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2-HYDROXY-5-METHYLBENZOPHENONE

2-HYDROXY-5-METHYLBENZOPHENONE Suppliers list
Company Name: Mainchem Co., Ltd.  
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Products Intro: Product Name:2-HYDROXY-5-METHYLBENZOPHENONE
CAS:1470-57-1
Company Name: J & K SCIENTIFIC LTD.  
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Products Intro: Product Name:2-Hydroxy-5-Methylbenzophenone
CAS:1470-57-1
Purity:97.0%(GC) Package:25G,5G
Company Name: Meryer (Shanghai) Chemical Technology Co., Ltd.  
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Email: sh@meryer.com
Products Intro: Product Name:2-Hydroxy-5-Methylbenzophenone
CAS:1470-57-1
Purity:99% Remarks:12143
Company Name: TCI (Shanghai) Development Co., Ltd.  
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Products Intro: Product Name:2-Hydroxy-5-methylbenzophenone
CAS:1470-57-1
Purity:97.0% GC Package:25G,5G
Company Name: Energy Chemical  
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Products Intro: Product Name:2-HYDROXY-5-METHYLBENZOPHENONE
CAS:1470-57-1
Purity:97% Package:25G,5G
2-HYDROXY-5-METHYLBENZOPHENONE Basic information
Product Name:2-HYDROXY-5-METHYLBENZOPHENONE
Synonyms:(2-Hydroxy-5-methylphenyl)phenylmethanone;2-Benzoyl-4-methylphenol;5-Methyl-2-hydroxybenzophenone;Benzophenone, 2-hydroxy-5-methyl-;Methanone, (2-hydroxy-5-methylphenyl)phenyl-;RARECHEM FH 1L 0064;2'-HYDROXY 5'-METHYL BENZOPHENONE;2-HYDROXY-5-METHYLBENZOPHENONE
CAS:1470-57-1
MF:C14H12O2
MW:212.24
EINECS:216-002-1
Product Categories:C13 to C14;Carbonyl Compounds;Ketones;Aromatic Benzophenones & Derivatives (substituted)
Mol File:1470-57-1.mol
2-HYDROXY-5-METHYLBENZOPHENONE Structure
2-HYDROXY-5-METHYLBENZOPHENONE Chemical Properties
Melting point 83-85 °C(lit.)
Boiling point 312.08°C (rough estimate)
density 1.1035 (rough estimate)
refractive index 1.6000 (estimate)
pka8.24±0.43(Predicted)
CAS DataBase Reference1470-57-1(CAS DataBase Reference)
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26-37/39
WGK Germany 3
Hazard Note Irritant
HS Code 29145000
MSDS Information
ProviderLanguage
SigmaAldrich English
ACROS English
2-HYDROXY-5-METHYLBENZOPHENONE Usage And Synthesis
Chemical Propertiesyellow crystalline powder
PreparationPreparation by condensation of benzotrichloride with p-cresol,
? in the presence of aluminium chloride in carbon disulfide for 2 h (75%). The 6,12-diphenyl-2,8-dimethyl-6,12-epoxy-6H,12H-dibenzo[b,f] dioxocin, an intermediate compound, was also formed under these conditions (29%). This “dioxocin”, by hydrolysis with concentrated sulfuric acid at r.t., gave the expected ketone (91%);
? in the presence of aqueous sodium hydroxide in a water bath for 4 h (33%) or in 32–40% aqueous sodium hydroxide at 70–80° (67%).
Synthesis Reference(s)The Journal of Organic Chemistry, 38, p. 1924, 1973 DOI: 10.1021/jo00950a030
2-HYDROXY-5-METHYLBENZOPHENONE Preparation Products And Raw materials
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