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| | PHENYL AZIDE Basic information |
| | PHENYL AZIDE Chemical Properties |
| Melting point | -27.5°C | | Boiling point | 212.39°C (rough estimate) | | density | 1.0860 | | vapor density | 73.5 at 22-24 mm | | refractive index | 1.5589 | | Fp | -12°C | | storage temp. | -20°C | | form | liquid | | color | Pale-yellow oil | | BRN | 742248 |
| | PHENYL AZIDE Usage And Synthesis |
| Uses | Phenylazide in greener solvent, 2-methyltetrahydrofuran (2-MeTHF).
2-Methyltetrahydrofuran (2-MeTHF): A Biomass-Derived Solvent with Broad Application in Organic Chemistry | | Synthesis Reference(s) | Journal of the American Chemical Society, 89, p. 5284, 1967 DOI: 10.1021/ja00996a036
Tetrahedron Letters, 27, p. 4749, 1986 DOI: 10.1016/S0040-4039(00)85055-8 | | General Description | Azidobenzene solution can undergo click reaction with alkyne-functionalized oligomers to form O-ester-functionalized o-phenylenes, a group of aromatic foldamers with a good folding tendency in most solvents. | | Safety Profile | Explodes when heated.Explosive or violent reactions with Lewis acids [e.g., aluminum chloride (explosive); sulfuric acid (violent)]. When heated to decomposition it emits toxic fumes of NOx. |
| | PHENYL AZIDE Preparation Products And Raw materials |
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