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| | TITANIUM(III) FLUORIDE Basic information |
| Product Name: | TITANIUM(III) FLUORIDE | | Synonyms: | TiF3;Titanium fluoride (TiF3);titaniumfluoride(tif3);TITANIUM TRIFLUORIDE;TITANIUM(III) FLUORIDE;TITANIUM FLUORIDE;Titanium(III)fluoride99%;Titanium(III) fluoride, min. 98% | | CAS: | 13470-08-1 | | MF: | F3Ti | | MW: | 104.86 | | EINECS: | 236-732-4 | | Product Categories: | metal halide | | Mol File: | 13470-08-1.mol |  |
| | TITANIUM(III) FLUORIDE Chemical Properties |
| Melting point | 1200 °C | | Boiling point | 1400 °C | | density | 3.4 g/mL at 25 °C(lit.) | | solubility | insoluble in H2O, dilute acid solutions, alkaline solutions | | form | Crystalline Powder | | Specific Gravity | 3.4 | | color | Red to brown | | Water Solubility | Sparingly soluble. It hydrolyses in water. | | Sensitive | Air & Moisture Sensitive | | Crystal Structure | VF3 type | | crystal system | Three sides | | Space group | R3c | | Lattice constant | | a/nm | b/nm | c/nm | α/o | β/o | γ/o | V/nm3 | | 0.543 | 0.543 | 1.364 | 90 | 90 | 120 | 0.3488 |
| | Exposure limits | ACGIH: TWA 2.5 mg/m3
NIOSH: IDLH 250 mg/m3; TWA 2.5 mg/m3 | | InChI | 1S/3FH.Ti/h3*1H;/q;;;+3/p-3 | | InChIKey | NLPMQGKZYAYAFE-UHFFFAOYSA-K | | SMILES | F[Ti](F)F | | CAS DataBase Reference | 13470-08-1(CAS DataBase Reference) | | EPA Substance Registry System | Titanium fluoride (TiF3) (13470-08-1) |
| Hazard Codes | C | | Risk Statements | 20/21/22-34-32-14 | | Safety Statements | 26-36/37/39-45 | | RIDADR | UN 3260 8/PG 2 | | WGK Germany | 3 | | F | 10 | | Hazard Note | Corrosive | | TSCA | TSCA listed | | HazardClass | 8 | | PackingGroup | II | | HS Code | 28261990 | | Storage Class | 8A - Combustible corrosive hazardous materials | | Hazard Classifications | Eye Dam. 1
Skin Corr. 1B |
| | TITANIUM(III) FLUORIDE Usage And Synthesis |
| Chemical Properties |
Red to brown crystalline powder
Blue rhombic crystals are stable in air and unusually resistant to acids and bases. Sublimation begins at about 930°C in a less than 0.1 mm vacuum. M.p. >1100°C; d%5 2.98. Insoluble in water and alcohol. Disproportionation to TiF4 and Ti begins at 950°C.
| | Uses | It is used as a laboratory chemicals & for manufacture of chemicals. | | Production Methods | Titanium metal is hydrogenated at 600-700°C. It is then placed in a small nickel boat and inserted into the horizontal nickel tube (closed at one end). The hydride is fluorinated with gaseous HF. The open end of the tube has a cooling jacket and is sealed with picein to a copper cover. Two copper tubes are silver-soldered into the cover and serve as an inlet and outlet for the hydrogen; the inlet tube also contains a concentric silver tube for introducing HF. The output gases pass through an empty polyethylene bottle, a bubble counter filled with paraffin oil and a polyethylene trap to freeze excess HF gas. The closed end of the reaction tube is placed in a tubular furnace. The temperature is measured externally. After thoroughly flushing the apparatus with Hs, fluorination followed with a 1 4 mixture of H2 and HF for four to five hours. The HF flow is first started at a temperature above 200°C. The water temperature in the cooling jacket should be higher than 20°C to prevent condensation of the HF. After completion of the fluorination, the product is left to cool in a stream of hydrogen. The yield is 90%. | | reaction suitability | core: titanium
reagent type: catalyst |
| | TITANIUM(III) FLUORIDE Preparation Products And Raw materials |
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