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| | ((R,R)-2-AMINO-1,2-DIPHENYLETHYL)[(4-TOLYL)SULFONYL]AMIDO](P-CYMENE)RUTHENIUM(II)CHLORIDE Basic information | | Reaction |
| Product Name: | ((R,R)-2-AMINO-1,2-DIPHENYLETHYL)[(4-TOLYL)SULFONYL]AMIDO](P-CYMENE)RUTHENIUM(II)CHLORIDE | | Synonyms: | ((R,R)-2-AMINO-1,2-DIPHENYLETHYL)[(4-TOLYL)SULFONYL]AMIDO](P-CYMENE)RUTHENIUM(II)CHLORIDE;Chloro{[(1R,2R)-(-)-2-amino-1,2-diphenylethyl](4-toluenesulfonyl)amido}(p-cymene)ruthenium(II), min. 95% RuCl[(R,R)-Tsdpen](p-cymene);Chloro{[(1R,2R)-(-)-2-amino-1,2-diphenylethyl](4-toluenesulfonyl)amido}(p-cymene)ruthenium(II), min. 95%;Chloro{[(1R,2R)-(-)-2-amino-1,2-diphenylethyl](4-toluenesulfonyl)amido}(p-
cymene)ruthenium(II), min. 95% RuCl[(R,R)-Tsdpen](p-cymene);Chloro{[(1R,2R)-(-)-2-aMino-1,2-diphenylethyl](4-toluenesulfonyl)aMido}(p-cyMene)rutheniuM(II),95% RuCl[(R,R)-Tsdpen](p-cyMene);((R,R)-2-aMino-1,2-diphenylethyl0[(4-tolyl)sulfonyl]aMino](p-cyMene)RutheniuM(II)chloride;Chloro{[(1R,2R)-(-)-2-aMino-1,2-diphenylethyl](4-toluenesulfonyl)aMido}(p-cyMene)rutheniuM(II), Min. 95% C31H35ClN2O2RuS;Chloro{[(1R,2R)-(-)-2-aMino-1,2-diphenylethyl](4-toluenesulfonyl)aMido}(p-cyMene)rutheniuM(II),RuCl[(R,R)-Tsdpen](p-cyMene) | | CAS: | 192139-92-7 | | MF: | C21H21ClN2O2RuS.C10H14 | | MW: | 636.219 | | EINECS: | | | Product Categories: | Ru;organometallic complex | | Mol File: | 192139-92-7.mol | ![((R,R)-2-AMINO-1,2-DIPHENYLETHYL)[(4-TOLYL)SULFONYL]AMIDO](P-CYMENE)RUTHENIUM(II)CHLORIDE Structure](CAS/GIF/192139-92-7.gif) |
| | ((R,R)-2-AMINO-1,2-DIPHENYLETHYL)[(4-TOLYL)SULFONYL]AMIDO](P-CYMENE)RUTHENIUM(II)CHLORIDE Chemical Properties |
| Melting point | 215 °C | | storage temp. | 2-8°C | | solubility | Deuterated Chloroform, DMF | | form | solid | | color | yellow to dark brown | | optical activity | [α]20/D 116°, c = 0.1 in chloroform | | Sensitive | air sensitive | | InChIKey | AZFNGPAYDKGCRB-MNPNNRAMNA-M | | SMILES | C1=C(S(=O)(=O)N([C@H](C2=CC=CC=C2)[C@H](N)C2=CC=CC=C2)[Ru]Cl)C=CC(C)=C1.C1=CC(C)=CC=C1C(C)C |&1:6,13,r| |
| WGK Germany | 3 | | HS Code | 28439000 |
| | ((R,R)-2-AMINO-1,2-DIPHENYLETHYL)[(4-TOLYL)SULFONYL]AMIDO](P-CYMENE)RUTHENIUM(II)CHLORIDE Usage And Synthesis |
| Reaction | This catalyst has shown to effect highly enantioselective hydrogenation of functionalized ketones where the substituents are dialkylamino, hydoxy, siloxy, carbonyl, ester, amide or thioester.
| | Chemical Properties | Orange to brown powder | | Uses | Phosphine cationic ruthenium catalysts used for enantioselective hydrogenation of:
- Quinolines
- N-Alkyl ketimines
- Antitumor and antiproliferative derivatives of natural products isolated from bacteria
- Hydroxy arylaldehydes via Rap-Stoermer-enantioselective transfer hydrogenation
Catalyst with improved performance modified via microenvironment engineering of nanocages | | General Description | RuCl(p-cymene)[(R,R)-Ts-DPEN] is a chiral diamine ligand complexed with ruthenium. |
| | ((R,R)-2-AMINO-1,2-DIPHENYLETHYL)[(4-TOLYL)SULFONYL]AMIDO](P-CYMENE)RUTHENIUM(II)CHLORIDE Preparation Products And Raw materials |
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