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Allylboronic acid pinacol ester

Allylboronic acid pinacol ester Suppliers list
Company Name: Capot Chemical Co.,Ltd.
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Products Intro: Product Name:3-Hydroxy-2,3-dimethylbutan-2-yl hydrogen allylboronate
CAS:72824-04-5
Purity:98%(Min,HPLC) Package:100g;1kg;5kg,10kg,25kg,50kg
Company Name: Shanghai Daken Advanced Materials Co.,Ltd
Tel: +86-371-66670886
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Products Intro: Product Name:Allylboronic acid pinacol ester
CAS:72824-04-5
Purity:99% Package:100g ;1KG ;5KG 25KG
Company Name: ATK CHEMICAL COMPANY LIMITED
Tel: +undefined-21-51877795
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Products Intro: CAS:72824-04-5
Purity:0.99 Package:5G,10G,25G,50G,100G,250G,1KG
Company Name: Shanghai Arbor Chemical Co., Ltd.
Tel: 021-60451682
Email: act@arborchemical.com
Products Intro: Product Name:Allylboronic acid pinacol ester
CAS:72824-04-5
Purity:97% Package:10G 100G 1KG 25KG
Company Name: Hubei Jusheng Technology Co.,Ltd.
Tel: 18871490254
Email: linda@hubeijusheng.com
Products Intro: Product Name:Allylboronic acid pinacol ester
CAS:72824-04-5
Purity:0.99 Package:5KG;1KG Remarks:C9H17BO2

Allylboronic acid pinacol ester manufacturers

Allylboronic acid pinacol ester Basic information
Product Name:Allylboronic acid pinacol ester
Synonyms:2-(Prop-2-en-1-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane, 2-Allyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane;Allylboronic acid pinacol ester 2-Allyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane;Allylboronic acid pinacol ester 97%;2-Allyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane (stabilized with Phenothiazine);4,4,5,5-tetramethyl-2-(2-propen-1-yl)-1,3,2-dioxaborolane;4,4,5,5-tetramethyl-2-(2-propenyl)-1,3,2-dioxaborolane;Allyl pinacol boronate;Pinacolyl 2-propenylboronate
CAS:72824-04-5
MF:C9H17BO2
MW:168.04
EINECS:672-877-3
Product Categories:Alkyl Boronate Esters;Boronate Esters;Boronic Acids and Derivatives;Chemical Synthesis;Organometallic Reagents;Olefin;Organoborons;B (Classes of Boron Compounds);Boronic Acids Esters;CHIRAL CHEMICALS
Mol File:72824-04-5.mol
Allylboronic acid pinacol ester Structure
Allylboronic acid pinacol ester Chemical Properties
Boiling point 50-53 °C/5 mmHg (lit.)
density 0.896 g/mL at 25 °C (lit.)
refractive index n20/D 1.4268(lit.)
Fp 115 °F
storage temp. 2-8°C
solubility Chloroform, Methanol (Slightly)
form Liquid
color Clear colorless
Water Solubility Not miscible or difficult to mix in water.
BRN 4244068
CAS DataBase Reference72824-04-5(CAS DataBase Reference)
Safety Information
Hazard Codes Xi
Risk Statements 10-36/37/38
Safety Statements 26-36
RIDADR UN 1993 3/PG 3
WGK Germany 3
Hazard Note Irritant
HazardClass 3
PackingGroup III
HS Code 29310095
MSDS Information
ProviderLanguage
2-Allyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane English
SigmaAldrich English
ALFA English
Allylboronic acid pinacol ester Usage And Synthesis
Chemical PropertiesClear corless liquid
UsesAllylboronic acid pinacol ester can act as reagent used for Palladium-catalyzed Suzuki-Miyaura cross-coupling reactions and olefin metathesis; Intermolecular radical additions; Allylboration of aldehydes catalyzed by chiral spirobiindane diol (SPINOL) based phosphoric acids and Cobalt-catalyzed regioselective hydrovinylation of dienes with alkenes ; Nucleic acid-templated energy transfer leading to a photorelease reaction .
UsesAllylboronic acid pinacol ester reacts with carboxylic acids, in the presence of tri-n-butyltin hydride, to give homoallylic alcohols in good yield. Homoallylic alcohols can also be formed by allylboration of aldehydes. It is a reagent used for palladium-catalyzed Suzuki-Miyaura cross-coupling reactions and olefin metathesis, intermolecular radical additions, allylboration of aldehydes catalyzed by chiral spirobiindane diol (SPINOL) based phosphoric acids, cobalt-catalyzed regioselective hydrovinylation of dienes with alkenes, nucleic acid-templated energy transfer leading to a photorelease reaction and stereoselective indium-catalyzed Hosomi-Sakurai reactions.
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