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Thiophanate-methyl

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Company Name: Mainchem Co., Ltd.
Tel: +86-0592-6210733
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Products Intro: Product Name:Thiophanate-methyl
CAS:23564-05-8
Company Name: Hefei TNJ Chemical Industry Co.,Ltd.
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Products Intro: Product Name:Thiophanate-Methyl
CAS:23564-05-8
Purity:95%TC/70%WP/50%WP Package:25kg;USD
Company Name: career henan chemical co
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Products Intro: Product Name:Thiophanate-methyl
CAS:23564-05-8
Purity:99% Package:1kg;1USD
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Purity:99% Package:5KG;1KG;25KG
Company Name: Hubei Jusheng Technology Co.,Ltd.
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Products Intro: Product Name:thiophanate-methyl
CAS:23564-05-8
Purity:99% Package:5KG;1KG

Lastest Price from Thiophanate-methyl manufacturers

  • Thiophanate-methyl
  • US $1.00 / kg
  • 2019-05-13
  • CAS:23564-05-8
  • Min. Order: 1kg
  • Purity: 99%
  • Supply Ability: Customized
  • Thiophanate-Methyl
  • US $0.00 / kg
  • 2019-03-11
  • CAS:23564-05-8
  • Min. Order: 25kg
  • Purity: 95%TC/70%WP/50%WP
  • Supply Ability: 1000MT
Thiophanate-methyl Basic information
Description References
Product Name:Thiophanate-methyl
Synonyms:(1,2-phenylenebis(iminocarbonothioyl))bis-carbamicacidimethylester;[1,2-phenylenebis(iminocarbonothioyl)]bis-carbamicacidimethylester;1,2-bis(methoxycarbonylthioureido)benzene;1,2-di-(3-Methoxy-carbonyl-2-thioureido)benzene;ditek;easout;enovitm;enovitmethyl
CAS:23564-05-8
MF:C12H14N4O4S2
MW:342.39
EINECS:245-740-7
Product Categories:FUNGICIDE;Alpha sort;MetabolitesPesticides&Metabolites;Q-ZAlphabetic;BenzimidazolesPesticides;CarbamatesEnvironmental Standards;Fungicides;MetabolitesAlphabetic;Pesticides;Pesticides&Metabolites;TF - TO;NULL
Mol File:23564-05-8.mol
Thiophanate-methyl Structure
Thiophanate-methyl Chemical Properties
Melting point 172°C
density 1.4542 (rough estimate)
refractive index 1.6000 (estimate)
storage temp. 0-6°C
form neat
Water Solubility <0.1 g/100 mL at 20 ºC
Merck 13,9427
BRN 937942
Stability:Stable. Incompatible with strong oxidizing agents, alkalies, copper salts.
EPA Substance Registry SystemCarbamic acid, [1,2-phenylenebis(iminocarbonothioyl)] bis-, dimethyl ester(23564-05-8)
Safety Information
Hazard Codes Xn;N,N,Xn
Risk Statements 20-43-50/53-68
Safety Statements 36/37-46-60-61
RIDADR UN 3077
WGK Germany 2
RTECS BA3675000
HS Code 29309090
Hazardous Substances Data23564-05-8(Hazardous Substances Data)
ToxicityLD50 in rats, mice, guinea pigs, rabbits (g/kg): 3.40, 6.64, 3.64, 2.27 orally (Hashimoto)
MSDS Information
Thiophanate-methyl Usage And Synthesis
DescriptionThiophanate methyl is a member of benzimidazole and a systemic fungicide with protective and curative activity against a broad spectrum of fungal diseases including leaf spots, blotches, blights, fruit spots, rots, sooty mould, scabs, bulb/corn/tuber decays, blossom blights, powdery mildews, certain rusts, and common soil borne crown and root rots. It is used on a variety of tree, vine, root crops, canola, and wheat, as well as on lawns and ornamentals. Thiophanate methyl is absorbed by the roots and leaves. Thiophanate-methyl has a low mammalian toxicity. But, it is an irritant and a skin sensitizer. It may also be mutagen. Moderate toxicity of thiophanate methyl is observed for aquatic organisms and earthworms. In EU, thiophanate methyl is approved to control fungal diseases on crops, while in Australia it is not registered for use on food-producing species, while it is only for the control of soil-borne diseases of ornamentals plants. For application, Thiophanate-methyl is formulated into wettable powders containing 50 and 70% active ingredient.
References
  1. https://apvma.gov.au
  2. https://www.epa.gov
  3. https://sitem.herts.ac.uk
  4. http://www.inchem.org
  5. Terry R Roberts, David H Hutson, Philip W Lee, Peter H Nicholls, and Jack R Plimmer, Metabolic Pathways of Agrochemicals: Part 2: Insecticides and Fungicides, 1999, ISBN 978-0-85404-499-3
Chemical PropertiesMethyl thiophanate is a colorless crystals, prisms or light brown powder.
Chemical Propertiescolourless crystals, or white or light brown powder
UsesThiophanate-Methyl is a systematic fungicide of the thiophanate class. Thiophanate-Methyl is commonly used in agriculture to protect against powdery mildew, rot and other fungal diseases in fruits, ve getables and other crops.
UsesSystemic fungicide.
DefinitionChEBI: A member of the class of thioureas that is the dimethyl ester of (1,2-phenylenedicarbamothioyl)biscarbamic acid. A fungicide effective against a broad spectrum of diseases in fruit, vegetables, turf and other crops including eyespot, scab, powdery mildew a d grey mould.
General DescriptionColorless crystals or light brown powder.
Air & Water ReactionsInsoluble in water.
Reactivity ProfileThiophanate-methyl is incompatible with strong acids and bases, and with strong reducing agents such as hydrides. Produces flammable gaseous hydrogen with active metals or nitrides. Incompatible with strong oxidizing acids, peroxides. Incompatible with alkaline material. Forms complexes with copper salts .
Fire HazardFlash point data for Thiophanate-methyl are not available. Thiophanate-methyl is probably combustible.
Agricultural UsesFungicide: Thiophanate-methyl is a systemic fungicide used to control a broad spectrum of fungal diseases on fruits, vegetables, turf and ornamentals, including shade trees, and diseases in the field, nurseries, and in greenhouses. Note: Do not confuse with thiophanate-ethyl (CAS: 23564-06-9), which is not currently registered for use in the U.S. Registered for use in EU countries. Registered for use in the U.S.
Trade nameBASF® 32500 F; BASF® 32500 Fungicide; CERCOBIN®; CLEARY® 3336; CONSYST®; DITEK®[C]; DOMAIN®; DOUSAN®[C]; ENOVIT®; EVOLVE®; FANATE®; FUNGITOX®; FUNGO®; MILDOTHANE® Turf Liquid; NEOTOPSIN®; NF- 35®; NF-44®; NSC 170810®; PELT®; PRO-TURF®; SIPCAVIT®; SNARE®; SPECTRO®; SYSTEC®; SYSTEMIC® FUNGICIDE; TD 1771®; TOPSIN®; TOPSIN-WP METHYL®; 3336 TURF FUNGICIDE®; ZYBAN®
Potential ExposureMethyl thiophanate is thiocarbamate ester, used in the synthesis of polymers and in agriculture as pesticides, soil fumigants, and seed disinfectants.
First aidIf this chemical gets into the eyes, remove any contact lenses at once and irrigate immediately for at least 15 minutes, occasionally lifting upper and lower lids. Seek medical attention immediately. If this chemical contacts the skin, remove contaminated clothing and wash immediately with soap and water. Shampoo hair. Speed in removing material from skin is of extreme importance. Seek medical attention immediately. If this chemical has been inhaled, remove from exposure, begin rescue breathing (using universal precautions, including resuscitation mask) if breathing has stopped and CPR if heart action has stopped. Transfer promptly to a medical facility. When this chemical has been swallowed, get medical attention. Give large quantities of water and induce vomiting. Do not make an unconscious person vomit.
ShippingUN2771 Thiocarbamate pesticides, solid, toxic, Hazard Class: 6.1; Labels: 6.1-Poisonous materials. UN3077 Environmentally hazardous substances, solid, n.o.s., Hazard class: 9; Labels: 9-Miscellaneous hazardous material, Technical Name Required.
IncompatibilitiesThiocarbamate esters are combustible; dust may form explosive mixture with air. Decomposes163℃Thiocarbamate esters are combustible. They react violently with powerful oxidizers such as calcium hypochlorite. Poisonous gases are generated by the thermal decomposition of thiocarbamate compounds, including carbon disulfide, oxides of sulfur, oxides of nitrogen, hydrogen sulfide, ammonia, and methylamine. Thio and dithio carbamates slowly decompose in aqueous solution to form carbon disulfide and methylamine or other amines. Such decompositions are accelerated by acids. Flammable gases are generated by the combination of thiocarbamates with aldehydes, nitrides, and hydrides. Thiocarbamates are incompatible with acids, peroxides, and acid halides.
Waste DisposalIn accordance with 40CFR 165 recommendations for the disposal of pesticides and pesticide containers. Must be disposed properly by following package label directions or by contacting your local or federal environmental control agency, or by contacting your regional EPA office. Consult with environmental regulatory agencies for guidance on acceptable disposal practices. Generators of waste containing this contaminant (≥100 kg/mo) must conform with EPA regulations governing storage, transportation, treatment, and waste disposal.
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