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Benzyl formate

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CAS:104-57-4
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Benzyl formate manufacturers

  • Benzyl formate
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  • $1.00 / 1mL
  • 2024-01-08
  • CAS:104-57-4
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  • Benzyl formate
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  • $150.00 / 1kg
  • 2023-08-10
  • CAS:104-57-4
  • Min. Order: 1kg
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  • Benzyl formate
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  • 2023-02-13
  • CAS:104-57-4
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Benzyl formate Basic information
Product Name:Benzyl formate
Synonyms:benzylalcohol,formate;Benzylester kyseliny mravenci;benzylesterkyselinymravenci;Benzylformiat;Formicacid,phenylmethylester;formicacidphenylmethylester;BENZYL FORMATE;Benzyl methanoater
CAS:104-57-4
MF:C8H8O2
MW:136.15
EINECS:203-214-4
Product Categories:Industrial/Fine Chemicals;A-B;Alphabetical Listings;Flavors and Fragrances
Mol File:104-57-4.mol
Benzyl formate Structure
Benzyl formate Chemical Properties
Melting point 3.6℃
Boiling point 203 °C(lit.)
density 1.088 g/mL at 25 °C(lit.)
vapor pressure 1.69hPa at 20℃
FEMA 2145 | BENZYL FORMATE
refractive index n20/D 1.511(lit.)
Fp 180 °F
storage temp. Inert atmosphere,Room Temperature
form clear liquid
Specific Gravity1.091 (20/4℃)
color Colorless liquid
Odorpowerful fruity, spicy odor
Odor Typefloral
Water Solubility Insoluble in water, soluble in organic solvents, oils.
Merck 14,1134
JECFA Number841
BRN 2041319
LogP1.79 at 21.9℃
CAS DataBase Reference104-57-4(CAS DataBase Reference)
NIST Chemistry ReferenceFormic acid, phenylmethyl ester(104-57-4)
EPA Substance Registry SystemFormic acid, phenylmethyl ester (104-57-4)
Safety Information
Hazard Codes Xn
Risk Statements 21/22
Safety Statements 36-36/37-23
RIDADR NA 1993 / PGIII
WGK Germany 1
RTECS LQ5400000
TSCA Yes
HS Code 29151300
ToxicityLD50 orl-rat: 1400 mg/kg FCTXAV 11,1019,73
MSDS Information
ProviderLanguage
SigmaAldrich English
ALFA English
Benzyl formate Usage And Synthesis
Chemical PropertiesBenzyl formate has an intense, pleasant, floral-fruity odor and sweet taste reminiscent of apricot and pineapple.
Chemical PropertiesColorless liquid; fruity-spicy odor. Resembles benzyl acetate in many respects but differs in its greater volatility. Miscible with alcohols, ketones, oils, aromatic, aliphatic and halogenated hydrocarbons; insoluble in water.
OccurrenceReported found in the oil of Rosa rugosa, sour cherry, American cranberry, ligonberry, coffee, black tea, Agaricus mushroom, Ocimum basilicum, Bourbon vanilla and crowberry (Empetrum nigrum Coll.).
UsesSolvent for cellulose esters; in perfumery.
DefinitionChEBI: Benzylformate is a carboxylic ester. It is functionally related to a benzyl alcohol.
PreparationBy heating a mixture of formic/acetic anhydride and benzyl alcohol to 50°C; by passing a mixture of formic acid and excess benzyl alcohol over a catalyst (ThO2 or TiO2) at high temperature.
Taste threshold valuesTaste characteristics at 10 ppm: fresh cherry with a berry, strawberry fruity nuance.
Synthesis Reference(s)Journal of the American Chemical Society, 82, p. 2380, 1960 DOI: 10.1021/ja01494a065
The Journal of Organic Chemistry, 55, p. 2952, 1990 DOI: 10.1021/jo00296a072
HazardMay be narcotic in high concentration.
Safety ProfileModerately toxic by ingestion andskin contact. Mutation data reported. Probably narcotic inhigh concentrations. When heated todecomposition it emits acrid, irritating fumes.
Tag:Benzyl formate(104-57-4) Related Product Information
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