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2,3-Dibromo-1-propanol

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CAS:96-13-9
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CAS:96-13-9
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2,3-Dibromo-1-propanol manufacturers

2,3-Dibromo-1-propanol Basic information
Product Name:2,3-Dibromo-1-propanol
Synonyms:beta-dibromohydrin;Glycerol 1,2-dibromohydrin;GLYCEROL ALPHA,BETA-DIBROMOHYDRIN;1,2-DIBROMOHYDRIN;2,3-DIBROMOPROPANOL;2,3-DIBROMO-1-PROPANOL;ALPHA,BETA-DIBROMOHYDRIN;dbp(flameretardant)
CAS:96-13-9
MF:C3H6Br2O
MW:217.89
EINECS:202-480-9
Product Categories:Alcohols;C2 to C6;Oxygen Compounds;bc0001
Mol File:96-13-9.mol
2,3-Dibromo-1-propanol Structure
2,3-Dibromo-1-propanol Chemical Properties
Melting point 9 °C
Boiling point 95-97 °C/10 mmHg (lit.)
density 2.12 g/mL at 25 °C (lit.)
refractive index n20/D 1.559(lit.)
Fp >230 °F
storage temp. Keep in dark place,Inert atmosphere,Room temperature
form clear liquid
pka13.69±0.10(Predicted)
color Colorless to Light yellow
Water Solubility 5-10 g/100 mL at 20 ºC
BRN 1719127
CAS DataBase Reference96-13-9(CAS DataBase Reference)
IARC2B (Vol. 77) 2000
NIST Chemistry Reference1-Propanol, 2,3-dibromo-(96-13-9)
EPA Substance Registry System2,3-Dibromopropanol (96-13-9)
Safety Information
Hazard Codes T
Risk Statements 45-20/22-24-52/53-62
Safety Statements 53-45-61
RIDADR UN 2810 6.1/PG 2
WGK Germany 3
RTECS UB0175000
HazardClass 6.1(b)
PackingGroup III
HS Code 29055900
Hazardous Substances Data96-13-9(Hazardous Substances Data)
MSDS Information
ProviderLanguage
Glycerol 1,2-dibromohydrin English
SigmaAldrich English
2,3-Dibromo-1-propanol Usage And Synthesis
Chemical Propertiesclear colorless liquid
Chemical Properties2,3-Dibromo-1-propanol is a clear, colorless to slightly yellow thick liquid.
Uses2,3-Dibromo-1-propanol is a metabolite of the flame retardant tris(2,3-dibromopropyl) phosphate (T775560), previously shown to be a mutagen and carcinogen in experimental animals.
UsesSynthetic building block, fire-proofing agent, and carcinogen.
UsesThe major use of 2,3-dibromo-1-propanol is as an intermediate in the production of flame retardants, insecticides, and pharmaceuticals, and the chemical itself has been used as a flame retardant. 2,3-Dibromo-1-propanol was used in the production of tris(2,3-dibromopropyl) phosphate, a flame retardant used in children’s clothing and other products (HSDB 2009). Tris(2,3-dibromopropyl) phosphate was banned from use in sleepwear in 1977 by the Consumer Product Safety Commission after studies showed that it causedcancer in experimental animals (NTP 1993, HSDB 2009).
Synthesis Reference(s)The Journal of Organic Chemistry, 30, p. 587, 1965 DOI: 10.1021/jo01013a069
General DescriptionClear colorless to slightly yellow viscous liquid.
Air & Water ReactionsWater soluble.
Reactivity Profile2,3-Dibromo-1-propanol is incompatible with strong oxidizers.
Fire Hazard2,3-Dibromo-1-propanol is probably combustible.
Potential ExposureChemical intermediate used to pro- duce insecticides, pharmaceuticals, and flame retardants.
Carcinogenicity2,3-Dibromo-1-propanol is reasonably anticipated to be a human carcinogen based on sufficient evidence of carcinogenicity from studies in experimental animals.
ShippingUN2810 Toxic liquids, organic, n.o.s., Hazard Class: 6.1; Labels: 6.1-Poisonous materials, Technical Name Required.
IncompatibilitiesIncompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explo- sions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, and epoxides.
Waste DisposalUse a licensed professional waste disposal service to dispose of this material. Dissolve or mix the material with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber. All federal, state, and local environmental regulations must be observed.
2,3-Dibromo-1-propanol Preparation Products And Raw materials
Raw materialsGovernment regulation-->Carbon tetrachloride-->Allyl alcohol
Preparation Products1,2-DINITROGLYCERIN-->3-BROMO-1,2-PROPANEDIOL-->1,4-ditosyl-1,4-diazepan-6-ol
Tag:2,3-Dibromo-1-propanol(96-13-9) Related Product Information
3,5-Dibromo-4-hydroxybenzaldehyde 1-PHENYL-2-PROPANOL 2,3-Dibromopropionic acid 1,2-Dibromopropane 1,3-Dibromo-5,5-dimethylhydantoin 2,2-Bis(bromomethyl)propane-1,3-diol 1-Propanol Glycerol 1,3-Dibromopropane meso-2,3-Dibromosuccinic acid 2,3-DIBROMOPROPYL ACRYLATE ETHYL 2,3-DIBROMOBUTYRATE ETHYL 2,3-DIBROMO-3-PHENYLPROPIONATE Ethyl 2,3-dibromopropionate 2,3-DIBROMOBUTYRIC ACID 2,3-Dibromo-1,4-butanediol Methyl 2,3-dibromopropionate Tris(2,3-dibromopropyl)phosphate