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Undecanedioic acid

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Undecanedioic acid Basic information
Description
Product Name:Undecanedioic acid
Synonyms:Nonane-1,9-dicarboxylic acid;Undecanedioic acid,97%;Nonamethylenedicarboxylic Acid Undecanedioic Acid;Undecanedioic acid,1,9-Nonanedicarboxylic acid;Undecane-1,11-dioic acid;UNDECANEDIOIC ACID;RARECHEM AL BO 0436;NONAMETHYLENEDICARBOXYLIC ACID
CAS:1852-04-6
MF:C11H20O4
MW:216.27
EINECS:217-440-6
Product Categories:Undecanedionic acid;Building Blocks;C11 to C12;Carbonyl Compounds;Carboxylic Acids;Chemical Synthesis;Organic Building Blocks;Monofunctional & alpha,omega-Bifunctional Alkanes;alpha,omega-Alkanedicarboxylic Acids;alpha,omega-Bifunctional Alkanes
Mol File:1852-04-6.mol
Undecanedioic acid Structure
Undecanedioic acid Chemical Properties
Melting point 108-110 °C (lit.)
Boiling point 389.33°C (rough estimate)
density 1.1629 (rough estimate)
vapor pressure 10Pa at 20℃
refractive index 1.4421 (estimate)
storage temp. Sealed in dry,Room Temperature
solubility methanol: 10 mg/mL, clear
form Solid
pka4.48±0.10(Predicted)
color White to Off-White
Water Solubility 5.10g/L(21 ºC)
BRN 1780537
InChIKeyLWBHHRRTOZQPDM-UHFFFAOYSA-N
LogP2.8 at 25℃
CAS DataBase Reference1852-04-6(CAS DataBase Reference)
NIST Chemistry ReferenceUndecanedioic acid(1852-04-6)
EPA Substance Registry SystemUndecanedioic acid (1852-04-6)
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26-36
WGK Germany 3
HS Code 29171900
MSDS Information
ProviderLanguage
Undecanedioic acid English
SigmaAldrich English
ACROS English
Undecanedioic acid Usage And Synthesis
Description

Undecanedioic acid, in the form of a white powder or flake, is dibasic acids which is a family of organic compounds, also known as ‘long-chain dicarboxylic acids’. Undecanedioic acid is an alpha, omega-dicarboxylic acid that is nonane with two carboxylic acid groups at positions C-1 and C-9. It has a role as a metabolite. It is a conjugate acid of an undecanedioic acid anion. It has recommended applications in corrosion inhibitors, hot melt adhesives, high performance polyamides/nylon, metal-working fluid, lubircant, adhesive, powder coating, and more. 
Undecanedioic acid has been found in parts of human aortas with advanced atherosclerotic lesions associated with intercellular matrix macromolecules and specifically with elastin, and may be the result of an increased hydrolysis of esters and (or) a decreased esterification. Undecanedioic acid has been found (among other unusual dicarboxylic acids) in the urine from patients under hopantenate therapy during episodes of Reye's-like syndrome.

Chemical Propertieswhite to light yellow powder
UsesUndecanedioic Acid is a bioactive compound found in Polygala tenuifolia root which is used as a functional food due to its attractive health benefits.
DefinitionChEBI: An alpha,omega-dicarboxylic acid that is nonane with two carboxylic acid groups at positions C-1 and C-9.
Flammability and ExplosibilityNon flammable
SynthesisUndecanedioic acid is obtained by reacting α -nitro ketone and NaOH in MeOH.To a solution of α -nitro ketone (0.7 mmol) in MeOH (4.2 ml), 25 ml of 0.5 M Na2HPO4 in a 1 N of NaOH were added and the resulting mixture was heated at 70 °C for 1-4 h, then Oxone (1.75 mmol) in water (3 ml) was added to the cold solution (r. t.). After 4 h the mixture was diluted with brine (10 ml), acidified to pH=2 with a 10% solution of HCl and extracted with EtOAc (3 x 20 ml). The combined organic layers were washed with brine (10 ml), dried over Na2SO4 and evaporated to yield pure dicarboxylic acid.
synthetic method of Undecanedioic acid
Fig The synthetic method 2 of Undecanedioic acid.
SourceUndecanedioic acid is a natural product found in Aloe africana, Phaseolus vulgaris, and other organisms with data available.
Undecanedioic acid Preparation Products And Raw materials
Preparation Products1,9-DIAMINONONANE-->9-DECENOIC ACID
Tag:Undecanedioic acid(1852-04-6) Related Product Information
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