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| | (8S)-8α,13β-Dihydroxyserratinane-5-one Basic information |
| Product Name: | (8S)-8α,13β-Dihydroxyserratinane-5-one | | Synonyms: | (13S)-8α,13-Dihydroxyserratinan-5-one;(8S)-8α,13β-Dihydroxyserratinane-5-one;Serratinine;Serratinin, 7aα,1-Trimethylen-4aβ,5β-(1'β,4'α-dihydroxy-3'α-methyl-tetramethylen)-perhydro-pyrindinon-(7);5H,9H,12H-Indeno[7a,1-h]indolizin-12-one, decahydro-1,4-dihydroxy-2-methyl-, (1S,2S,4S,4aS,11aR,13aS)- (9CI) | | CAS: | 5545-99-3 | | MF: | C16H25NO3 | | MW: | 279.37 | | EINECS: | | | Product Categories: | | | Mol File: | 5545-99-3.mol |  |
| | (8S)-8α,13β-Dihydroxyserratinane-5-one Chemical Properties |
| | (8S)-8α,13β-Dihydroxyserratinane-5-one Usage And Synthesis |
| Description | A further alkaloid present in Lycopodium serratum Thunb. vaT. thunbergii Mak. The base crystallizes from Me2CO in colourless prisms and has [α]8D - 27.8° (c 1.44, EtOH). Two non-phenolic hydroxyl groups are present and the alkaloid forms the 8-0-acetate, m.p. 244-5°C; the l3-0-acetate, m.p. 240-2°C and the di-O-acetate, m.p. 1 57-8°C. The tetracyc1ic structure has been proposed on the basis of the mass spectra of the alkaloid and a tentative biogenesis from lycodoline-type alkaloids also proposed. | | References | Inubushi et al., Tetrahedron Lett., 1537 (1966)
Mass spectra:
Inubishietal., Tetrahedron, 24,3541 (1968)
Stereochemistry :
Inubushi et al., Tetrahedron Lett., 1551 (1966)
Biosythesis:
Inubushi et aI., Chem. Pharm. Bull. (Tokyo), 16,92 (1968) |
| | (8S)-8α,13β-Dihydroxyserratinane-5-one Preparation Products And Raw materials |
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