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J & K SCIENTIFIC LTD.
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Product Name:(S)-(-)-2,2'-Bis[di(3,5-di-t-butylphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl, min. 97%
CAS:167709-31-1
Purity:min. 97% Package:100mg;10g;2g;500mg
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(S)-(-)-2,2'-Bis[di(3,5-di-t-butylphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl,min.97% manufacturers
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| | (S)-(-)-2,2'-Bis[di(3,5-di-t-butylphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl,min.97% Basic information | | Reactions |
| Product Name: | (S)-(-)-2,2'-Bis[di(3,5-di-t-butylphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl,min.97% | | Synonyms: | (S)-(-)-2,2'-Bis[di(3,5-di-t-butylphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl,min.97%;(S)-(-)-2,2''-BIS[DI(3,5-DI-T-BUTYLPHENYL)PHOSPHINO]-6,6''-DIMETHOXY-1,1''-BIPHENYL, MIN. 97%;(S)-(6,6μ-Dimethoxybiphenyl-2,2μ-diyl)bis[bis(3,5-di-tert-butylphenyl)phosphine];(S)-3,5-t-Bu-MeOBIPHEP, SL-A121-2, (S)-2,2μ-Bis[bis(3,5-di-tert-butyl)phosphino]-6,6μ-dimethoxy-1,1μ-biphenyl;(S)-(-)-2,2'-Bis[di-(3,5-di-tert-butylphenyl)-phosphino]-6,6'-dimethoxy-1,1'-biphenyl;(S)-3,5-t-Bu-MeOBIPHEP;SL-A121-2;(S)-(-)-2,2'-Bis[di-(3,5-di-t-butylphenyl)-phosphino]-
6,6'-dimethoxy-1,1'-biphenyl | | CAS: | 167709-31-1 | | MF: | C70H96O2P2 | | MW: | 1031.46 | | EINECS: | | | Product Categories: | Chiral Phosphine;MeOBIPHEP Series | | Mol File: | 167709-31-1.mol | ![(S)-(-)-2,2'-Bis[di(3,5-di-t-butylphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl,min.97% Structure](CAS/GIF/167709-31-1.gif) |
| | (S)-(-)-2,2'-Bis[di(3,5-di-t-butylphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl,min.97% Chemical Properties |
| Boiling point | 856.5±65.0 °C(Predicted) | | storage temp. | under inert gas (nitrogen or Argon) at 2-8°C | | form | Powder | | color | white |
| WGK Germany | 3 | | HS Code | 29319090 |
| | (S)-(-)-2,2'-Bis[di(3,5-di-t-butylphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl,min.97% Usage And Synthesis |
| Reactions |
- Pd-catalyzed enantioselective Heck reaction.
- Used in enantioselective lactam synthesis via Pd-catalyzed intramolecular allylic alkylation.
- Used in enantioselective Au-catalyzed polycyclization reactions.
| | Chemical Properties | White powder | | Uses | (S)-3,5-t-Bu-MeOBIPHEP can be used as a ligand in the stereoselective preparation of allenoates via palladium-catalyzed asymmetric carbonylation of propargylic carbonates. It can also be used in the C-C coupling reactions. | | General Description | sold in collaboration with Solvias AG |
| | (S)-(-)-2,2'-Bis[di(3,5-di-t-butylphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl,min.97% Preparation Products And Raw materials |
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