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Beijing HwrkChemical Technology Co., Ltd
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Product Name:1,3-Bis(2,6-di-i-propylphenyl)imidazol-2-ylidene][bis(trifluoromethanesulfonyl)imide]gold(I) CAS:951776-24-2 Purity:97.00% Package:1g;250mg
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Bide Pharmatech Ltd.
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400-164-7117 13681763483 |
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Products Intro: |
Product Name:1,3-Bis(2,6-di-i-propylphenyl)imidazol-2-ylidene][bis(trifluoromethanesulfonyl)imide]gold(I) CAS:951776-24-2 Purity:98% Package:100mg;250mg;1g; Remarks:BD635542
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Sigma-Aldrich
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021-61415566 800-8193336 |
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Products Intro: |
Product Name:[1,3-Bis(2,6-diisopropylphenyl)imidazol-2-ylidene] [bis(trifluoromethanesulfonyl)imide]gold(I) CAS:951776-24-2 Purity:95% Package:100MG Remarks:753343-100MG
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| [1,3-Bis[2,6-bis(1-methylethyl)phenyl]-1,3-dihydro-2H-imidazol-2-ylidene][1,1,1-trifluoro-N-[(trifluoromethyl)sulfonyl]methanesulfonamidato-κN]gold Basic information | Reaction |
Product Name: | [1,3-Bis[2,6-bis(1-methylethyl)phenyl]-1,3-dihydro-2H-imidazol-2-ylidene][1,1,1-trifluoro-N-[(trifluoromethyl)sulfonyl]methanesulfonamidato-κN]gold | Synonyms: | [1,3-Bis(2,6-diisopropylphenyl)imidazol-2-ylidene] [bis(trifluoromethanesulfonyl)imide]gold(I);[1,3-Bis(2,6-diisopropylphenyl)imidazol-2-ylidene][bis(trifluoromethanesulfonyl)imide]gold(I);[1,3-Bis[2,6-bis(1-methylethyl)phenyl]-1,3-dihydro-2H-imidazol-2-ylidene][1,1,1-trifluoro-N-[(trifluoromethyl)sulfonyl]methanesulfonamidato-κN]gold;IPrAuNTf2;[1,3-BIS(2,6-DI-I-PROPYLPHENYL)IMIDAZOL-2-YLIDENE][BIS(TRIFLUOROMETHANESULFONYL)IMIDE]GOLD(I),MIN.95%;)imide]goL;(1,3-bis(2,6-diisopropylphenyl)-1,3-dihydro-2H-imidazol-2-ylidene)((1,1,1-trifluoro-N-((trifluoromethyl)sulfonyl)methyl)sulfonamido)gold(I);[1,3-Bis(2,6-di-i-propylphenyl)imidazol-2-ylidene][bis(trifluoromethanesulfonyl)imide]gold(I), min. 95% | CAS: | 951776-24-2 | MF: | C29H36AuF6N3O4S2 | MW: | 865.7 | EINECS: | | Product Categories: | | Mol File: | 951776-24-2.mol | |
| [1,3-Bis[2,6-bis(1-methylethyl)phenyl]-1,3-dihydro-2H-imidazol-2-ylidene][1,1,1-trifluoro-N-[(trifluoromethyl)sulfonyl]methanesulfonamidato-κN]gold Chemical Properties |
Melting point | 202-287°C (decomposition) | storage temp. | under inert gas (nitrogen or Argon) at 2-8°C | form | solid | color | white to pale yellow | Sensitive | air sensitive |
Hazard Codes | Xi | Risk Statements | 36/37/38 | Safety Statements | 26 | WGK Germany | 3 |
| [1,3-Bis[2,6-bis(1-methylethyl)phenyl]-1,3-dihydro-2H-imidazol-2-ylidene][1,1,1-trifluoro-N-[(trifluoromethyl)sulfonyl]methanesulfonamidato-κN]gold Usage And Synthesis |
Reaction |
- Gold catalyst used for the hydroarylating cyclization of 1,2-bis(2-iodoethynyl)benzenes.
- Gold catalyst used for the carbocyclization of phenols with a terminal alkyne.
- Intermolecular C-H activation through the gold(I)-catalyzed reaction of iodoalkynes.
- Reaction of ynamide with benzyl azides.
| Uses | Selective Au(I) catalyst for hydroaminations. |
| [1,3-Bis[2,6-bis(1-methylethyl)phenyl]-1,3-dihydro-2H-imidazol-2-ylidene][1,1,1-trifluoro-N-[(trifluoromethyl)sulfonyl]methanesulfonamidato-κN]gold Preparation Products And Raw materials |
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