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Bis(1,5-cyclooctadiene)rhodium(I) trifluoromethanesulfonate

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Products Intro: Product Name:Bis(1,5-cyclooctadiene)rhodium(I) trifluoromethanesulfonate
CAS:99326-34-8
Purity:98% Min. Package:1G;1KG;100KG
Company Name: Shanghai Daken Advanced Materials Co.,Ltd
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Products Intro: Product Name:Bis(1,5-cyclooctadiene)rhodium(I) trifluoromethanesulfonate
CAS:99326-34-8
Purity:99% Package:100g ;1KG ;5KG 25KG Remarks:Catalysts
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Products Intro: Product Name:Bis(1,5-cyclooctadiene)rhodium(I) trifluoromethanesulfonate
CAS:99326-34-8
Purity:99% Package:25KG;5KG;1KG
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Products Intro: Product Name:Bis(1,5-cyclooctadiene)rhodium(I) trifluoromethanesulfonate
CAS:99326-34-8
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Products Intro: Product Name:Bis(1,5-cyclooctadiene)rhodium(I) trifluoromethanesulfonate
CAS:99326-34-8
Purity:0.99 Package:5KG;1KG

Bis(1,5-cyclooctadiene)rhodium(I) trifluoromethanesulfonate manufacturers
Bis(1,5-cyclooctadiene)rhodium(I) trifluoromethanesulfonate Basic information
Reaction
Product Name:Bis(1,5-cyclooctadiene)rhodium(I) trifluoromethanesulfonate
Synonyms:Bis(1,5-cyclooctadiene)rhodium(I)trifluoromethanesulphonate99%;Bis-(1,5-cyclooctadiene)-rhodium trifluoromethanesulfonate;BIS(1,5-CYCLOOCTADIENE)RHODIUM(I)TRIFLUOROMETHANESULFONATE;BIS(1,5-CYCLOOCTADIENE)-TRIFLUOROMETHANESULFITORHODIUM (I);BIS(1,5-CYCLOOCTADIENE)RHODIUM(I) TRIFL&;Bis(1,5-cyclooctadiene)rhodium(I)trifluoromethanesulfonate,99%;Bis(1,5-cyclooctadiene)rhodium(I) trifluoromethane sulphonate 99%;Bis(1,5-cyclooctadiene)rhodiuM(I) trifluoroMethanesulfonate 98%
CAS:99326-34-8
MF:C17H24F3O3RhS
MW:468.34
EINECS:
Product Categories:Rh;organometallic complex;Catalysis and Inorganic Chemistry;Chemical Synthesis;Rhodium
Mol File:99326-34-8.mol
Bis(1,5-cyclooctadiene)rhodium(I) trifluoromethanesulfonate Structure
Bis(1,5-cyclooctadiene)rhodium(I) trifluoromethanesulfonate Chemical Properties
Melting point 159 °C (dec.)(lit.)
storage temp. Inert atmosphere,Room Temperature
solubility Soluble in chloroform
form crystal
color dark red
Water Solubility insoluble
Sensitive Air Sensitive
Exposure limitsACGIH: TWA 1 mg/m3
NIOSH: IDLH 100 mg/m3; TWA 0.1 mg/m3
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26
WGK Germany 3
Hazard Note Irritant
TSCA No
HS Code 28439000
MSDS Information
ProviderLanguage
ACROS English
SigmaAldrich English
ALFA English
Bis(1,5-cyclooctadiene)rhodium(I) trifluoromethanesulfonate Usage And Synthesis
Reaction
  1. Rhodium catalyzed contrasteric regiocontrolled hydrogenative couplings of nonsymmetric 1,3-diynes to ethyl glyoxalate
  2. Rhodium catalyzed reductive Mannich coupling of vinyl ketones to N-Sulfonylimines mediated by hydrogen
  3. Rhodium catalyzed asymmetric synthesis of Sitagliptin
  4. Rhodium catalyzed asymmetric hydrogenation of tetrasubstituted α,β-unsaturated ketones
Reactions of 99326-34-8_1
Reactions of 99326-34-8_2
Chemical Propertiesdark red crystals
UsesUmicore Precatalysts for Asymmetric and Cross-Coupling Catalysis
Bis(1,5-cyclooctadiene)rhodium(I) trifluoromethanesulfonate Preparation Products And Raw materials
Tag:Bis(1,5-cyclooctadiene)rhodium(I) trifluoromethanesulfonate(99326-34-8) Related Product Information
Trifluoromethanesulfonic acid 1,5-Cyclooctadiene Levofloxacin Methylate Rhodium Pefloxacin mesylate Trifluoromethanesulfonic anhydride 1,3-CYCLOOCTADIENE Danofloxacin mesylate BIS(1,5-CYCLOOCTADIENE)IRIDIUM (I) TETRAFLUOROBORATE Chloro(1,5-cyclooctadiene)iridium(I) dimer Bis[1,2-bis(diphenylphosphino)ethane]palladium(0) Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate BIS(1 5-CYCLOOCTADIENE)RHODIUM(I) Bis(1,5-cyclooctadiene)bis(μ-diphenylphosphido)dirhodium Trifluoromethane Bis(1,5-cyclooctadiene)rhodium(I) trifluoromethanesulfonate