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3-Nitrotoluene

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CAS:99-08-1
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Products Intro: Product Name:3-Nitrotoluene
CAS:99-08-1
Purity:1000 μg/ML in MeOH:AcCN (1:1) Package:1ML
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Products Intro: Product Name:3-Nitrotoluene
CAS:99-08-1
Purity:99.0% GC Package:25G,500G
3-Nitrotoluene Basic information
Product Name:3-Nitrotoluene
Synonyms:m-mononitrotoluene;m-nitro-toluen;MNT;nsc9578;Toluene, m-nitro-;toluene,3-nitro-;3-NITROTOLUENE;3-METHYLNITROBENZENE
CAS:99-08-1
MF:C7H7NO2
MW:137.14
EINECS:202-728-6
Product Categories:Industrial/Fine Chemicals;Aromatic Hydrocarbons (substituted) & Derivatives;Organics;Method 8330Alphabetic;NA - NIAnalytical Standards;8000 Series Solidwaste Methods;Analytical Standards;AromaticsEnvironmental Standards;Chemical Class;Environmental Standards;ExplosivesEPA;N;Nitro CompoundsChromatography;Solid WasteMore...Close...;Volatiles/ Semivolatiles
Mol File:99-08-1.mol
3-Nitrotoluene Structure
3-Nitrotoluene Chemical Properties
Melting point 15 °C
Boiling point 230-231 °C(lit.)
density 1.157 g/mL at 25 °C(lit.)
vapor density 4.73 (vs air)
vapor pressure 1 mm Hg ( 50.2 °C)
refractive index n20/D 1.541(lit.)
Fp 215 °F
storage temp. 2-8°C
solubility 0.419g/l
form Liquid
color Clear yellow to yellow-brownish
explosive limit2.2%(V)
Water Solubility insoluble
Merck 14,6650
BRN 1906910
Stability:Stable. Combustible. Incompatible with reducing agents, strong oxidizing agents, strong bases.
CAS DataBase Reference99-08-1(CAS DataBase Reference)
NIST Chemistry ReferenceBenzene, 1-methyl-3-nitro-(99-08-1)
EPA Substance Registry SystemBenzene, 1-methyl-3-nitro-(99-08-1)
Safety Information
Hazard Codes T,F,Xn
Risk Statements 23/24/25-33-51/53-36/37/38-11-36-20/21/22
Safety Statements 36/37-45-61-37-28A-27-16-26
RIDADR UN 1664 6.1/PG 2
WGK Germany 2
RTECS XT2975000
TSCA Yes
HazardClass 6.1
PackingGroup II
HS Code 29042000
Hazardous Substances Data99-08-1(Hazardous Substances Data)
MSDS Information
ProviderLanguage
m-Nitrophenylmethane English
SigmaAldrich English
ACROS English
ALFA English
3-Nitrotoluene Usage And Synthesis
Chemical Propertiesyellow-green liquid
Chemical PropertiesNitrotoluene is formed in 3 isomeric forms. The o-and m-forms are yellow liquids or solids. The p-form is a pale yellow crystalline solid. All have weak aromatic odors. The Odor Thresholds are: 0.05 mg/L (o-isomer); 1.74 ppm (m-isomer).
UsesOrganic synthesis.
DefinitionChEBI: A mononitrotoluene carrying a nitro group at position 3.
General DescriptionYellow crystals that melt at 59°F to a yellow liquid. Often therefore encountered as a liquid. Flash point 223°F. Boiling point 450°F. Insoluble in water. Toxic by inhalation and ingestion.
Air & Water ReactionsInsoluble in water.
Reactivity Profile3-Nitrotoluene reacts with sulfuric acid, strong oxidizing agents and reducing agents.
HazardToxic by inhalation, ingestion, skin absorption. Methemoglobinemia. Probable carcinogen.
Health HazardINHALATION, INGESTION OR SKIN ABSORPTION: Headache, flushing of face, dizziness, difficult breathing, cyanosis, nausea, vomiting, muscular weakness, increased pulse and respiratory rate, irritability and convulsions. EYES: Slight irrita- tion. SKIN: Slight irritation.
Potential ExposureThe nitrotoluenes are used in the production of toluidines and other dye intermediates. All isomers are used in manufacture of agriculture and rubber chemicals and in various dyes.
First aidIf this chemical gets into the eyes, remove any contact lenses at once and irrigate immediately for at least 15 minutes, occasionally lifting upper and lower lids. Seek medical attention immediately. If this chemical contacts the skin, remove contaminated clothing and wash immediately with soap and water. Seek medical attention immediately. If this chemical has been inhaled, remove from exposure, begin rescue breathing (using universal precautions, including resuscitation mask) if breathing has stopped and CPR if heart action has stopped. Transfer promptly to a medical facility. When this chemical has been swallowed, get medical attention. Give large quantities of water and induce vomiting. Do not make an unconscious person vomit.
ShippingUN1664 Nitrotoluenes, (o-; m-; p-), Hazard Class: 6.1; Labels: 6.1-Poisonous materials.
Purification MethodsDry 3-nitrotoluene over P2O5 for 24hours, then fractionally distil it under reduced pressure. [Clark & Taylor Org. Synth Coll Vol I 415 1941, Beilstein 5 IV 847.]
IncompatibilitiesDecomposes on contact with strong oxidizers; strong acids; reducing agents; strong bases; ammonia, amines producing toxic fumes, causing fire and explosion hazard. Heat above 190C may cause explosive decomposition. Attacks some plastics, rubbers, and coatings.
Waste DisposalControlled incineration-care must be taken to maintain complete combustion at all times. Incineration of large quantities may require scrubbers to control the emission of nitrogen oxides.
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