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Chloro[(S)-(-)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl](p-cymene)ruthenium(II)chloride

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Products Intro: Product Name:Chloro[(S)-(-)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl](p-cymene)ruthenium(II)chloride
CAS:228120-95-4
Purity:98% Package:1KG;1USD
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Products Intro: Product Name:(S)-RuCl[(p-cymene)(T-BINAP)]Cl
CAS:228120-95-4
Purity:0.99 Package:5KG;1KG
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Products Intro: Product Name:Chloro[(S)-(-)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl](p-cymene)ruthenium(II)chloride
CAS:228120-95-4
Purity:0.98 Package:1kg，2kg，5kg，10kg，25kg
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Products Intro: Product Name:Chloro[(S)-(-)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl](p-cymene)ruthenium(II)chloride
CAS:228120-95-4
Purity:99%min Package:100g/bottle;500g/bottle;1kg/bottle;10kg/drum;50kg/drum;100kg/drum;1199T/drum;
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Products Intro: Product Name:Chloro[(S)-(-)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl](p-cymene)ruthenium(II)chloride
CAS:228120-95-4

Chloro[(S)-(-)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl](p-cymene)ruthenium(II)chloride manufacturers
Chloro[(S)-(-)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl](p-cymene)ruthenium(II)chloride Basic information
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Product Name:Chloro[(S)-(-)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl](p-cymene)ruthenium(II)chloride
Synonyms:Chloro[(S)-(-)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl](p-cymene)ruthenium(II)chloride;(S)-RuCl[(p-cymene)(T-BINAP)]Cl;[RuCl(p-cymene)((S)-tolbinap)]Cl;Chloro[(S)-(-)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl](p-cymene)ruthenium(II) chloride [RuCl(p-cymene)((S)-tolbinap)]Cl;-binaphthyl](p-cymene)ruthenium(II) chloride,[RuCl(p-cymene)((S)-tolbinap)]Cl;Chloro[(S)-(-)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl](p-cymene)ruthenium(II)chloride
CAS:228120-95-4
MF:C58H52Cl2P2Ru
MW:982.97
EINECS:
Product Categories:Ru
Mol File:228120-95-4.mol
Chloro[(S)-(-)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl](p-cymene)ruthenium(II)chloride Structure
Chloro[(S)-(-)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl](p-cymene)ruthenium(II)chloride Chemical Properties
Melting point >100°C
storage temp. 2-8°C
Water Solubility Insoluble in water
form solid
color yellow to dark brown
Sensitive air sensitive
Safety Information
WGK Germany 3
HS Code 2843.90.0000
MSDS Information
Chloro[(S)-(-)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl](p-cymene)ruthenium(II)chloride Usage And Synthesis
Reactions1. Useful ligand for palladium-catalyzed carbon-oxygen bond formation.
2. Ligand for palladium-catalyzed α-arylation of ketones.
3. Ligand for Cu-catalyzed asymmetric conjugate reduction.
4. Ligand for Cu-catalyzed asymmetric dienolate addition to aldehydes.
5. Enantioselective conjugate reduction of lactones and lactams.
6. Ligand used in the enantioselective cycloaddition of allenylsilanes with α-Imino esters.
7. Catalytic Aldol reaction to ketones.
8. Ligand with rhodium catalyses [2+2+2] cycloaddition reaction of alkenes and alkynes.
9. Ligand used in the iridium-catalyzed enantioselective C-H bond activation of 2-(alkylamino)-pyridine with alkenes.
10. Iridium-catalyzed regio-, diastereo-, and enantioselective tert-(hydroxyl)-prenylation of alcohols.
11. Rhodium-catalyzed cross cyclotrimerization.
Reactions of 228120-95-4_1
Reactions of 228120-95-4_2
UsesTakasago Ligands and Complexes for Asymmetric Reactions
Chloro[(S)-(-)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl](p-cymene)ruthenium(II)chloride Preparation Products And Raw materials
Tag:Chloro[(S)-(-)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl](p-cymene)ruthenium(II)chloride(228120-95-4) Related Product Information
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