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J & K SCIENTIFIC LTD.
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Product Name:(S)-(-)-4-[2-(Diphenylphosphino)-1-naphthalenyl]-N-[(R)-1-phenylethoxy]phthalazine, min. 97% (R,S)-O-PINAP CAS:828927-94-2 Purity:min. 95% Package:1g;250mg
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Bide Pharmatech Ltd.
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Product Name:(S)-4-[2-(Diphenylphosphino)-1-naphthalenyl]-N-[(R)-1-phenylethoxy]phthalazine CAS:828927-94-2 Purity:97% Package:100mg;250mg;1g;
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LaaJoo
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Product Name:(S)-(-)-4-[2-(Diphenylphosphino)-1-naphthalenyl]-N-[(R)-1-phenylethoxy]phthalazine CAS:828927-94-2 Purity:97% Package:100mg
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Rhawn Reagent
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Product Name:(S)-(-)-4-[2-(DIPHENYLPHOSPHINO)-1-NAPHTHALENYL]-N-[(R)-1-PHENYLETHOXY]PHTHALAZINE CAS:828927-94-2
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Shanghai Anyinuo Biomedical Technology Co., Ltd.
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021-34625901 |
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Products Intro: |
Product Name:(S)-4-[2-(Diphenylphosphino)-1-naphthalenyl]-N-[(R)-1-phenylethoxy]phthalazine CAS:828927-94-2 Purity:>=98% Package:100mg;250mg;500mg;1g;10g;100g;1kg
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| (S)-(-)-4-[2-(DIPHENYLPHOSPHINO)-1-NAPHTHALENYL]-N-[(R)-1-PHENYLETHOXY]PHTHALAZINE Basic information | Reaction |
Product Name: | (S)-(-)-4-[2-(DIPHENYLPHOSPHINO)-1-NAPHTHALENYL]-N-[(R)-1-PHENYLETHOXY]PHTHALAZINE | Synonyms: | (S)-(-)-4-[2-(Diphenylphosphino)-1-naphthalenyl]-N-[(R)-1-phenylethoxy]phthalazine,Min.95%(R,S)-O-PINAP;(R)-(+)-4-[2-(DIPHENYLPHOSPHINO)-1-NAPHTHALENYL]-N-[(R)-1-PHENYLETHOXY]PHTHALAZINE;(R,S)-O-PINAP;(S)-(-)-4-[2-(DIPHENYLPHOSPHINO)-1-NAPHTHALENYL]-N-[(R)-1-PHENYLETHOXY]PHTHALAZINE;(S)-(-)-4-[2-(Diphenylphosphino)-1-naphthalenyl]-N-[(R)-1-phenylethoxy]phthalazine, min. 97% (R,S)-O-PINAP;Phthalazine, 1-[2-(diphenylphosphino)-1-naphthalenyl]-4-[(1R)-1-phenylethoxy]-, (1S)- | CAS: | 828927-94-2 | MF: | C38H29N2OP | MW: | 560.62 | EINECS: | | Product Categories: | Chiral Phosphine;PINAP Series | Mol File: | 828927-94-2.mol | |
| (S)-(-)-4-[2-(DIPHENYLPHOSPHINO)-1-NAPHTHALENYL]-N-[(R)-1-PHENYLETHOXY]PHTHALAZINE Chemical Properties |
Melting point | 178-181°C | alpha | -160.4° (c 0.53, CHCl3) | Boiling point | 726.4±60.0 °C(Predicted) | pka | 3.45±0.30(Predicted) | form | crystal | color | colorless | Sensitive | air sensitive |
| (S)-(-)-4-[2-(DIPHENYLPHOSPHINO)-1-NAPHTHALENYL]-N-[(R)-1-PHENYLETHOXY]PHTHALAZINE Usage And Synthesis |
Reaction |
- The PINAP family of P,N ligands is a synthetically more accessible but a similarly performing analog of the QUINAP (15-1777, 15-1778) ligand in enantioselective hydroboration, alkyne addition, and azomethine cycloaddition reactions.
- With rhodium, enantioselective hydroboration of alkenes as a route to chiral alcohols.
- With silver, catalytic, enantioselective, azomethine cycloaddition with acrylates.
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| (S)-(-)-4-[2-(DIPHENYLPHOSPHINO)-1-NAPHTHALENYL]-N-[(R)-1-PHENYLETHOXY]PHTHALAZINE Preparation Products And Raw materials |
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