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alpha,2-Dimethyl-5-nitro-1H-imidazole-1-ethanol

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CAS:3366-95-8
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Products Intro: Product Name:alpha,2-Dimethyl-5-nitro-1H-imidazole-1-ethanol
CAS:3366-95-8
Purity:99% Package:25KG;5KG;1KG

alpha,2-Dimethyl-5-nitro-1H-imidazole-1-ethanol manufacturers

  • Secnidazole
  • Secnidazole pictures
  • $1.00 / 1kg
  • 2025-11-14
  • CAS:3366-95-8
  • Min. Order: 1kg
  • Purity: 99%
  • Supply Ability: 10 mt
  • Secnidazole
  • Secnidazole pictures
  • $0.00 / 1kg
  • 2025-11-14
  • CAS:3366-95-8
  • Min. Order: 1kg
  • Purity: 98%-102%
  • Supply Ability: 1000KGS
  • Secnidazole
  • Secnidazole pictures
  • $34.00 / 5mg
  • 2025-11-10
  • CAS:3366-95-8
  • Min. Order:
  • Purity: 98.86%
  • Supply Ability: 10g
alpha,2-Dimethyl-5-nitro-1H-imidazole-1-ethanol Basic information
Product Name:alpha,2-Dimethyl-5-nitro-1H-imidazole-1-ethanol
Synonyms:Secnidazole, alpha,2-DiMethyl-5-nitro-1H-iMidazole-1-ethanol;Secnidazole hydrate(see Data Sheet);1-(2-Methyl-5-nitro-1H-iMidazol-1-yl)propan-2-ol;SECNIDAZOLE;1-(2-Methyl-5-nitroimidazol-1-yl)-2-propanol;a,2-Dimethyl-5-nitro-1H-imidazole-1-ethanol;Flagentyl;PM 185184
CAS:3366-95-8
MF:C7H11N3O3
MW:185.18
EINECS:222-134-0
Product Categories:API;secnidazole;Heterocycles;Intermediates & Fine Chemicals;Pharmaceuticals;Active Pharmaceutical Ingredients
Mol File:3366-95-8.mol
alpha,2-Dimethyl-5-nitro-1H-imidazole-1-ethanol Structure
alpha,2-Dimethyl-5-nitro-1H-imidazole-1-ethanol Chemical Properties
Melting point 76°C
Boiling point 396.1±22.0 °C(Predicted)
density 1.39±0.1 g/cm3(Predicted)
storage temp. Inert atmosphere,Room Temperature
solubility Chloroform (Sparingly), Methanol (Sparingly)
pka14.50±0.20(Predicted)
form Solid
color White to Light Yellow
Water Solubility H2O: 2mg/mL, clear (warmed)
λmax319nm(H2O)(lit.)
Merck 14,8419
InChIInChI=1S/C7H11N3O3/c1-5(11)4-9-6(2)8-3-7(9)10(12)13/h3,5,11H,4H2,1-2H3
InChIKeyKPQZUUQMTUIKBP-UHFFFAOYSA-N
SMILESC(N1C(=NC=C1N(=O)=O)C)C(O)C
CAS DataBase Reference3366-95-8(CAS DataBase Reference)
Safety Information
HS Code 2933.29.2000
MSDS Information
alpha,2-Dimethyl-5-nitro-1H-imidazole-1-ethanol Usage And Synthesis
Chemical PropertiesCrystalline Solid
UsesAnalog of Metronidazole. Antiamebic. Antiprotozoal (Trichomonas).
Usesantiameobic, antitrichomonas
DefinitionChEBI: Secnidazole is a C-nitro compound that is 5-nitroimidazole in which the hydrogens at positions 1 and 2 are replaced by 2-hydroxypropyl and methyl groups, respectively. It has a role as an epitope. It is a C-nitro compound, a member of imidazoles and a secondary alcohol.
Pharmaceutical ApplicationsA 5-nitroimidazole with properties similar to those of metronidazole. It is rapidly absorbed after oral administration and is distinguished by having the longest plasma half-life (18 h) of clinically used nitroimidazole drugs. It is used in the treatment of intestinal amebiasis, giardiasis, trichomoniasis and bacterial vaginosis.
Biological ActivitySecnidazole is a nitroimidazole anti-microbial selective against many anaerobic Gram-positive and Gram-negative bacteria and protozoa. It has been approved for the treatment of bacterial vaginosis. Secnidazole is a prodrug, whose nitro group is reduced by bacterial enzymes to radical anions th at interfere with bacterial DNA synthesis.
Synthesis
1-BROMO-2-PROPANOL

19686-73-8

2-Methyl-4-nitroimidazole

696-23-1

alpha,2-Dimethyl-5-nitro-1H-imidazole-1-ethanol

3366-95-8

In a 10 L glass reactor, 2-methyl-5-nitroimidazole (635 g), 1-bromo-2-propanol (2070 g), potassium carbonate (2114 g) and acetone (7.1 L) were added in a molar ratio of 1:3:3:20. The reaction mixture was heated to 70 °C and refluxed for 5 h under stirring conditions. The progress of the reaction was monitored by TLC (GF254 silica gel plate, unfolding agent was chloroform:ethanol=85:15) to confirm the completion of the reaction to obtain the reaction mixture A. Acetone was recovered by distillation under reduced pressure to obtain the reaction mixture B. 9 L of water was added to the reaction mixture B, cooled down to 0 °C and centrifuged to obtain the wet product. The wet product was washed with cold water and centrifuged again after stirring at 1 °C for 3 h to obtain 1-(2-methyl-5-nitro-1H-imidazol-1-yl)propan-2-ol crude product. The crude product was transferred to a 5L reactor, 40% ethanol (3L) and activated carbon (30g) were added, heated to 70°C refluxed to dissolve and then hot filtered. The filtrate was cooled to 0°C for crystallization for 3 h. After centrifugal separation, the product was dried under vacuum at 40°C to obtain the pure Secnidazole. After weighing, the mass of the final product was 820 g, and the total yield was 89.1%.

References[1] Patent: CN103772289, 2016, B. Location in patent: Paragraph 0036-0042
alpha,2-Dimethyl-5-nitro-1H-imidazole-1-ethanol Preparation Products And Raw materials
Raw materials1-BROMO-2-PROPANOL-->2-Methyl-4-nitroimidazole-->Acetone-->Potassium carbonate
Tag:alpha,2-Dimethyl-5-nitro-1H-imidazole-1-ethanol(3366-95-8) Related Product Information
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