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ChemicalBook > Product Catalog >Chemical Reagents >Organic reagents >Phosphine ligand >(R)-1-[(1S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDI-PHENYLPHOSPHINE

(R)-1-[(1S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDI-PHENYLPHOSPHINE

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(R)-1-[(1S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDI-PHENYLPHOSPHINE Suppliers list
Company Name: XINXIANG RUNYU MATERIAL CO., LTD.
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Products Intro: Product Name:(R)-1-[(1S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDI-PHENYLPHOSPHINE
CAS:158923-09-2
Purity:0.98 Package:100g;200g;500g;1kg;2kg;5kg;10kg;25kg
Company Name: Changzhou Ansciep Chemical Co., Ltd.
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Products Intro: Product Name:(R)-(-)-1-[(Sp)-2-(Dicyclohexylphosphino)ferrocenyl]-ethyldicyclohexylphosphine
CAS:158923-09-2
Purity:98% Package:100g, 500g, 1kg, 25kg, 50kg, 200kg Remarks:Good quality; Large stock; Hot sale
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Products Intro: Product Name:(R)-1-[(1S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDI-PHENYLPHOSPHINE
CAS:158923-09-2
Purity:95.0%-99.0% Package:1ASSAYS;6.05USD
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Products Intro: Product Name:(R)-1-[(1S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDI-PHENYLPHOSPHINE
CAS:158923-09-2
Purity:98%+ Package:Standard or custom package Remarks:excellent quality and reliable supplier
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Products Intro: Product Name:(R)-(-)-1-[(S)-2-(Dicyclohexylphosphino)ferrocenyl]ethyldiphenylphosphine
CAS:158923-09-2
Purity:0.95&0.99 Package:0.1KG;1KG;1000KG Remarks:Top Quality
(R)-1-[(1S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDI-PHENYLPHOSPHINE Basic information
Product Name:(R)-1-[(1S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDI-PHENYLPHOSPHINE
Synonyms:(R)1 (1S)2(DI-C-HEXYLPHOSPHINO)FERROCEN&;(R)-(-)-1-[(S)-2-(Dicyclohexylphosphino)ferrocenyl]ethyldiphenylphosphine,min.97%;(r,r)-1-(dicyclohexylphosphino)-2-[1-(diphenylphosphino)ethyl]ferrocene (acc to cas);(R)-(-)-1-[(S)-2-(DICYCLOHEXYLPHOSPHINO) FERROCENYL]ETHYLDIPHENYLPHOSPHINE, MIN. 97%;(R)-1-[(SP)-2-(Dicyclohexylphosphino)ferrocenylethyl]diphenylphosphine;Josiphos SL-J004-1, (1R)-1-(Dicyclohexylphosphino)-2-[(1R)-1-(diphenylphosphino)ethyl]ferrocene (acc to CAS);(R)1[(1S)2(di-C-hex;(S)-(-)-l-[(S)-2-( Dicyclohexylphosphino)ferroceny1] ethyldicyclohexylphosphino
CAS:158923-09-2
MF:C36H44FeP210*
MW:594.53
EINECS:
Product Categories:Chiral Phosphine;Ferrocene Series;Josiphos Series;organophosphine ligand
Mol File:158923-09-2.mol
(R)-1-[(1S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDI-PHENYLPHOSPHINE Structure
(R)-1-[(1S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDI-PHENYLPHOSPHINE Chemical Properties
alpha -100° ±5° (c 0.5, CHCl3)
storage temp. under inert gas (nitrogen or Argon) at 2-8°C
form Powder
color orange
Safety Information
Risk Statements 36/37/38
Safety Statements 26-36/37/39
WGK Germany 3
F 10
HS Code 29319090
MSDS Information
ProviderLanguage
SigmaAldrich English
(R)-1-[(1S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDI-PHENYLPHOSPHINE Usage And Synthesis
Chemical PropertiesRed crystal
Uses(R)-1-[(SP)-2-(Dicyclohexylphosphino)ferrocenylethyl]diphenylphosphine can be used as a ligand:
  • To prepare iridium metal complex (IrIJOSIPHOS), which is used as a catalyst in the asymmetric hydrogenation of 2-phenylquinoxaline.
  • In the preparation of natural products by asymmetric conjugate addition of Grignard reagents to α-substituted cyclic alkenones.

Reactions1. Ligand for asymmetric hydroformylation reactions
2. Ligand for asymmetric intramolecular amide arylation
3. Ligand for enantioselective 1,6-conjugate addition of Grignard reagents to linear dienolates
4. Ligand for enantioselective synthesis of vicinal dialkyl arrays
5. Ligand for asymmetric conjugate addition of Grignard reagents to chromones .
Reactions of 158923-09-2
General Descriptionsold in collaboration with Solvias AG
(R)-1-[(1S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDI-PHENYLPHOSPHINE Preparation Products And Raw materials
Tag:(R)-1-[(1S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDI-PHENYLPHOSPHINE(158923-09-2) Related Product Information
ETHYLDIPHENYLPHOSPHINE (S)-1-[(1R)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDI-PHENYLPHOSPHINE (R)-1-[(1S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDI-PHENYLPHOSPHINE 1,3-BIS(DIMETHYLPHOSPHINO)PROPANE DICYCLOHEXYLPHOSPHINE 1,3-BIS(PHOSPHINO)PROPANE TRIISOPROPYLPHOSPHINE TRIHEXYLPHOSPHINE