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(Bromomethyl)cyclopropane

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(Bromomethyl)cyclopropane Basic information
Uses Description
Product Name:(Bromomethyl)cyclopropane
Synonyms:CPMBr;Cyclopropylcarbinyl bromide;Bromo(cyclopropyl)methane;1-(Bromomethyl)cyclopropane, 95+%;(Bromomethyl)cyclopropane,Cyclopropylmethyl bromide;(Bromomethyl)cyclopr;(Bromomethyl)cyclopropane,96%;Cyclopropane Methyl Chloride
CAS:7051-34-5
MF:C4H7Br
MW:135
EINECS:230-331-8
Product Categories:Methyl Halides;Halides;Methyl Halides;Ring Systems;Cycloalkanes;Miscellaneous Reagents;bc0001
Mol File:7051-34-5.mol
(Bromomethyl)cyclopropane Structure
(Bromomethyl)cyclopropane Chemical Properties
Melting point 87-90 °C
Boiling point 105-107 °C(lit.)
density 1.392 g/mL at 25 °C(lit.)
refractive index n20/D 1.457(lit.)
Fp 107 °F
storage temp. Inert atmosphere,2-8°C
solubility Chloroform (Slightly), Methanol (Slightly)
form Liquid
Specific Gravity1.392
color Clear colorless to slightly colored
Water Solubility Not miscible in water.
BRN 605296
Stability:Stable. Flammable. Incompatible with strong bases, strong oxidizing agents.
InChIKeyAEILLAXRDHDKDY-UHFFFAOYSA-N
CAS DataBase Reference7051-34-5(CAS DataBase Reference)
NIST Chemistry ReferenceCyclopropane, (bromomethyl)-(7051-34-5)
Safety Information
Hazard Codes Xi,F,Xn
Risk Statements 10-36/37/38-22
Safety Statements 23-24/25-37/39-26-16-36/37/39
RIDADR UN 1993 3/PG 3
WGK Germany 3
Hazard Note Irritant
HazardClass 3
PackingGroup III
HS Code 29035990
MSDS Information
ProviderLanguage
1-(Bromomethyl)cyclopropane English
SigmaAldrich English
ACROS English
ALFA English
(Bromomethyl)cyclopropane Usage And Synthesis
Uses

(Bromomethyl)cyclopropane is used in the synthesis of 1,4-dienes by iron-catalyzed cross-coupling with alkenyl Grignard reagents.

Description(Bromomethyl) cyclopropane is a cyclopropane derivative. It can be used as a synthetic building block for the introduction of the cyclopropylmethyl group. It was also used in the synthesis of 1, 4-dienes via iron-catalyzed cross-coupling with alkenyl Grignard reagents.
Chemical PropertiesColorless to yellow liquid
Uses(Bromomethyl)cyclopropane was used as a synthetic building block for the introduction of the cyclopropylmethyl group. It was also used in the synthesis of 1,4-dienes via iron-catalyzed cross-coupling with alkenyl Grignard reagents.
Synthesis Reference(s)Tetrahedron Letters, 13, p. 2135, 1972 DOI: 10.1016/S0040-4039(01)84787-0
General DescriptionThe coupling reaction of (bromomethyl)cyclopropane with phenylmagnesium bromide was studied.
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