TRIPHENYLARSINE

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Products Intro: Product Name:TRIPHENYLARSINE
CAS:603-32-7
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Products Intro: Product Name:TRIPHENYLARSINE
CAS:603-32-7
Purity:0.99 Package:1kg
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Products Intro: Product Name:TRIPHENYLARSINE
CAS:603-32-7
Purity:99% Package:1KG;1USD
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Products Intro: Product Name:TRIPHENYLARSINE
CAS:603-32-7
Purity:95% Min. Package:5g, 10g, 100g; 500g; 1kg; 25kg
Company Name: Hefei TNJ Chemical Industry Co.,Ltd.
Tel: 0551-65418671
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Products Intro: Product Name:Triphenylarsine
CAS:603-32-7

TRIPHENYLARSINE manufacturers

  • TRIPHENYLARSINE
  • TRIPHENYLARSINE pictures
  • $1.00 / 1KG
  • 2020-01-15
  • CAS:603-32-7
  • Min. Order: 1KG
  • Purity: 99%
  • Supply Ability: 100KG
TRIPHENYLARSINE Basic information
Reaction
Product Name:TRIPHENYLARSINE
Synonyms:TRIPHENYLARSINE FOR SYNTHESIS;NSC 478;Triphenylarsenic;triphenyl-arsin;ARSINETRIPHENYL;ARSENIC TRIPHENYL;Triphenylarsine, 99.99% metals basis;Triphenylarsine,98%
CAS:603-32-7
MF:C18H15As
MW:306.23
EINECS:210-032-9
Product Categories:As (Arsenic) Compounds;Classes of Metal Compounds;Semimetal Compounds;organoarsenic compound
Mol File:603-32-7.mol
TRIPHENYLARSINE Structure
TRIPHENYLARSINE Chemical Properties
Melting point 58-61 °C (lit.)
Boiling point 360 °C
density 1,225 g/cm3
refractive index 1.6888
Fp 265 °C
storage temp. Store below +30°C.
form Powder
color white
Specific Gravity1.2225
Water Solubility Soluble in methanol. Insoluble in water.
Hydrolytic Sensitivity4: no reaction with water under neutral conditions
BRN 1842037
CAS DataBase Reference603-32-7(CAS DataBase Reference)
EPA Substance Registry SystemArsine, triphenyl- (603-32-7)
Safety Information
Hazard Codes T,N
Risk Statements 23/25-50/53
Safety Statements 20/21-28-45-60-61
RIDADR UN 3465 6.1/PG 2
WGK Germany 3
RTECS CH8942500
TSCA Yes
HS Code 2931 90 00
HazardClass 6.1
PackingGroup II
MSDS Information
ProviderLanguage
ACROS English
SigmaAldrich English
ALFA English
TRIPHENYLARSINE Usage And Synthesis
Reaction
  1. Useful as a ligand in Stille coupling reactions.
  2. Synthesis of functionalized cyclopropanes from the reaction between acetylenic esters and C-H acids.
  3. Rh-complex catalyzed addition reactions of chloroacetyl chlorides to alkynes.
Reactions of 603-32-7
Chemical PropertiesCOLOURLESS TO SLIGHTLY YELLOW CRYSTALLINE SOLID
UsesTriphenylarsine is used in certain metal-catalyzed coupling reactions. It is a precursor to tetraphenylarsonium chloride a popular precipitating agent.
Purification MethodsRecrystallise Ph3As from EtOH or aqueous EtOH [Dahlinger et al. J Chem Soc, Dalton Trans 2145 1986, Boert et al. J Am Chem Soc 109 7781 1987]. [Beilstein 16 H 829, 16 I 431, 16 II 407, 16 III 921, 16 IV 1139.] HIGHLY TOXIC.
TRIPHENYLARSINE Preparation Products And Raw materials
Preparation ProductsTungsten,pentacarbonyl(triphenylarsine)-(OC-6-22)-
Tag:TRIPHENYLARSINE(603-32-7) Related Product Information
ARSENIC (III) SELENIDE CACODYLIC ACID TRIMETHYLARSINE ARSINE TETRAPHENYLARSONIUM CHLORIDE HYDROCHLORIDE TETRAPHENYLARSONIUM CHLORIDE MONOHYDRATE TETRAPHENYLARSONIUM CHLORIDE METHYLTRIPHENYLARSONIUM IODIDE TRIPHENYLARSINE OXIDE TRIPHENYLARSINE TETRAPHENYLARSONIUM BROMIDE TRI-(4-METHYLPHENYL)ARSINE chlorotris(triphenylarsine)rhodium Tungsten,pentacarbonyl(triphenylarsine)-(OC-6-22)- Phenylarsine TETRAPHENYLARSONIUM CHLORIDE HYDROCHLORIDE DIHYDRATE METHYL TRIPHENYLARSONIUM CHLORIDE TRI(3-METHYLPHENYL)ARSINE