- 1,2-Cyclohexanedione
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- $0.00 / 1kg
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2023-05-23
- CAS:765-87-7
- Min. Order: 1kg
- Purity: 98%
- Supply Ability: 1MT
- 1,2-Cyclohexanedione
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- $0.00 / 1kg T
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2023-03-21
- CAS:765-87-7
- Min. Order: 1kg T
- Purity: 96%MIN
- Supply Ability: 20TONS
- 1,2-Cyclohexanedione
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- $0.00 / 1kg
-
2022-10-18
- CAS:765-87-7
- Min. Order: 1kg
- Purity: 98%
- Supply Ability: 1Ton
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| | 1,2-Cyclohexanedione Basic information |
| Product Name: | 1,2-Cyclohexanedione | | Synonyms: | 1,2-Cyclohexanedione, 98+%;1,2-Cyclohexanedione,97%;1,2-Cyclohexanedione, 98% 10GR;Two1,2-cyclohexylketone;1,2-Cyclohexanedione 97%;1,2-Cyclohexadione;1,2-Dioxocyclohexane;1,2-CYCLOHEXANEDIONE | | CAS: | 765-87-7 | | MF: | C6H8O2 | | MW: | 112.13 | | EINECS: | 212-155-3 | | Product Categories: | C3 to C6Protein Modification;Reagents for arginine modification;Carbonyl Compounds;Ketones;Specific Amino Acid Modification;Ketone;Pharmaceutical intermediate | | Mol File: | 765-87-7.mol |  |
| | 1,2-Cyclohexanedione Chemical Properties |
| Hazard Codes | Xi,Xn | | Risk Statements | 22 | | Safety Statements | 24/25 | | WGK Germany | 3 | | RTECS | GV0340000 | | F | 8 | | Hazard Note | Irritant | | TSCA | Yes | | HS Code | 29142990 |
| | 1,2-Cyclohexanedione Usage And Synthesis |
| Chemical Properties | clear yellow liquid after melting | | Uses | 1,2-Cyclohexanedione is utilized as a substrate to study enzyme cyclohexane-1,2-dione hydrolase, which is a new tool to degrade alicyclic compounds. It also acts as a specific reagent for arginine residues. | | Uses | 1,2-Cyclohexanedione have been used as a substrate to study enzyme cyclohexane-1,2-dione hydrolase as a new tool to degrade alicyclic compounds. | | Definition | ChEBI: Cyclohexane-1,2-dione is a cyclohexanedione carrying oxo substituents at positions 1 and 2. | | Reactions |
1,2-Cyclohexanedione may effectively occupy vacant coordination sites and thus promote the present cycloisomerization[1]. Tanaka et al. research the catalytic cycloisomerization of 1,6- and 1,7-diynes leading to trienes and vinylpyrroles by using a cationic rhodium(I)/Segphos complex (2.5-10 mol %) and 1,2-cyclohexanedione (100 mol %).
| | Synthesis Reference(s) | Journal of the American Chemical Society, 73, p. 4658, 1951 DOI: 10.1021/ja01154a048
Tetrahedron Letters, 25, p. 603, 1984 DOI: 10.1016/S0040-4039(00)99949-0
The Journal of Organic Chemistry, 39, p. 3295, 1974 DOI: 10.1021/jo00936a034 | | References |
[1] Ken Tanaka, Masao Hirano, Yousuke Otake. “Cationic Rhodium(I)/Segphos-Catalyzed Cycloisomerization of 1,6- and 1,7-Diynes in the Presence of 1,2-Cyclohexanedione.” Organic Letters 9 20 (2007): 3953–3956.
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| | 1,2-Cyclohexanedione Preparation Products And Raw materials |
| Raw materials | Cyclohexanone-->Selenium dioxide | | Preparation Products | 1,2-CYCLOHEXANEDIONE DIOXIME-->1,2,3,4-tetrahydro-Phenazine-->Adipaldehyde-->6-BROMO-2,3,4,9-TETRAHYDRO-1H-CARBAZOL-1-ONE-->2H-Pyran-2-one, tetrahydro-6-pentadecyl--->6-NITRO-2,3,4,9-TETRAHYDRO-1H-CARBAZOL-1-AMINE-->1-Methyl-decahydro-quinoxaline-->2-HYDROXY-3-P-TOLYL-CYCLOHEX-2-ENONE |
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