes.
Fire HazardWhen heated to decomposition, Benzeneacetonitrile emits very toxic fumes of cyanide and nitrogen oxides. Container may explode in heat of fire. Runoff from fire control water may give off poisonous gases. Avoid sodium hypochlorite.
Safety ProfilePoison by ingestion, inhalation, skin contact, subcutaneous, and intraperitoneal routes. A skin irritant. Explosive reaction with sodium hypochlorite. Used in production of drugs of abuse. When heated to decomposition it emits very toxic fumes of CNand NOx. See also NITRILES
Potential Exposure(as CN): Benzyl cyanide is used in organic synthesis, especially of penicillin precursors. It is used as a chemical intermediate for amphetamines, phenobarbital; the stimulant, methyl phenidylacetate; esters as perfumes and flavors.
First aidIf this chemical gets into the eyes, remove any contact lenses at once and irrigate immediately for at least 15 minutes, occasionally lifting upper and lower lids. Seek medical attention immediately. If this chemical contacts the skin, remove contaminated clothing and wash immediately with soap and water. Speed in removing material from skin is of extreme importance Seek medical attention immediately. If this chemical has been inhaled, remove from exposure, begin rescue breathing (using universal precautions, including resuscitation mask) if breathing has stopped and CPR if heart action has stopped. Transfer promptly to a medical facility. When this chemical has been swallowed, get medical attention. Give large quantities of water and induce vomiting. Do not make an unconscious person vomit. For cyanide poisoning, use amyl nitrate capsules if symptoms develop. All area employees should be trained regularly in emergency measures for cyanide poisoning and in CPR. A cyanide antidote kit should be kept in the immediate work area and must be rapidly available. Kit ingredients should be replaced every 1 2 years to ensure freshness. Persons trained in the use of this kit; oxygen use, and CPR must be quickly available.
ShippingUN2470 Phenylacetonitrile, Hazard Class: 6.1; Labels: 6.1—Poisonous materials.
Purification MethodsAny benzyl isocyanide impurity can be removed by shaking vigorously with an equal volume of 50% H2SO4 at 60o, washing with saturated aqueous NaHCO3, then half-saturated NaCl solution, drying and fractionally distilling under reduced pressure. Distillation from CaH2 causes some decomposition of this compound: it is better to use P2O5. Other purification procedures include passage through a column of highly activated alumina, and distillation from Raney nickel. Precautions should be taken because of possible formation of free TOXIC cyanide, use an efficient fume cupboard.[Beilstein 9 IV 1663.]
IncompatibilitiesViolent reaction with strong oxidizers; sodium hypochlorite, lithium aluminum hydride. Nitriles may polymerize in the presence of metals and some metal compounds. They are incompatible with acids; mixing nitriles with strong oxidizing acids can lead to extremely violent reactions. Nitriles are generally incompatible with other oxidizing agents such as peroxides and epoxides. The combination of bases and nitriles can produce hydrogen cyanide. Nitriles are hydrolyzed in both aqueous acid and base to give carboxylic acids (or salts of carboxylic acids). These reactions generate heat. Peroxides convert nitriles to amides. Nitriles can react vigorously with reducing agents. Acetonitrile and propionitrile are soluble in water, but nitriles higher than propionitrile have low aqueous solubility. They are also insoluble in aqueous acids.
Tag:Benzeneacetonitrile(140-29-4) Related Product Information
Acetonitrile Phenylacetic acid 2-Fluorobenzyl cyanide Diphenylacetonitrile alpha,alpha-dicyanobenzyl benzoate 2,4-Dichlorophenylacetonitrile α-methoxy-α-(trifluoromethyl)phenylacetonitrile,(+/-)-2-Methoxy-2-(trifluoromethyl)phenylacetonitrile 98%,(+/-)-2-Methoxy-2-(trifluoromethyl)phenylacetonitrile98% 2-Bromobenzyl cyanide ALPHA-METHYLPHENYLACETONITRILE 2-CHLORO-6-FLUOROPHENYLACETONITRILE ALPHA-ACETYLPHENYLACETONITRILE 1,2-Bis(cyanomethyl)benzene 1-CYANO-1-PHENYL-2-(4-METHOXY-PHENYL)ETHYLENE 2-(tert-Butoxycarbonyloxyimino)-2-phenylacetonitrile 1-Benzocyclobutenecarbonitrile 2-Methylbenzyl cyanide 2-PHENYLBUTYRONITRILE 2,3-DIPHENYLACRYLONITRILE