Dimethyl chloromalonate

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Products Intro: Product Name:Dimethyl chloromalonate
CAS:28868-76-0
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Products Intro: Product Name:Dimethyl chloromalonate
CAS:28868-76-0
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Products Intro: Product Name:dimethyl 2-chloropropanedioate
CAS:28868-76-0
Purity:99% Package:5KG;1KG Remarks:C5H7ClO4
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Products Intro: Product Name:dimethyl chloromalonate
CAS:28868-76-0
Purity:99% Package:1kg

Dimethyl chloromalonate manufacturers

  • Dimethyl chloromalonate
  • Dimethyl chloromalonate pictures
  • $15.00 / 1KG
  • 2021-07-13
  • CAS:28868-76-0
  • Min. Order: 1KG
  • Purity: 99%+ HPLC
  • Supply Ability: Monthly supply of 1 ton
  • Dimethyl chloromalonate
  • Dimethyl chloromalonate pictures
  • $15.00 / 1KG
  • 2021-07-10
  • CAS:28868-76-0
  • Min. Order: 1KG
  • Purity: 99%+ HPLC
  • Supply Ability: Monthly supply of 1 ton
Dimethyl chloromalonate Basic information
Product Name:Dimethyl chloromalonate
Synonyms:Ethylsuccinyl monochloride;2-CHLORO-MALONIC ACID DIMETHYL ESTER;DIMETHYL CHLOROMALONATE;CL-DMM;AURORA KA-6079;2-Chloropropanedioic acid dimethyl ester;Chloro-Methyl Malonate;ChlorotwoMethylMalonic acid
CAS:28868-76-0
MF:C5H7ClO4
MW:166.56
EINECS:249-275-0
Product Categories:ester series;Pharmaceutical Intermediates;TheMalonateRamificationProducts;C2 to C5;Carbonyl Compounds;Esters
Mol File:28868-76-0.mol
Dimethyl chloromalonate Structure
Dimethyl chloromalonate Chemical Properties
Boiling point 105-106 °C/19 mmHg (lit.)
density 1.305 g/mL at 25 °C (lit.)
refractive index n20/D 1.437(lit.)
Fp 224 °F
storage temp. Keep in dark place,Sealed in dry,Room Temperature
form clear liquid
pka9.02±0.46(Predicted)
color Colorless to Light yellow
BRN 1768415
InChIInChI=1S/C5H7ClO4/c1-9-4(7)3(6)5(8)10-2/h3H,1-2H3
InChIKeyLNBQBURECUEBKZ-UHFFFAOYSA-N
SMILESC(OC)(=O)C(Cl)C(OC)=O
CAS DataBase Reference28868-76-0(CAS DataBase Reference)
Safety Information
Hazard Codes C
Risk Statements 34
Safety Statements 26-36/37/39-45
RIDADR UN 3265 8/PG 2
WGK Germany 3
21
HazardClass 8
PackingGroup III
HS Code 2917198090
MSDS Information
ProviderLanguage
SigmaAldrich English
Dimethyl chloromalonate Usage And Synthesis
UsesDimethyl chloromalonate is suitable for use in the synthesis of 4,5,6-trichloropyrimidine. It may be used in the stereoselective synthesis of highly functionalized nitrocyclopropanes. It may be used in one-pot synthesis of tetra-alkoxycarbonylallylidenetriphenylphosphoranes.
General DescriptionDimethyl chloromalonate (dimethyl 2-chloromalonate) is a dialkyl 2-substituted malonate. Carbanions of dimethyl chloromalonate are reported to react with naphthoquinone derivatives, via vicarious nucleophilic substitution or oxidative nucleophilic substitution of hydrogen processes. Dimethyl chloromalonate is reported to react with hydroquinone and monosubstituted hydroquinones to afford 2-oxido-benzo[b]furan derivatives. Synthesis of dimethyl 2-chloromalonate, via chlorination of dimethyl malonate has been reported.
Dimethyl chloromalonate Preparation Products And Raw materials
Raw materialsChlorine-->Dimethyl malonate
Preparation Products4-Methylbenzylsulfonyl chloride
Tag:Dimethyl chloromalonate(28868-76-0) Related Product Information
N,N-Dimethylformamide Dimethyl fluoromalonate Malononitrile Dimethyl sulfide Dimethyl methylmalonate Dimethyl fumarate Diethyl malonate Dimethyl phthalate Dimethyl sulfoxide ETHANE Dimethyl malonate Dimethyl ether Malonic acid Dimethyl acetamidomalonate Diethyl methylmalonate Dimethyl isobutylmalonate DIMETHYL METHOXYMALONATE 2,2-DIMETHYL-MALONIC ACID DIMETHYL ESTER

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