Log in | Join Free | china | japan | germany

Diacetato[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]ruthenium(II)

Request For Quotation
Diacetato[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]ruthenium(II) Suppliers list
Company Name: career henan chemical co
Tel: +86-0371-86658258
Email: sales@coreychem.com
Products Intro: Product Name:Diacetato[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]ruthenium(II)
CAS:373650-12-5
Purity:98% Package:1KG;1USD
Company Name: Chongqing Chemdad Co., Ltd
Tel: +86-023-61398051 +8613650506873
Email: sales@chemdad.com
Products Intro: Product Name:Diacetato[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]ruthenium(II)
CAS:373650-12-5
Purity:0.98 Package:1kg，2kg，5kg，10kg，25kg
Company Name: Richest Group Ltd
Tel: 18017061086
Email: oled@richest-group.com
Products Intro: Product Name:Diacetato[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]ruthenium(II)
CAS:373650-12-5
Purity:99%min Package:100g/bottle;500g/bottle;1kg/bottle;10kg/drum;50kg/drum;100kg/drum;939T/drum;
Company Name: SHANGHAI T&W PHARMACEUTICAL CO., LTD.
Tel: +86-021-61551413 +8618813727289
Email: contact@trustwe.com
Products Intro: Product Name:Ru(OAc)2[(S)-segphos]
CAS:373650-12-5
Purity:99% HPLC Package:5KG;1KG
Company Name: changzhou huayang technology co., ltd
Tel: +8615250961469
Email: 2571773637@qq.com
Products Intro: Product Name:Diacetato[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]ruthenium(II)
CAS:373650-12-5

Diacetato[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]ruthenium(II) manufacturers
Diacetato[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]ruthenium(II) Basic information
Reaction
Product Name:Diacetato[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]ruthenium(II)
Synonyms:Diacetato[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]ruthenium(II);(S)-Ru(OAc)2(SEGPHOS(R));Diacetato[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]ruthenium(II) Ru(OAc)2[(S)-segphos];Diacetato[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]ruthenium(II) Ru(OAc)2[(S)-segphos(R)];Diacetoxyruthenium, [4-(5-diphenylphosphanyl-1,3-benzodioxol-4-yl )-1,3-benzodioxol-5-yl]-diphenyl-phosphane;Diacetato[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-be...;(S)-Ru(OAc)2(SEGPHOS);RU(OAC)2[(S)-SEGPHOS]
CAS:373650-12-5
MF:C38H28O4P2.C4H6O4Ru
MW:829.741
EINECS:
Product Categories:Ru
Mol File:373650-12-5.mol
Diacetato[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]ruthenium(II) Structure
Diacetato[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]ruthenium(II) Chemical Properties
Melting point >100°C
storage temp. 2-8°C
form solid
color yellow to black
Sensitive air sensitive
Safety Information
WGK Germany 3
MSDS Information
Diacetato[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]ruthenium(II) Usage And Synthesis
Reaction
  1. Highly active highly enantioselective catalyst for hydrogenation of functionalized ketones. The acetate salts are frequently used for hydrogenation of allyl alcohols, unsaturated carboxylic acids and reductive amination.
  2. Asymmetric hydrogenation of substituted allyl alcohols.
Reactions of 373650-12-5
Uses(S)-Ru(OAc)2(SEGPHOS?) can be used as a catalyst:
  • To prepare highly chemo, enantio, and diastereoselective primary β-amino lactams by asymmetric reductive amination of racemic β-keto lactams.
  • To synthesize chiral primary diarylmethylamines and sterically bulky benzylamines from diaryl and sterically hindered ketones via asymmetric reductive amination reaction.
  • For the conversion of levulinic acid to optically active γ-valerolactone via asymmetric hydrogenation reaction.

Diacetato[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]ruthenium(II) Preparation Products And Raw materials
Tag:Diacetato[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]ruthenium(II)(373650-12-5) Related Product Information
Diacetato[(R)-(+)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole] ruthenium(II) Ru(OAc)2[(R)-segphos]　 Diacetato[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II) [1,2-Bis(diphenylphosphino)ethane]dichloropalladium(II) Dichloro(cycloocta-1,5-diene)ruthenium(II) Diacetato[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II) DICHLORO[1,3-BIS(DIPHENYLPHOSPHINO)PROPANE]PALLADIUM(II) Dichloro(2-pyridinecarboxylato)gold (S)-(-)-5,5'-Bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole,min.98%(S)-SEGPHOS Diacetato{(R)-(+)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}ruthenium(II) Diacetato[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]ruthenium(II)