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| | CYCLOPENTYLZINC BROMIDE Basic information |
| Product Name: | CYCLOPENTYLZINC BROMIDE | | Synonyms: | CYCLOPENTYLZINC BROMIDE;cyclopentylzinc bromide solution;CYCLOPENTYLZINC BROMIDE, 0.5M SOLUTION I N TETRAHYDROFURAN;Cyclopentylzinc bromide solution 0.5 in THF;Cyclopentylzinc broMide, 0.5M in THF, packaged under Argon in resealable CheMSeal^t bottles;cyclopentylzinc(II) broMide;Cyclopentylzinc broMide solution 0.5 M in THF;Cyclopentylzinc broMide, 0.5 M solution in THF, SpcSeal | | CAS: | 171860-68-7 | | MF: | C5H9BrZn | | MW: | 214.42 | | EINECS: | | | Product Categories: | Alkyl;Organozinc Halides;Reike and Organozinc Reagents | | Mol File: | 171860-68-7.mol |  |
| | CYCLOPENTYLZINC BROMIDE Chemical Properties |
| density | 0.955 g/mL at 25 °C | | Fp | 1 °F | | storage temp. | 2-8°C | | Water Solubility | Reacts with water. | | Sensitive | Air Sensitive | | Exposure limits | ACGIH: TWA 50 ppm; STEL 100 ppm (Skin)
OSHA: TWA 200 ppm(590 mg/m3)
NIOSH: IDLH 2000 ppm; TWA 200 ppm(590 mg/m3); STEL 250 ppm(735 mg/m3) |
| | CYCLOPENTYLZINC BROMIDE Usage And Synthesis |
| Uses | Cyclopentylzinc bromide is an organozinc reagent that can be used in:
- The synthesis of polyfunctional indoles by reacting with various aryldiazonium salts via Fischer indole synthesis.
- Negishi cross-coupling reactions with various haloarenes in presence of Pd-complex catalyst.
- The preparation of aryl alkyl ketones by alkylation of aryl N-methyl-N-tosyl or N-benzyl-N-(tert-butoxycarbonyl) amide derivatives in the presence of Ni catalyst and imidazolidinylidene ligand.
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| | CYCLOPENTYLZINC BROMIDE Preparation Products And Raw materials |
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