| Company Name: |
Mainchem Co., Ltd.
|
| Tel: |
+86-0592-6210733 |
| Email: |
sale@mainchem.com |
| Products Intro: |
Product Name:ALLYLIDENE DIACETATE
CAS:869-29-4
|
|
| | ALLYLIDENE DIACETATE Basic information |
| Product Name: | ALLYLIDENE DIACETATE | | Synonyms: | ALLYLIDENE DIACETATE;ACROLEIN DIACETATE;1,1-DIACETOXY-2-PROPENE;2-PROPENYLIDENE DIACETATE;2-PROPENE-1,1-DIOL DIACETATE;3,3-DIACETOXY-1-PROPENE;,3-Diacetoxy-1-propene;1-(Acetyloxy)-2-propenyl acetate | | CAS: | 869-29-4 | | MF: | C7H10O4 | | MW: | 158.15 | | EINECS: | 212-789-0 | | Product Categories: | monomer | | Mol File: | 869-29-4.mol |  |
| | ALLYLIDENE DIACETATE Chemical Properties |
| Risk Statements | 36/37/38 | | Safety Statements | 26-36/37/39 | | RIDADR | 2810 | | HazardClass | 6.1(a) | | PackingGroup | II |
| | ALLYLIDENE DIACETATE Usage And Synthesis |
| Uses | Allylidene Diacetate is a fungicide useful for the control of pea root rot and effective against Phytophthora palmivora. It may also be useful in the formation of vitamin C conjugate of acrolein. | | Synthesis Reference(s) | The Journal of Organic Chemistry, 48, p. 1765, 1983 DOI: 10.1021/jo00158a036 | | Purification Methods | Check the NMR spectrum. If it is not satisfactory, then add Ac2O and a drop of conc H2SO4 and heat at 50o for 10minutes. Then add anhydrous NaOAc (ca 3g/ 100g of liquid) and fractionate. Note that it forms an azeotrope with H2O, so do not add H2O at any time. It is a highly flammable and TOXIC liquid; keep away from the skin. [Smith et al. J Am Chem Soc 73 5282 1951, Beilstein 2 H 154, 2 I 72, 2 III 356, 2 IV 291.] |
| | ALLYLIDENE DIACETATE Preparation Products And Raw materials |
|