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Cupric acetylacetonate

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Cupric acetylacetonate Basic information
Product Name:Cupric acetylacetonate
Synonyms:COPPER(+2)ACETYLACETONATE;CUPRIC(II) ACETYLACETONATE;CUPRIC AA;CUPRIC ACETYLACETONATE;BIS(ACETYLACETONATO)COPPER(II);2,4-PENTANEDIONE, COPPER(II) DERIVATIVE;ACETYLACETONE COPPER(+2);ACETYLACETONE, COPPER(II) DERIVATIVE
CAS:13395-16-9
MF:C10H14CuO4
MW:261.76
EINECS:236-477-9
Product Categories:Catalysts for Organic Synthesis;Classes of Metal Compounds;Cu (Copper) Compounds;Homogeneous Catalysts;Metal Complexes;Synthetic Organic Chemistry;Pharmaceutical Intermediates;Organometallics;Transition Metal Compounds;metal beta-diketonate complexes;proteins
Mol File:13395-16-9.mol
Cupric acetylacetonate Structure
Cupric acetylacetonate Chemical Properties
Melting point 284-288 °C (dec.) (lit.)
Boiling point 160 °C (9.7513 mmHg)
bulk density200-400kg/m3
density 0.721 g/cm3
vapor pressure 0.13 hPa (163 °C)
Fp 160°C/10mm
storage temp. Store below +30°C.
solubility 0.2g/l
form Crystalline Powder
color Blue to blue-grayish
Specific Gravity1.594
Water Solubility 0.2 g/L (20 ºC)
Hydrolytic Sensitivity4: no reaction with water under neutral conditions
Sublimation 160 ºC
BRN 4157957
Exposure limitsACGIH: TWA 1 mg/m3
NIOSH: IDLH 100 mg/m3; TWA 1 mg/m3
Stability:Stable. Incompatible with strong oxidizing agents.
InChI1S/2C5H8O2.Cu/c2*1-4(6)3-5(2)7;/h2*3,6H,1-2H3;/q;;+2/p-2/b2*4-3-;
InChIKeyQYJPSWYYEKYVEJ-FDGPNNRMSA-L
SMILESCC(=O)\C=C(\C)O[Cu]O\C(C)=C/C(C)=O
NIST Chemistry ReferenceCopper, bis(2,4-pentanedionato-o,o')-(13395-16-9)
EPA Substance Registry SystemCopper, bis(2,4-pentanedionato-.kappa.O,.kappa.O')-, (SP-4-1)- (13395-16-9)
Safety Information
Hazard Codes Xi,Xn
Risk Statements 36/37/38-20/21/22
Safety Statements 26-36-36/37/39
WGK Germany 3
RTECS GL6520000
TSCA TSCA listed
HS Code 29420000
Storage Class11 - Combustible Solids
Hazard ClassificationsEye Irrit. 2
Skin Irrit. 2
STOT SE 3
Hazardous Substances Data13395-16-9(Hazardous Substances Data)
ToxicityLD50 ipr-mus: 19 mg/kg CHTHBK 16,371,71
MSDS Information
ProviderLanguage
Cupric acetylacetonate English
SigmaAldrich English
ACROS English
ALFA English
Cupric acetylacetonate Usage And Synthesis
Chemical Propertiescrystalline solid
UsesCopper(II) acetylacetonate catalyzes coupling and carbene transfer reactions. Metal acetylacetonates are used as catalysts for polymerization of olefins and transesterification. They are used as PVC stabilizer. They are used as curing agents for epoxy resins, acrylic adhesives and silicone rubbers. They are used as solvents, lubricant additives, paint drier, and pesticides. They are used in glass coatings.
DefinitionCrystalline powder, slightly soluble in water and alcohol, soluble in chloroform, mp >230C. Resistant to hydrolysis. A chelating nonionizing compound.
reaction suitabilitycore: copper
reagent type: catalyst
Safety ProfilePoison by intravenous andintraperitoneal routes. When heated to decomposition it emits acrid smoke andfumes of Cu.
Cupric acetylacetonate Preparation Products And Raw materials
Raw materialsAmmonium hydroxide-->Acetylacetone-->Cupric nitrate trihydrate
Preparation ProductsAluminum acetylacetonate
Tag:Cupric acetylacetonate(13395-16-9) Related Product Information
ZIRCONIUM(IV) ACETYLACETONATE Acetylacetone Platinum bis(acetylacetonate) Cobaltic acetylacetonate Aluminum acetylacetonate Copper Ethyl 2,4-dioxovalerate Cupric oxide Vanadyl acetylacetonate VANADIUM(III) ACETYLACETONATE Bis(acetylacetonato)cobalt Copper oxychloride Calcium acetylacetonate Ferrous acetylacetonate Acetylacetonatobis(ethylene)rhodium(I) Zinc(II) acetylacetonate Ferric acetylacetonate Titanium(IV)oxide acetylacetonate