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| | (S)-(-)-N,ALPHA-DIMETHYLBENZYLAMINE Basic information |
| Product Name: | (S)-(-)-N,ALPHA-DIMETHYLBENZYLAMINE | | Synonyms: | (S)-N-METHYL-1-PHENYLETHANAMINE;S(-)-N-METHYL-1-PHENYLETHYLAMINE;(S)(-)-N-METHYL-ALPHA-PHENETHYLAMINE;(S)-N-METHYL-ALPHA-PHENYLETHYLAMINE;(S)-(-)-N-METHYL A-METHYLBENZYLAMINE;(S)-(-)-N,ALPHA-DIMETHYLBENZYLAMINE;(1S)-N-Methyl-1-phenylethanamine;(S)-(-0-N,α-DIMETHYLBENZYLAMINE | | CAS: | 19131-99-8 | | MF: | C9H13N | | MW: | 135.21 | | EINECS: | | | Product Categories: | Chiral Compound | | Mol File: | 19131-99-8.mol |  |
| | (S)-(-)-N,ALPHA-DIMETHYLBENZYLAMINE Chemical Properties |
| Melting point | 116°C (estimate) | | alpha | -72o (C=2 IN CHLOROFORM) | | Boiling point | 74-76 °C11 mm Hg(lit.) | | density | 0.928 g/mL at 20 °C(lit.) | | refractive index | n20/D 1.512(lit.) | | Fp | 143 °F | | storage temp. | Keep in dark place,Inert atmosphere,Room temperature | | pka | 9.77±0.10(Predicted) | | form | clear liquid | | color | Colorless to Almost colorless | | optical activity | [α]20/D 73±5°, c = 2 in chloroform | | BRN | 1446867 |
| Hazard Codes | C | | Risk Statements | 20/21/22-34 | | Safety Statements | 26-36-45 | | RIDADR | UN 2619 8/PG 2 | | WGK Germany | 3 | | F | 10-23 | | HazardClass | IRRITANT | | HS Code | 29214990 |
| | (S)-(-)-N,ALPHA-DIMETHYLBENZYLAMINE Usage And Synthesis |
| Uses | Used to make asymmetric organometallic catalysts (e.g., for conjugate additions to enones). | | General Description | (S)-(-)-N,a-Dimethylbenzylamine may be used along with benzaldehyde in the Mannich-type aminoalkylation of 2-naphthol to form 1-((S)-phenyl(((1′S)-1′-phenylethyl)methylamino)methyl)-2-naphthol. This optically active tertiary aminonaphthol can catalyze the enantioselective alkenylation of various aldehyde to generate chiral (E)- allyl alcohols. |
| | (S)-(-)-N,ALPHA-DIMETHYLBENZYLAMINE Preparation Products And Raw materials |
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